@article {2281,
	title = {Structure and vibrational assignment of the enol form of 1-chloro-1,1 difluoro-pentane-2,4-dione},
	journal = {J. Mol. Struct.},
	volume = {878},
	number = {1-3},
	year = {2008},
	note = {ISI Document Delivery No.: 300CGTimes Cited: 0Cited Reference Count: 42Tayyari, Sayyed Faramarz Najafi, Atefeh Afzali, Raheleh Emamian, Saeedreza Wang, Yan Alexander},
	month = {Apr},
	pages = {10-21},
	type = {Article},
	abstract = {<p>Molecular structure of 1-chloro-1,1-difluoro-pentane-2,4-dione (monochlorodifluoro-acetylacetone, CDFAA) has been investigated by means of ab initio and Density Functional Theory (DFT) calculations and the results were compared with those of 1,1,1-trifluoropentane-2,4-dione (trifluoro-acetylacetone, TFAA). The harmonic vibrational frequencies of the two most stable cis-enol forms were calculated at the 133LYP level of theory using 6-3 1 G** and 6-311 ++G** basis sets. We also calculated the anharmonic frequencies at the B3LYP/6-31G** level of theory for these two stable cis-enol isomers. The calculated frequencies and the Raman and IR intensities were compared with the experimental results. The energy difference between the two stable cis-enol forms, calculated at the MP2/6-31G** level, is only 3.42 U/mol. The observed vibrational frequencies and intensities in the gas phase are in excellent agreement with the corresponding values calculated for the two most stable conformers. However, the observed IR and Raman frequencies also indicate coexisting of both tautomers in the liquid phase and in solution. According to the theoretical calculations, at the B3LYP/6-31 1++G** level, the hydrogen bond strength for the most stable conformer is 54.45 U/mol, about 2.4 kJ/mol less than that of the corresponding conformer of TFAA. These results are in agreement with the obtained experimental data. (C) 2007 Elsevier B.V. All rights reserved.</p>},
	keywords = {1-chloro-1, 1-difluoro-pentane-2, 4-dione, AB-INITIO, anharmonicity, BETA-DIKETONES, density, ELECTRON-DIFFRACTION, ENERGY, EQUILIBRIUM, functional theory, HEXAFLUORO-ACETYLACETONE, intramolecular hydrogen bond, MALONALDEHYDE, MOLECULAR-STRUCTURE, TAUTOMERISM, vibrational spectra},
	isbn = {0022-2860},
	url = {<Go to ISI>://000255801300002},
	author = {S. F. Tayyari* and Najafi, A. and Afzali, R. and Emamian, S. and Wang, Y. A.}
}
@article {5216,
	title = {Fourier transform microwave spectroscopy of cyanides and isocyanides of Al, Ga, and In},
	journal = {Journal of Molecular Spectroscopy},
	volume = {209},
	number = {2},
	year = {2001},
	note = {ISI Document Delivery No.: 490JPTimes Cited: 22Cited Reference Count: 44},
	month = {Oct},
	pages = {178-191},
	type = {Article},
	abstract = {Microwave spectra of the three Group 13 metal cyanide pairs AlNC/AlCN, GaNC/GaCN, and InNC/InCN have been measured in the frequency range 6-25 GHz using a pulsed jet cavity Fourier transform microwave spectrometer. The molecules were prepared by ablating the metal with a pulsed Nd:YAG laser and allowing the vapor to react with cyanogen or acetonitrile contained in the Ar backing gas of the jet. The spectra are those of linear molecules. Rotational constants. centrifugal distortion constants. and nuclear quadrupole coupling constants have been precisely evaluated. Molecular geometries determined from the rotational constants using a linear model have revealed unexpectedly short NC bond lengths for the isocyanides, MNC, and are interpreted in terms of a broadened potential well for the bending mode of these molecules. This interpretation is confirmed with ab initio calculations. The centrifugal distortion constants are consistent with this picture. A new formulation of the rigid bender model has produced plausible values for bond lengths and bending amplitudes for the isocyanides. The N-14 quadrupole coupling constants are discussed in terms of the approximate bending amplitudes. A description of the bonding in the molecules has been obtained using Townes-Dailey theory. (C) 2001 Academic Press.},
