@article {4971,
	title = {Hyperfine structure in the rotational spectrum of GaF: A comparison of experimental and calculated spin-rotation and electric field gradient tensors},
	journal = {Journal of Molecular Spectroscopy},
	volume = {204},
	number = {2},
	year = {2000},
	note = {ISI Document Delivery No.: 380JBTimes Cited: 18Cited Reference Count: 74},
	month = {Dec},
	pages = {184-194},
	type = {Article},
	abstract = {{The high-resolution pure rotational spectrum of Gal; has been measured using a Balle-Flygare-type Fourier transform spectrometer. improved nuclear quadrupolar coupling constants and rotational constants have been obtained along with the first reported fluorine spin-rotation constant for gallium fluoride, C-I ((GaF)-Ga-69-F-19},
	keywords = {ab initio calculations, CHEMICAL-SHIFTS, CONSTANTS, electric field gradient tensors, FINITE BASIS-SET, gallium fluoride, group-13 fluorides, HARTREE-FOCK CALCULATIONS, hyperfine structure, LASER-ABLATION, MICROWAVE-SPECTRUM, MILLIMETER, MOLECULES, MONOFLUORIDE, NMR, nuclear magnetic shielding tensors, quadrupolar coupling, QUADRUPOLE COUPLING-CONSTANTS, rotational spectroscopy, SPECTROSCOPY, spin-rotation constants},
	isbn = {0022-2852},
	url = {<Go to ISI>://000165697100003},
	author = {Wasylishen, R. E. and Bryce, D. L. and Evans, C. J. and Gerry, M. C. L.}
}
@article {4109,
	title = {Fourier-transform microwave spectrum, structure, harmonic force field, and hyperfine constants of sulfur chloride fluoride, ClSF},
	journal = {Journal of Chemical Physics},
	volume = {106},
	number = {24},
	year = {1997},
	note = {ISI Document Delivery No.: XE593Times Cited: 3Cited Reference Count: 46},
	month = {Jun},
	pages = {10037-10047},
	type = {Article},
	abstract = {The rotational spectrum of sulfur choride fluoride, ClSF, has been observed for the first time in the frequency range 8-26 GHz by means of a pulsed molecular jet Fourier-transform microwave spectrometer. The unstable sample molecule has been prepared using a pulsed electrical discharge in jets containing a mixture of SF6 and SCl2 in Ne. Besides the parent species (ClSF)-Cl-35-S-32-F-19, the isotopomers (ClSF)-Cl-37-S-32-F-19 and (ClSF)-Cl-35-S-34-F-19 could be observed in natural abundance. Rotational constants and quartic centrifugal distortion constants as well as nuclear quadrupole coupling constants due to Cl-35 and Cl-37 and spin-rotation constants due to Cl-35, Cl-37, and F-19 are given. The data were used for the determination of r(0), r(Delta P), r(s) structural parameters. Additionally, the new data were used for the refinement of the molecular harmonic force field. Results from those harmonic force field calculations were applied in the evaluation of the ground-state average structure, r(z), and the estimation of the equilibrium structure, r(e). The r(s) structure is r(SF)=160.653(162) pm, r(SCl)=199.437(65) pm, and angle(ClSF)=100.732(81)degrees. The diagonal elements of the Cl-35/Cl-37 quadrupole coupling tensors have been obtained, and are interpreted in terms of the bonding at Cl-35/Cl-37. Negative F-19 spin-rotation constants suggest a close analogy of the electronic structures of CISF and SF2. (C) 1997 American Institute of Physics.},
	keywords = {(SF2)-S-32, DICHLORIDE, DIFLUORIDE, DIODE-LASER SPECTROSCOPY, F-19 SPIN, MONOFLUORIDE, POTENTIAL FUNCTION, QUADRUPOLE COUPLING-CONSTANTS, ROTATION, SCL2, SPECTROMETER},
	isbn = {0021-9606},
	url = {<Go to ISI>://A1997XE59300006},
	author = {Preusser, J. and Gerry, M. C. L.}
}
@article {3785,
	title = {Density functional computations of the dipole moment derivatives for halogenated silanes},
	journal = {Theochem-Journal of Molecular Structure},
	volume = {363},
	number = {1},
	year = {1996},
	note = {ISI Document Delivery No.: UH856Times Cited: 1Cited Reference Count: 49},
	month = {Mar},
	pages = {115-124},
	type = {Article},
	abstract = {Electric dipole moments for the equilibrium molecular structures and their derivatives along the symmetry coordinates of vibration were computed for SiH2F2, SiD2F2, SiH2Cl2, SiD2Cl2, SiH3F, SiD3F, SiH3Cl, SiD3Cl, SiHF3, SiDF3, SiHCl3, SiDCl3, SIFCl3, SiF3Cl, SiF4 and SiCl4 by means of the deMon density functional program (A. St-Amant and D. R. Salahub, Chem. Phys. Lett., 169 (1990) 387). Satisfactory agreement was found between the experimental and computed dipole moments for the equilibrium molecular structures. Perfect agreement was found between the rotational corrections to the dipole moment derivatives calculated by deMon and those obtained independently from the orthogonality relationships between the symmetry coordinates and the rotational coordinates. Derivatives of the dipole moments were transformed into the representation of the normal coordinates of vibration and the results were compared with the experimental data which are available on the infrared intensities of fundamental bands.},
	keywords = {ABINITIO, density functional computations, DIPOLE MOMENT DERIVATIVES, GEOMETRIES, HALIDES, halogenated, METHANE, MICROWAVE-SPECTRA, MOLECULAR-STRUCTURES, QUADRUPOLE COUPLING-CONSTANTS, SILANES, SILYL, TRICHLOROSILANE, VIBRATIONAL-SPECTRA},
	isbn = {0166-1280},
	url = {<Go to ISI>://A1996UH85600010},
	author = {Papousek, D. and Papouskova, Z. and Chong, D. P.}
}
@article {3456,
	title = {HYPERFINE CONSTANTS OF BROMINE AND IODINE MONOFLUORIDE},
	journal = {Journal of Chemical Physics},
	volume = {103},
	number = {2},
	year = {1995},
	note = {ISI Document Delivery No.: RH105Times Cited: 49Cited Reference Count: 67},
	month = {Jul},
	pages = {577-583},
	type = {Article},
	keywords = {BRF, DIODE-LASER SPECTRUM, DIPOLE-MOMENT, DISCHARGE, electronic state, F-19 SPIN ROTATION, FLUORIDE, FOURIER-TRANSFORM SPECTROMETER, GROUND, IF, QUADRUPOLE COUPLING-CONSTANTS},
	isbn = {0021-9606},
	url = {<Go to ISI>://A1995RH10500011},
	author = {Muller, H. S. P. and Gerry, M. C. L.}
}
