@article {1332,
	title = {Bis(amidate) titanium precatalyst for the intermolecular hydroamination of allenes},
	journal = {Inorganica Chimica Acta},
	volume = {359},
	number = {9},
	year = {2006},
	note = {ISI Document Delivery No.: 052YITimes Cited: 25Cited Reference Count: 64},
	month = {Jun},
	pages = {3097-3102},
	type = {Article},
	abstract = {A bis(amidate)-bis(amido) titanium complex (5) is an efficient precatalyst for the regioselective intermolecular hydroamination of substituted allenes. Arylamines react quickly with a 5 mol\% precatalyst loading at 90 degrees C to give the ketimine product, which can be reduced to give substituted amines. With precatalyst loading of 10 mol\% and temperatures of 120 degrees C alkyl amines can be used as viable substrates for the hydroamination of substituted allenes. (c) 2006 Elsevier B.V. All rights reserved.},
	keywords = {ALKENES, allenes, amidate ligands, AMIDO COMPLEXES, CATALYST, CYCLIZATION, HYDROAMINATION, IMIDO COMPLEXES, INTRAMOLECULAR HYDROAMINATION, NITROGEN-HETEROCYCLES, ORGANOLANTHANIDE-CATALYZED HYDROAMINATION, precatalyst, TERMINAL ALKYNES, titanium complex, UNPROTECTED AMINO OLEFINS, VINYLARENES},
	isbn = {0020-1693},
	url = {<Go to ISI>://000238269600063},
	author = {Ayinla, R. O. and Schafer, L. L.}
}
@article {1106,
	title = {Interactions of Rh(III)-dihydrido-bis(phosphine) complexes with semicarbazones},
	journal = {Inorganic Chemistry},
	volume = {44},
	number = {5},
	year = {2005},
	note = {ISI Document Delivery No.: 902HUTimes Cited: 8Cited Reference Count: 34},
	month = {Mar},
	pages = {1482-1491},
	type = {Article},
	abstract = {Interaction of cis, trans, cis-[Rh(H)(2)(PR3)(2)(acetone)(2)] PF6 complexes (R = aryl or R-3 = Ph2Me, Ph2Et) under H-2 with E-semicarbazones gives the Rh(III)-dihydrido-bis(phosphine)-semicarbazone species cis, trans-[Rh(H)(2)(PR3)(2)-{R{\textquoteright}(R")C=N-N(H)CONH2}]PF6, where R{\textquoteright} and R" are Ph, Et, or Me. The complexes are generally characterized by elemental analysis, P-31{H-1} NMR, H-1 NMR, and IR spectroscopies, and MS. X-ray analysis of three PPh3 complexes reveals chelation of E-semicarbazones by the imine-N atom and the carbonyl-O atom. In contrast, the corresponding reaction of [Rh(H)(2)(PPhMe2)(2)(acetone)(2)]PF6 with acelophenone semicarbazone gives the orthometalated-semicarbazone species cis-[RhH(PPhMe2)(2){o-C6H4(Me)C=N-N(H)CONH2}]PF6. The X-ray structure of E-propophenone semicarbazone is also reported. Rhodium-catalyzed, homogeneous hydrogenation of semicarbazones was not observed even at 40 atm H-2.},
	keywords = {BENZALDEHYDE SEMICARBAZONE, CATALYST, COMPLEXES, CRYSTAL-STRUCTURES, DIHYDRIDO COMPLEXES, HYDROGENATION, LIGANDS, MOLECULAR-STRUCTURES, REFINEMENT, rhodium, UNPRECEDENTED CHEMICAL TRANSFORMATION},
	isbn = {0020-1669},
	url = {<Go to ISI>://000227346300049},
	author = {Ezhova, M. B. and Patrick, B. O. and Sereviratne, K. N. and James, Brian R. and Waller, F. J. and Ford, M. E.}
}
@article {916,
	title = {Atom transfer radical polymerization using multidentate amine ligands supported on soluble hyperbranched polyglycidol},
	journal = {Macromolecular Chemistry and Physics},
	volume = {205},
	number = {5},
	year = {2004},
	note = {ISI Document Delivery No.: 811MBTimes Cited: 12Cited Reference Count: 31},
	month = {Mar},
	pages = {567-573},
	type = {Article},
	abstract = {Controlled polymerization of styrene in toluene was achieved by atom transfer radical polymerization (ATRP) using hyperbranched polyglycidol-supported multidentate amine ligands/(CuBr)-Br-I catalyst systems. These catalyst systems with nanoscopic dimensions were more active than the corresponding low-molecular-weight ligands. The controlled/living nature of the polymerization is supported by linear first order plots (ln[M](o)/[M] versus time) and a linear increase of (M) over bar (n) versus conversion as well as low polydispersity. Similar controlled polymerization of methyl methacrylate was possible in acetonitrile. Up to 97\% of total copper used for polymerization could be removed from the polymer by simple precipitation in methanol and filtration.},
	keywords = {AMBIENT-TEMPERATURE, atom transfer radical polymerization (ATRP), ATRP, branched, CATALYST, CATALYSTS, COPPER BROMIDE, DENDRIMERS, METHYL-METHACRYLATE, polystyrene, ROMP},
	isbn = {1022-1352},
	url = {<Go to ISI>://000220774900002},
	author = {Kumar, K. R. and Kizhakkedathu, J. N. and Brooks, D. E.}
}
@article {938,
	title = {Imine hydrolysis and role of a rhodium(I)-imine-amine complex in homogeneous H-2-hydrogenation of the imine and a rare example of inequivalent NH2 protons},
	journal = {Inorganic Chemistry},
	volume = {43},
	number = {16},
	year = {2004},