	keywords = {aluminum, ATOMS, CORRELATED MOLECULAR CALCULATIONS, EQUILIBRIUM, GAUSSIAN-BASIS SETS, IRC+10216, MONOCYANIDES, PARAMETERS, SPECTRUM, STRUCTURE, TRENDS},
	isbn = {0022-2852},
	url = {<Go to ISI>://000172049000004},
	author = {Walker, K. A. and Evans, C. J. and Suh, S. H. K. and Gerry, M. C. L. and Watson, J. K. G.}
}
@article {4613,
	title = {Excess partial molar enthalpy of 1-propanol in 1-propanol-NaCl-H2O at 25 degrees C: The effect of NaCl on molecular organization of H2O},
	journal = {Journal of Physical Chemistry B},
	volume = {103},
	number = {15},
	year = {1999},
	note = {ISI Document Delivery No.: 189YNTimes Cited: 23Cited Reference Count: 26},
	month = {Apr},
	pages = {2981-2983},
	type = {Article},
	abstract = {Excess partial molar enthalpies of l-propanol, H-1p(E), in 1-propanol-NaCl-H2O were measured directly, accurately, and in small increments in mole fraction of 1-propanol, x(1P), at 25 degrees C in the range x(NaCl) < 0.04 x(NaCl) is the mole fraction of NaCl. The enthalpic interaction function, H-1P-1P(E), between l-propanol molecules was then evaluated. H-1P-1P(E) is a convenient, model-free measure for the intermolecular interaction in terms of enthalpy. The behavior of these thermodynamic quantities was compared with that of the binary 1-propanol-H2O. Based on the knowledge accumulated in our laboratory on the binary aqueous l-propanol, the effect of NaCl on H2O became apparent. Our tentative conclusions are that (1) a NaCl molecule "binds" to seven or eight molecules of H2O on dissolving into H2O, and (2) the reminder of bulk H2O away from solute NaCl is not affected and stays almost the same as pure H2O.},
	keywords = {2-BUTOXYETHANOL, AQUEOUS SODIUM-CHLORIDE, CLUSTERS, EQUILIBRIUM, fluctuations, INTERMOLECULAR INTERACTIONS, LYSOZYME, SPECTROSCOPY, vibrational, VOLUMES, WATER},
	isbn = {1089-5647},
	url = {<Go to ISI>://000079934100023},
	author = {Matsuo, H. and To, E. C. H. and Wong, D. C. Y. and Sawamura, S. and Taniguchi, Y. and Koga,Yoshikata}
}
@article {4410,
	title = {Complexation of gallium(III) by 2-hydroxynicotinic acid and 3-hydroxypicolinic acid in aqueous solution},
	journal = {Inorganica Chimica Acta},
	volume = {273},
	number = {1-2},
	year = {1998},
	note = {ISI Document Delivery No.: ZP204Times Cited: 17Cited Reference Count: 27XXXIII International Conference on Coordination ChemistryAUG 30-SEP 04, 1998FLORENCE, ITALY},
	month = {May},
	pages = {47-53},
	type = {Proceedings Paper},
	abstract = {The deprotonations of 2-hydroxynicotinic acid (H(2)nic) and 3-hydroxypicolinic acid (H(2)pic) and the complexation of these molecules with Ga3+ were studied by H-1 NMR, UV-Vis spectrophotometry and potentiometric titration. Both ligands bind Ga3+ at very low pH; the ligand binds in the monodeprotonated form. The stability constants of the [Ga(HL)(n)]((3-n)+) (L = nic or pic; n = 1, 2, or 3) complexes were measured at 25 degrees C, 1.0 M NaCl (for beta(1)) and 0.16 M NaCl (for beta(2) and beta(3)); for H(2)nic (H(2)pic), log beta(1) = 6.78 (7.04), log beta(2) = 12.43 (13.09) and log beta(3) = 16.20 (17.74). At higher pH, polynuclear mixed ligand-hydroxo species form, although their composition and stability could not be determined. These complexes undergo hydrolysis to form [Ga(OH)(4)](-) above pH 7. (C) 1998 Elsevier Science S.A. All rights reserved.},
	keywords = {3-HYDROXY-4-PYRIDINONES, aluminum, CHELATION, CHEMISTRY, COMPLEXES, EQUILIBRIUM, GA-68, gallium complexes, hydroxynicotinic acid, hydroxypicolinic acid complexes, INDIUM COMPLEXES, INVIVO, LIGANDS, RADIOPHARMACEUTICALS},
