@article {2373,
	title = {Reactions of Two Cp*W(NO) Complexes with Heterocyclic Olefins},
	journal = {Organometallics},
	volume = {28},
	number = {4},
	year = {2009},
	note = {ISI Document Delivery No.: 408FHTimes Cited: 1Cited Reference Count: 15Buschhaus, Miriam S. A. Semiao, Christopher J. Legzdins, Peter},
	month = {Feb},
	pages = {1122-1126},
	type = {Article},
	abstract = {Cp*W(NO)(CH2CMe3)(2) (1) and Cp*W(NO)(CH2SiMe3)(eta(2)-CPhCH2) (2), two complexes which initiate the catalytic ring-retaining oligomerization of cyclic olefin substrates from cyclopentene to cyclooctene, have been reacted with analogous heteroatom-containing cyclic olefins under thermolytic conditions. These reactions with 2,5-dihydrofuran, 3,4-dihydro-2H-pyran, and 1,2,3,6-tetrahydropyridine do not result in the formation of oligomeric organic products but, rather, afford organometallic complexes resulting from alternate modes of substrate reactivity, such as ring-opening C-O bond cleavage and N-H activation.},
	keywords = {ACTIVATION, BONDS, TUNGSTEN},
	isbn = {0276-7333},
	url = {<Go to ISI>://000263420400026},
	author = {Buschhaus, M. S. A. and Semiao, C. J. and Legzdins,Peter}
}
@article {2626,
	title = {Synthesis and Coordination Chemistry of a Tridentate o-Phenylene-Bridged Diphosphine-NHC System},
	journal = {Organometallics},
	volume = {28},
	number = {9},
	year = {2009},
	note = {ISI Document Delivery No.: 441CETimes Cited: 8Cited Reference Count: 48Steinke, Tobias Shaw, Bryan K. Jong, Howard Patrick, Brian O. Fryzuk, Michael D.},
	month = {May},
	pages = {2830-2836},
	type = {Article},
	abstract = {The preparation of a di-o-phenylene-bridged tridentate PCP donor set is described starting with t-BOC-aniline followed by a series of steps that include lithiation, quenching with (Pr2PCl)-P-i, conversion to the phosphine sulfide, and assembling the unsaturated N-heterocyclic carbene unit. After desulfurization, the imidazolinium unit flanked by two phosphine units, represented as [(PCP)H]PF6 is obtained. Subsequent reaction with group 10 M(0) reagents (Ni(COD)(2), Pd(PPh3)(4), and Pt(PPh3)(4)) generates good yields of the Corresponding metal hydride complexes, [(PCP)MH]PF6 salts (where M = Ni(II), Pd(II), and Pt(II)). Each of these species has been characterized by elemental analyses, NMR spectroscopy, and X-ray crystallography. All of the structures show that the PCP unit is twisted with respect to the square plane of the d(8) metal complex.},
	keywords = {BIS(BENZIMIDAZOLIN-2-YLIDENE) PALLADIUM, BONDS, C COUPLING REACTIONS, COMPLEXES, H, HETEROCYCLIC CARBENE COMPLEXES, IMIDAZOLIUM SALTS, LIGANDS, OLEFIN METATHESIS, ONE-POT SYNTHESIS, ORGANOMETALLIC CATALYSIS, OXIDATIVE ADDITION},
	isbn = {0276-7333},
	url = {<Go to ISI>://000265746100022},
	author = {Steinke, T. and Shaw, B. K. and Jong, H. and Patrick, B. O. and Fryzuk,Michael D.}
}
@article {2030,
	title = {Direct observation of Markovian behavior of the mechanical unfolding of individual proteins},
	journal = {Biophysical Journal},
	volume = {95},
	number = {2},
	year = {2008},
	note = {ISI Document Delivery No.: 318WGTimes Cited: 8Cited Reference Count: 20Cao, Yi Kuske, Rachel Li, Hongbin},
	month = {Jul},
	pages = {782-788},
	type = {Article},
