@article {4011,
	title = {Coordination chemistry, and catalytic conversions, of H2S},
	journal = {Pure and Applied Chemistry},
	volume = {69},
	number = {10},
	year = {1997},
	note = {ISI Document Delivery No.: YB877Times Cited: 21Cited Reference Count: 6831st International Conference on the Coordination ChemistryAUG 18-23, 1996VANCOUVER, CANADA},
	month = {Oct},
	pages = {2213-2220},
	type = {Proceedings Paper},
	abstract = {Some reactions of H2S with solutions of Pd- and Ru-phosphine complexes are described. The Pd systems involve sulfur abstraction and generation of H-2, catalytic conversions of H2S to H-2, and attempts to catalyse the (H2S {\textendash}> H-2 + {\textquoteright}S{\textquoteright}) reaction. The Ru studies have led to crystallographic characterisation of a reversibly formed H2S complex, as well as more familiar oxidative addition-type chemistry of H2S. This lecture/review naturally emphasises work carried out at this University (UBC).},
	keywords = {ASPECTS, BIS(DIPHENYLPHOSPHINO)METHANE DPM, DINUCLEAR PALLADIUM(I) COMPLEXES, HYDROGEN-SULFIDE, LEWIS-ACIDS, Mechanistic, MOLECULAR-HYDROGEN, PHOSPHINE COMPLEXES, S-H, SULFUR-CONTAINING LIGANDS, TRANSITION-METAL COMPLEXES},
	isbn = {0033-4545},
	url = {<Go to ISI>://A1997YB87700028},
	author = {James, Brian R.}
}
@article {4079,
	title = {Synthesis and X-ray structure of an H2S complex, RuCl2(P-N)(P(p-tolyl)(3))(SH2) (P-N=o-(diphenylphosphino)-N,N-dimethylaniline)},
	journal = {Inorganic Chemistry},
	volume = {36},
	number = {24},
	year = {1997},
	note = {ISI Document Delivery No.: YH560Times Cited: 24Cited Reference Count: 25},
	month = {Nov},
	pages = {5426-\&},
	type = {Article},
	abstract = {The interaction of transition metal complexes with H2S continues to attract attention. Such chemistry is of relevance in the biological sulfur cycle, in the formation of ores, in hydrodesulfurization catalysis, and in the use of H2S as a source of Hz and elemental sulfur (or organosulfur compounds). Literature dealing with these topics is plentiful and can be traced through recent references.(1,2) However, isolation and characterization of metal complexes containing H2S remain challenging,(2,3) as such species tend to undergo oxidative addition reactions to give products with SH ligands or bridged or terminal sulfide,(4) and only recently has an H2S complex been characterized crystallographically.(2) This was the structure reported by Sellmann et al. of the Ru(II)-complex Ru(SH2)(PPh3)({\textquoteright}S-4{\textquoteright}). THF ({\textquoteright}S-4{\textquoteright} = 1,2-bis[(2-mercaptophenyl)thio]ethane(2-)) formed by the reaction of the polymeric complex [Ru(PPh3)({\textquoteright}S-4{\textquoteright})](x) with liquid H2S at -70 degrees C; the reaction with H2S gas at room temperature in THF resulted in a mixture of the bridging sulfide complex [(mu-S-2){Ru(PPh3)({\textquoteright}S-4{\textquoteright})}(2)] and other uncharacterized products depicting the more typical reactivity of H2S with transition metal complexes.(2)},
	keywords = {ACTIVATION, hydride, HYDROGEN, LEWIS-ACIDS, MERCAPTO, REACTIVITY, S-H, sulfide, SULFUR-CONTAINING LIGANDS, TRANSITION-METAL COMPLEXES},
	isbn = {0020-1669},
	url = {<Go to ISI>://A1997YH56000003},
	author = {Mudalige, D. C. and Ma, E. S. and Rettig, S. J. and James, Brian R. and Cullen, W. R.}
}