	isbn = {0020-1693},
	url = {<Go to ISI>://000073728200008},
	author = {Stephens, A. K. W. and Orvig, Chris}
}
@article {4364,
	title = {Improved initial density dependence of the viscosity and a corresponding states function for high pressures},
	journal = {Physica a-Statistical Mechanics and Its Applications},
	volume = {260},
	number = {1-2},
	year = {1998},
	note = {ISI Document Delivery No.: 135WLTimes Cited: 24Cited Reference Count: 50},
	month = {Nov},
	pages = {31-48},
	type = {Article},
	abstract = {The initial density correction to gaseous viscosity using accurate realistic potentials of the noble gases is evaluated using the Rainwater-Friend theory. It is shown that this theory works satisfactorily for densities up to about 2 mol dm(-3). Due to the superimposability of the noble gas potential functions, a universal function of the reduced second viscosity virial coefficient is obtained over the entire reduced temperature range. At densities beyond the range of the theory, a variant of the excess viscosity is developed, by which the viscosity of the different gases can be easily calculated above the critical temperature for pressures up to 900 MPa. The accuracy of this method is within the experimental uncertainties. (C) 1998 Elsevier Science B.V. All rights reserved.},
	keywords = {11 POLYATOMIC GASES, ARGON, COEFFICIENT, COEFFICIENTS, EQUILIBRIUM, high-pressure excess viscosity, NOBLE-GASES, ORGANIC VAPORS, PHYSICAL-PROPERTIES, Rainwater-Friend theory, second viscosity virial, TEMPERATURE, THERMAL-CONDUCTIVITY, TRANSPORT-PROPERTIES, VISCOSITY},
	isbn = {0378-4371},
	url = {<Go to ISI>://000076825600004},
	author = {Najafi, B. and Ghayeb, Y. and Rainwater, J. C. and Alavi, S. and Snider, R. F.}
}
@article {4114,
	title = {Analysis of single and multiple quantum NMR spectra of 1,3-dichloro-2-ethenylbenzene in liquid crystal solvents},
	journal = {Molecular Physics},
	volume = {90},
	number = {4},
	year = {1997},
	note = {ISI Document Delivery No.: WN909Times Cited: 10Cited Reference Count: 37},
	month = {Mar},
	pages = {541-551},
	type = {Article},
	abstract = {The single and multiple quantum NMR spectra of 1,3-dichloro-2-ethenylbenzene as solute in two different nematic liquid crystals have been measured and analysed in terms of dipolar couplings and chemical shift differences. Because the single quantum spectra did not yield to straightforward analysis, normal and frequency selective multiple quantum experiments were used to aid the analysis. The results from four spectra were combined to yield structural information and the order matrix in each solution. The structure of the ring is very close to that of 1,3-dichlorobenzene, and that of the ethenyl group very close to that of ethenyl-benzene. The dihedral angle between the ethenyl group and the aromatic ring is found to be 454 +/- 1.0 degrees, and the C-CC=C angle is found to be 127.3 +/- 0.3 degrees.},
	keywords = {EQUILIBRIUM, FIELD, MAGNETIC-RESONANCE, MIXTURES, MOLECULAR-STRUCTURE, orientational order, ROTATION, SHAPE, SOLUTES, SPECTROSCOPY},
	isbn = {0026-8976},
	url = {<Go to ISI>://A1997WN90900005},
	author = {Rendell, J. C. T. and Burnell, E. E.}
}
@article {3813,
	title = {Nonequilibrium effects in reactive systems; The effect of reaction products and the validity of the Chapman-Enskog method},
	journal = {Physica a-Statistical Mechanics and Its Applications},
	volume = {223},
	number = {1-2},
	year = {1996},
	note = {ISI Document Delivery No.: TQ402Times Cited: 30Cited Reference Count: 62},
	month = {Jan},
	pages = {50-86},
	type = {Article},