	abstract = {Single-molecule force-clamp spectroscopy is a valuable tool to analyze unfolding kinetics of proteins. Previous force-clamp spectroscopy experiments have demonstrated that the mechanical unfolding of ubiquitin deviates from the generally assumed Markovian behavior and involves the features of glassy dynamics. Here we use single molecule force-clamp spectroscopy to study the unfolding kinetics of a computationally designed fast-folding mutant of the small protein GB1, which shares a similar beta-grasp fold as ubiquitin. By treating the mechanical unfolding of polyproteins as the superposition of multiple identical Poisson processes, we developed a simple stochastic analysis approach to analyze the dwell time distribution of individual unfolding events in polyprotein unfolding trajectories. Our results unambiguously demonstrate that the mechanical unfolding of NuG2 fulfills all criteria of a memoryless Markovian process. This result, in contrast with the complex mechanical unfolding behaviors observed for ubiquitin, serves as a direct experimental demonstration of the Markovian behavior for the mechanical unfolding of a protein and reveals the complexity of the unfolding dynamics among structurally similar proteins. Furthermore, we extended our method into a robust and efficient pseudo-dwell-time analysis method, which allows one to make full use of all the unfolding events obtained in force-clamp experiments without categorizing the unfolding events. This method enabled us to measure the key parameters characterizing the mechanical unfolding energy landscape of NuG2 with improved precision. We anticipate that the methods demonstrated here will find broad applications in single-molecule force-clamp spectroscopy studies for a wide range of proteins.},
	keywords = {ADHESION, BONDS, FORCE-CLAMP SPECTROSCOPY, MICROSCOPE, REVEALS, SINGLE-MOLECULE, UBIQUITIN},
	isbn = {0006-3495},
	url = {<Go to ISI>://000257122900033},
	author = {Cao, Y. and Kuske, R. and Li, H. B.}
}
@article {2085,
	title = {Macromolecular complexation of poly(methylenephosphine) to gold(I): a facile route to highly metallated polymers},
	journal = {Chemical Communications},
	number = {18},
	year = {2008},
	note = {ISI Document Delivery No.: 294SLTimes Cited: 8Cited Reference Count: 38Gillon, Bronwyn H. Patrick, Brian O. Gates, Derek P.},
	month = {May},
	pages = {2161-2163},
	type = {Article},
	abstract = {Alternating phosphorus-carbon polymers are found to be effective ligands for gold( I) to afford [MesP( AuCl)-CPh2](n), a new class of macromolecule with high gold content.},
	keywords = {addition polymerization, AMBIENT-TEMPERATURE, ANIONIC-POLYMERIZATION, BONDS, conjugated polymers, COORDINATION POLYMER, COPOLYMERIZATION, LIGANDS, OLIGOMERS, PHOSPHAALKENE},
	isbn = {1359-7345},
	url = {<Go to ISI>://000255425800023},
	author = {Gillon, B. H. and Patrick, B. O. and Gates, D. P.}
}
@article {2088,
	title = {Reactivity of Cp*Mo(NO)(= CHCMe3) with olefins and dienes: C-H activation reactions of molybdenacyclobutanes},
	journal = {Organometallics},
	volume = {27},
	number = {12},
	year = {2008},
	note = {ISI Document Delivery No.: 312BHTimes Cited: 5Cited Reference Count: 30Graham, Peter A. Buschhaus, Miriam S. A. Pamplin, Craig B. Legzdins, Peter},
	month = {Jun},
	pages = {2840-2851},
	type = {Article},