	note = {ISI Document Delivery No.: 844VXTimes Cited: 16Cited Reference Count: 19},
	month = {Aug},
	pages = {4820-4824},
	type = {Article},
	abstract = {{A Rh-catalyzed, homogeneous hydrogenation of the imine},
	keywords = {amine, ASYMMETRIC HYDROGENATION, CATALYST, CATIONIC COMPLEXES, PHOSPHINE COMPLEXES, rhodium},
	isbn = {0020-1669},
	url = {<Go to ISI>://000223190300016},
	author = {Marcazzan, P. and Abu-Gnim, C. and Seneviratne, K. N. and James, Brian R.}
}
@article {4352,
	title = {A comparison of bulk metal nitride catalysts for pyridine hydrodenitrogenation},
	journal = {Catalysis Letters},
	volume = {52},
	number = {1-2},
	year = {1998},
	note = {ISI Document Delivery No.: ZW621Times Cited: 29Cited Reference Count: 26},
	pages = {113-119},
	type = {Article},
	abstract = {A comparison of various group IV-VIII bulk metal nitride catalysts identified Co4N and Fe3N as having higher pyridine hydrodenitrogenation activity per unit area than Mo2N. Formation of the metal nitrides was confirmed by X-ray diffraction and X-ray photoelectron spectroscopy, and all the nitrides were prepared from metal oxide precursors using the same temperature-programmed reaction technique. In general, the specific activity of the metal nitrides decreased with increased hear of formation of the metal nitride.},
	keywords = {CATALYST, HYDRODENITROGENATION, HYDRODESULFURIZATION, metal nitride, MO2N, PYRIDINE, QUINOLINE, SUPPORTED MOLYBDENUM NITRIDE, SURFACE-AREA},
	isbn = {1011-372X},
	url = {<Go to ISI>://000074430100020},
	author = {Milad, I. K. and Smith, K. J. and Wong, P. C. and Mitchell, K. A. R.}
}
@article {3850,
	title = {Porphyrins bearing halogens at the meso-phenyl and beta-pyrrolic positions: Synthesis and spectral properties},
	journal = {Bulletin De La Societe Chimique De France},
	volume = {133},
	number = {7-8},
	year = {1996},
	note = {ISI Document Delivery No.: VN339Times Cited: 27Cited Reference Count: 58},
	pages = {765-775},
	type = {Article},
	abstract = {The synthesis of symmetrical porphyrins chlorinated at both ortho positions of the meso-aryl substituents, and the chlorination and bromination of the beta-pyrrole positions is reported. The beta-chlorination of meso-tetraphenylporphyrin via its nickel(II) complex is also described. In addition, we communicate the first perchlorination of tetramesitylporphyrin, where halogen substitution occurred at the beta-pyrrolic positions as well as at both the vacant meta positions of the trimethylphenyl groups. The iron complexes of these various polyhalogenated porphyrins are also described, since they are robust and efficient catalysts in oxidation reactions.},
	keywords = {6-dichlorophenyl) porphyrin, bromination, CATALYST, CHLORINATION, COMPLEXES, EASY ACCESS, EFFICIENT CATALYSTS, EPOXIDATION, home, iron porphyrin, IRON(III) PORPHYRINS, METALLOPORPHYRIN, METALLOPORPHYRINS, OXIDATION, SELECTIVE AIR-OXIDATION, TETRAARYLPORPHYRINS, tetrakis(2, TETRAMESITYLPORPHYRIN, TETRAPHENYLPORPHYRINS},
	isbn = {0037-8968},
	url = {<Go to ISI>://A1996VN33900018},
	author = {Wijesekera, T. and Dupre, D. and Cader, M. S. R. and Dolphin, D.}
}
@article {3264,
	title = {THE ONE-STEP SYNTHESIS OF CHIRAL AMINO PHOSPHINO FERROCENES},
	journal = {Journal of Organometallic Chemistry},
	volume = {492},
	number = {2},
	year = {1995},
	note = {ISI Document Delivery No.: QV350Times Cited: 10Cited Reference Count: 24},
	month = {May},
	pages = {157-164},
	type = {Article},
	abstract = {Reaction of the chiral lithium reagent-2-lithio-(alpha-N,N-dimethyl)aminoethylbenzene with 1,1{\textquoteright}-ferrocenediylphenylphosphine gives chiral aminophosphinoferrocenes that contain both chiral carbon and phosphorus centres. Treatment of the ferroceno-phane with 2-lithio-N,N-dimethylaminomethylferrocene followed by hydrolysis gives the product ferrocenyl 2-(dimethylaminomethylferrocenyl) phenylphosphine as a pair of diastereomers. The single crystal structures of compound 3a PdCl2 and compound 4. PdCl2.2CH(2)Cl(2) have been determined. The compounds, 2-(ferrocenylphenylphosphino)-1-(alpha-N, N{\textquoteright}-dimethylaminoethylbenzene)ferrocene, 5 and 1-[2-(alpha-N,N{\textquoteright}-dimethyraminoethylbenzene)phenylphospphino]-1{\textquoteright}-diphenyl phosphinoferrocene, 6a, have also been prepared by minor modifications of the methodology developed.},
	keywords = {<1>FERROCENOPHANES, ASYMMETRIC-SYNTHESIS, CATALYST, chirality, crystal structure, FERROCENE, GRIGNARD, HALIDES, HYDROGENATION, iron, METAL-COMPLEXES, ORGANIC, palladium, PHOSPHORUS, PLANAR CHIRALITY, REAGENTS, SECONDARY},
	isbn = {0022-328X},
	url = {<Go to ISI>://A1995QV35000005},
	author = {Butler, I. R. and Cullen, W. R. and Rettig, S. J. and White, A. S. C.}
}