	abstract = {The rates of gas phase reactions can be calculated from the averages of the appropriate reactive cross sections with the velocity distribution functions of the reacting species. The reactive process, especially for reactions with activation energy, removes translationally energetic species and the velocity distribution functions depart from Maxwellian. The rate coefficients can differ from the equilibrium rate calculated with the Maxwell-Boltzmann distribution. The extent of the departure of the distribution function from Maxwellian can be estimated from solutions of the Boltzmann equation with appropriate choices for the elastic and reactive collision cross sections. If there is a good separation in the elastic and reactive collision time scales, a steady solution of the Boltzmann equation can be obtained with a procedure analogous to the Chapman-Enskog method for transport coefficients. In the present paper, the nonequilibrium effects for model reactive systems of the type A + A reversible arrow B + B, with and without the reverse reaction, and the reaction A + C {\textendash}> products are examined with both a Chapman-Enskog method along with an explicitly time-dependent solution for the irreversible reaction A + A {\textendash}> B + B. The main objectives are to study the effect of the inclusion of the products with and without a reverse reaction as well as the range of validity of the Chapman-Enskog method.},
	keywords = {ANOMALOUS TRANSPORT, DISTRIBUTIONS, EQUILIBRIUM, HEAT-FLUX, hydrodynamics, KINETIC-THEORY, LASER-INDUCED FLUORESCENCE, PERTURBATION, PLASMA, STRONGLY INHOMOGENEOUS SYSTEMS, VELOCITY},
	isbn = {0378-4371},
	url = {<Go to ISI>://A1996TQ40200005},
	author = {Shizgal, B. D. and Napier, D. G.}
}
@article {2983,
	title = {COMPARISON OF SHORT-RANGE INTERACTIONS IN NEMATIC LIQUID-CRYSTALS - A H-2-NMR STUDY OF 5CB-D(19) AS A SOLUTE},
	journal = {Liquid Crystals},
	volume = {17},
	number = {4},
	year = {1994},
	note = {ISI Document Delivery No.: PH470Times Cited: 4Cited Reference Count: 42},
	month = {Oct},
	pages = {457-485},
	type = {Article},
	abstract = {Previous studies using dideuterium as a solute have demonstrated the importance for orientation of the interaction between the solute molecular quadrupole moment and the average electric field gradient present in liquid crystals. With the aim of learning about additional orientational mechanisms, we have studied the temperature dependence of the H-2-NMR spectra of the liquid crystal 5CB-d(19) as the solute in three liquid crystal mixtures: 55 wt \% 1132/EBBA, 56.5 wt \% 1132/EBBA and 70 wt \% 5CB/EBBA. In these mixtures, the contribution from the environment to the average electric field gradient at the H-2 nucleus of dideuterium is zero. The spectra of 5CB-d(19) in the mixtures 55 wt \% 1132/EBBA and 56.5 wt \% 1132/EBBA are equivalent, but are different from those in 70 wt \% 5CB/EBBA. The spectra of 5CB in 55 wt \% 1132/EBBA and 70 wt \% 5CB/EBBA are analysed using two different models for the short range potential, and parameters of the models are used to compare the potentials in the different mixtures. For a given spectral splitting of the chain C-1 deuteron, the reduced short range potential is the same in all three mixtures studied. The spectral differences observed are a consequence of different nematic-isotropic phase transition temperatures combined with the effect of trans/gauche-isomerization in the hydrocarbon chain.},
	keywords = {BINARY-MIXTURES, EQUILIBRIUM, FLEXIBILITY, MAGNETIC-RESONANCE, MOLECULAR-STRUCTURE, MULTIPLE-QUANTUM NMR, NORMAL-BUTANE, orientational order, RAMAN-SPECTRA, SPECTROSCOPY},
	isbn = {0267-8292},
	url = {<Go to ISI>://A1994PH47000001},
	author = {Chandrakumar, T. and Zimmerman, D. S. and Bates, G. S. and Burnell, E. E.}
}
@article {2983,
	title = {COMPARISON OF SHORT-RANGE INTERACTIONS IN NEMATIC LIQUID-CRYSTALS - A H-2-NMR STUDY OF 5CB-D(19) AS A SOLUTE},
	journal = {Liquid Crystals},
	volume = {17},
	number = {4},
	year = {1994},
	note = {ISI Document Delivery No.: PH470Times Cited: 4Cited Reference Count: 42},
	month = {Oct},
	pages = {457-485},
	type = {Article},
	abstract = {Previous studies using dideuterium as a solute have demonstrated the importance for orientation of the interaction between the solute molecular quadrupole moment and the average electric field gradient present in liquid crystals. With the aim of learning about additional orientational mechanisms, we have studied the temperature dependence of the H-2-NMR spectra of the liquid crystal 5CB-d(19) as the solute in three liquid crystal mixtures: 55 wt \% 1132/EBBA, 56.5 wt \% 1132/EBBA and 70 wt \% 5CB/EBBA. In these mixtures, the contribution from the environment to the average electric field gradient at the H-2 nucleus of dideuterium is zero. The spectra of 5CB-d(19) in the mixtures 55 wt \% 1132/EBBA and 56.5 wt \% 1132/EBBA are equivalent, but are different from those in 70 wt \% 5CB/EBBA. The spectra of 5CB in 55 wt \% 1132/EBBA and 70 wt \% 5CB/EBBA are analysed using two different models for the short range potential, and parameters of the models are used to compare the potentials in the different mixtures. For a given spectral splitting of the chain C-1 deuteron, the reduced short range potential is the same in all three mixtures studied. The spectral differences observed are a consequence of different nematic-isotropic phase transition temperatures combined with the effect of trans/gauche-isomerization in the hydrocarbon chain.},
	keywords = {BINARY-MIXTURES, EQUILIBRIUM, FLEXIBILITY, MAGNETIC-RESONANCE, MOLECULAR-STRUCTURE, MULTIPLE-QUANTUM NMR, NORMAL-BUTANE, orientational order, RAMAN-SPECTRA, SPECTROSCOPY},
	isbn = {0267-8292},
	url = {<Go to ISI>://A1994PH47000001},
	author = {Chandrakumar, T. and Zimmerman, D. S. and Bates, G. S. and Burnell, E. E.}
}
@article {2953,
	title = {PHARMACOKINETICS AND DISTRIBUTION OF TRIS(MALTOLATO)ALUMINUM(III) INTO THE CENTRAL-NERVOUS-SYSTEM},
	journal = {Neurotoxicology},
	volume = {15},
	number = {2},
	year = {1994},
	note = {ISI Document Delivery No.: PB305Times Cited: 4Cited Reference Count: 37},
	month = {Sum},
	pages = {371-378},
	type = {Article},
	abstract = {The maltolate compound of aluminum (Al), tris(maltolato)aluminum(III), has been demonstrated to be quite toxic after central administration and in cell cultures. However, reports of peripheral Al-maltolate administration in vivo demonstrated un impressive neurological effects. We found no reports of Al-maltolate pharmacokinetics or its distribution into the central nervous system (CNS) after systemic administration. In the present study, we evaluated Al pharmacokinetics in serum and Al distribution into brain extracellular fluid (ECF) in rats following Al-maltolate administration. The pharmacokinetic studies revealed that systemic clearance, elimination half-life and mean residence time were 42 (+/- 5) ml/hr/kg, 2.2 (+/- 0.5) hr and 3.1 (+/- 0.7) hr [mean+/-SD), respectively. The steady state volume of distribution (V-ss) for Al-maltolate was 130 ml/kg. This V-ss suggests that Al-maltolate may exhibit limited distribution outside the vascular compartment, which is estimated to be approximate to 80 ml/kg in these rats. Previously, we used microdialysis (MD) probes to assess Al-citrate distribution into the CNS. MD was utilized in the present study to evaluate the CNS distribution of Al as a result of Al-maltolate administration. MD probes were implanted into the frontal cortex (FC) and jugular vein to sample Al from brain and blood ECF, respectively. Al was not measurable in FC MD probe dialysates after a 0.5 mmol/kg Al (as maltolate) bolus, but could be measured after steady state blood and brain ECF Al concentrations had been achieved. The Al brain/blood ra tio calculated from Al-maltolate steady state brain and blood MD samples was 0.04, significantly less than those calculated for other Al salts at equimolar Al doses. The present study suggests that unless it is administered centrally, Al-maltolate might render minimal neurological insult because of its minimal permeation into brain extracellular space. (C) 1994 Intox Press, Inc.},
	keywords = {ALUMINUM MALTOL, ALUMINUM NEUROTOXICITY, ALUMINUM PHARMACOKINETICS, ALUMINUM-MALTOLATE, BLOOD-BRAIN-BARRIER, COMPLEXES, DIALYSIS, ENCEPHALOPATHY, EQUILIBRIUM, gallium, INVIVO MICRODIALYSIS, MICRODIALYSIS, permeability, RABBITS, SERUM},
	isbn = {0161-813X},
	url = {<Go to ISI>://A1994PB30500014},
	author = {Allen, D. D. and Orvig, Chris and Yokel, R. A.}
}
@article {3107,
	title = {PREPARATION OF 2-SUBSTITUTED AND 4-SUBSTITUTED 3-HYDROXY-5-METHYLFURANS AND THE ALUMINUM AND GALLIUM COMPLEXES OF 3-HYDROXY-5-METHYL-2-(N-METHYLFORMAMIDO)FURAN},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {72},
	number = {5},
	year = {1994},
	note = {ISI Document Delivery No.: NU280Times Cited: 3Cited Reference Count: 40},
	month = {May},
	pages = {1362-1369},
	type = {Article},
	abstract = {In model studies designed to study the synthesis of potentially hexadentate chelates based on the linkage of three furan rings to a triamine via amide linkages, new 2- and 1-substituted 3-hydroxy-5-methylfurans have been prepared. Particularly, 3-hydroxy-5-methyl-(N-methylformamido)fur (Hahm) and its Al and Ga complexes (M(ahm)(3)) have been prepared and thoroughly characterized by a variety of techniques, in the solid state and in solution. Solution equilibrium studies (mu = 0.6 M NaCl, 25 degrees C) uncovered a complicated set of equilibria in the Al3+/Hahm system; the solution potentiometric data were best explained by the presence of mixed ligand (HL = Hahm, L(-) = ahm(-)) hydroxo species [Al-3(OH)(4)L(3)](2+) and [AI(OH)(2)L(2)](-), in addition to the expected [AlL(n)]((3-n)+) (n = 1, 2, 3) species. Further solution studies at HL:M ratios of 3:1 (mu = 0.15 M NaCl, 25 degrees C) showed that Hahm is a relatively weak complexing agent for both Al and Ga, forming tris-ligand species with overall formation constants of 10(19.5) and 10(20.6), respectively.},
	keywords = {0.6 M NA(CL), 3-HYDROXY-4-PYRIDINONES, ACID, AQUEOUS-SOLUTION, EQUILIBRIUM, HYDROLYSIS, indium, SILICON(IV)},
	isbn = {0008-4042},
	url = {<Go to ISI>://A1994NU28000020},
	author = {Lutz, T. G. and Clevette, D. J. and Hoveyda, H. R. and Karunaratne, V. and Nordin, A. and Sjoberg, S. and Winter, M. and Orvig, Chris}
}
@article {3198,
	title = {THE RESPONSE OF THE INDUCTIVELY-COUPLED ARGON PLASMA TO SOLVENT PLASMA LOAD - SPATIALLY-RESOLVED MAPS OF ELECTRON-DENSITY OBTAINED FROM THE INTENSITY OF ONE ARGON LINE},
	journal = {Spectrochimica Acta Part B-Atomic Spectroscopy},
	volume = {49},
	number = {12-14},
	year = {1994},
	note = {ISI Document Delivery No.: QD364Times Cited: 13Cited Reference Count: 40},
	month = {Oct-Dec},
	pages = {1231-1250},
	type = {Article},
	abstract = {A survey of spatially resolved electron number density (n(e)) in the tail cone of the inductively coupled argon plasma (ICAP) is presented: all of the results of the survey have been radially inverted by numerical, asymmetric Abel inversion. The survey extends over the entire volume of the plasma beyond the exit of the ICAP torch; It extends over distances of z = 5-25 mm downstream from the induction coil, and over radial distances of +/- 8 mm from the discharge axis. The survey also explores a range of inner argon flow rates (Q(IN)), solvent plasma load (Q(SPL)) and r.f. power: moreover, it explores loading by water, methanol and chloroform. Throughout the survey, n(e) was determined from the intensity of one, optically thin argon line, by a method which assumes that the atomic state distribution function (ASDF) for argon lies close to local thermal equilibrium (LTE). The validity of this assumption is reviewed. Also examined are the discrepancies between n(e) from this method and n(e) from Stark broadening measurements. With the error taken into account, the results of the survey reveal how time averaged values of n(e) in the ICAP respond over an extensive, previously unexplored range of experimental parameters. Moreover, the spatial information lends insight into how the thermal conditions and the transport of energy respond. Overall, the response may be described in terms of energy consumption along the axial channel and thermal pinch within the induction region. The predominating effect depends on the solvent plasma load, the solvent composition, the robustness of the discharge, and the distribution of solvent material over the argon stream.},
	keywords = {ATOMIC EMISSION-SPECTROMETRY, DESOLVATION, EQUILIBRIUM, EXCITATION, GAS-FLOW, INTRODUCTION, NUMBER, SAMPLE, STATE DISTRIBUTION FUNCTION, TEMPERATURE DETERMINATION, WATER},
	isbn = {0584-8547},
	url = {<Go to ISI>://A1994QD36400009},
	author = {Weir, D. G. J. and Blades, M. W.}
}
@article {2829,
	title = {COORDINATION CHEMISTRY OF 2-(2{\textquoteright}-HYDROXYPHENYL)-2-BENZOXAZOLE WITH GALLIUM(III) AND ALUMINUM(III) - 2 UNCOMMON GROUP-13 METAL ENVIRONMENTS STABILIZED BY A BIOLOGICALLY RELEVANT BINDING GROUP},
	journal = {Inorganic Chemistry},
	volume = {32},
	number = {22},
	year = {1993},
	note = {ISI Document Delivery No.: ME779Times Cited: 28Cited Reference Count: 36},
	month = {Oct},
	pages = {4909-4913},
	type = {Article},
	abstract = {{The coordination chemistry of Ga(III) and Al(III) with 2-(2{\textquoteright}-hydroxyphenyl)-2-benzoxazole (Hhbo) was investigated both in the solid state (X-ray crystallography) and in solution (H-1, C-13, Al-27 N MR) These two group 13 metal ions exhibit different reactivities toward this bulky bidentate ligand leading with Ga(III) to the formation of Ga(hbo)3 (1) and [Ga(hbo)2(0,0{\textquoteright}-CH3CO2)] (2) complexes depending on the reaction conditions. With AI(III), the only complex formed is[Al(mu-OH)(hbo)2]2(3). The Ga bis(ligand) acetate complex 2 (C28H19GaN2O6) crystallizes in the monoclinic space group C2/c with a = 16.008(3) angstrom},
	keywords = {ACID, AQUEOUS-SOLUTION, COMPLEXES, EQUILIBRIUM, HYDROLYSIS, PERSPECTIVE, PROTEINS, RIBONUCLEOTIDE REDUCTASE, SILICON(IV), SPECIATION},
	isbn = {0020-1669},
	url = {<Go to ISI>://A1993ME77900041},
	author = {Hoveyda, H. R. and Rettig, S. J. and Orvig, Chris}
}
@article {7283,
	title = {COMPLEXATION OF IRON WITH THE ORALLY ACTIVE DECORPORATION DRUG-L1 (3-HYDROXY-1,2-DIMETHYL-4-PYRIDINONE)},
	journal = {Clinical Chemistry},
	volume = {38},
	number = {4},
	year = {1992},
	note = {ISI Document Delivery No.: HN921Times Cited: 18Cited Reference Count: 37},
	month = {Apr},
	pages = {562-565},
	type = {Note},
	abstract = {{The stability constants for the Fe(III) complexes of the orally active iron decorporation drug L1 (3-hydroxy-1,2-dimethyl-4-pyridinone) have been determined by potentiometric titration [glass electrode, 25.0-degrees-C},
	keywords = {2-DIMETHYL-3-HYDROXYPYRID-4-ONE L1, aluminum, CHELATOR 1, CHEMISTRY, DESFERRIOXAMINE, EQUILIBRIUM, gallium, HETEROAROMATIC CHELATORS, IRON OVERLOAD, IRON-BINDING DRUGS, LONG-TERM TRIAL, MOBILIZATION, POTENTIOMETRIC TITRATION, PROGRAM},
	isbn = {0009-9147},
	url = {<Go to ISI>://A1992HN92100022},
	author = {Kline, M. A. and Orvig, Chris}
}