	abstract = {Reactions of a variety of cyclic and acyclic olefins with the title alkylidene complex (formed spontaneously by loss of neopentane from Cp*Mo(NO)(CH2CMe3)(2) under ambient conditions) result in the initial formation of molybdenacyclobutane complexes (Cp* = C5Me5). These molybdenacyclobutane complexes do not react via olefin metathesis or cyclopropanation pathways, but instead via C-H activation. Thus, when cyclopentene is the olefinic substrate, the direct result of C-H activation at the beta-position of the metallacyclobutane affords a thermally stable allyl hydrido complex that can be isolated. Such an allyl hydride intermediate is not isolable for larger cyclic olefins (cyclohexene, cycloheptene, and cyclooctene) or acyclic olefins (allylbenzene and 1-hexene). Instead, those complexes react further, undergoing a second C-H activation at the allylic position to produce eta(4)-trans-diene complexes concomitant with the loss of dihydrogen. Upon heating, these eta(4)-trans-diene complexes liberate diene, thereby enabling the 14e Cp*Mo(NO) metal fragment to catalyze the oligomerization of cyclic olefins and dienes including cyclohexene and 1,4-cyclohexadiene. In the case of the acyclic olefin allylbenzene, the metal fragment catalyzes a dimerization to (E)-(4-methylpent-1-ene-1,5-diyl)dibenzene under ambient conditions.},
	keywords = {ALPHA-HYDROGEN ABSTRACTION, BONDS, COMPLEXES, CRYSTAL-STRUCTURES, CYCLOHEXENE, METATHESIS, MOLYBDENUM, NEOPENTYLIDENE, OLIGOMERIZATION, TUNGSTEN},
	isbn = {0276-7333},
	url = {<Go to ISI>://000256643600023},
	author = {Graham, P. A. and Buschhaus, M. S. A. and Pamplin, C. B. and Legzdins,Peter}
}
@article {1406,
	title = {Intramolecular C-H activation reactions of molybdenacyclobutanes},
	journal = {Journal of the American Chemical Society},
	volume = {128},
	number = {28},
	year = {2006},
	note = {ISI Document Delivery No.: 062VITimes Cited: 4Cited Reference Count: 7Graham, Peter M. Buschhaus, Miriam S. A. Legzdins, Peter},
	month = {Jul},
	pages = {9038-9039},
	type = {Article},
	keywords = {BONDS, COMPLEXES, METATHESIS},
	isbn = {0002-7863},
	url = {<Go to ISI>://000238972900025},
	author = {Graham, P. M. and Buschhaus, M. S. A. and Legzdins,Peter}
}
@article {1253,
	title = {Activation and cleavage of alkynes by the dinuclear tantalum complexes ([NPN]Ta)(2)(mu-H)(4) and ([NPN]Ta)(2)(mu-eta(1):eta(2)-N-2)(mu-H)(2) (where NPN = PhP(CH2SiMe2NPh)(2))},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {83},
	number = {6-7},
	year = {2005},
	note = {ISI Document Delivery No.: 963UVTimes Cited: 4Cited Reference Count: 29},
	month = {Jun},
	pages = {652-660},
	type = {Article},
	abstract = {Reaction of phenylacetylene with the dinuclear tetrahydride complex ([NPN]Ta)(2)(mu-H)(4) gives the product ([NPN]Ta)(2)(mu-PhCCH)(mu-H)(2) (where NPN is PhP(CH2SiMe2NPh)(2)). Activation of other terminal alkynes by ([NPN]Ta)(2)(mu-H)(4) accesses ([NPN]Ta)(2)(mu-RCCH)(mu-H)(2) (R = n-Pr, t-Bu). Crystallographic analysis of the R = Ph derivative showed it to be a bis(mu-alkylidene) bound asymmetrically to the two tantalum centres. Storage of solutions of ([NPN]Ta)(2)(mu-PhCCH)(mu-H)(2) under vacuum promotes the loss of H-2 and cleavage of the C-C bond to give a bis(mu-alkylidyne) complex, ([NPN]Ta)(2)(mu-CPh)(mu-CH). Addition of diphenylacetylene did not give the desired ([NPN]Ta)(2)(mu-CPh)(2), but rather promotes a complex decomposition of the supporting [NPN] ligands. Reaction of phenylacetylene with the dinitrogen complex ([NPN]Ta)(2)(mu-eta(1):eta(2)-N-2)(mu-H)(2) results in the dissociation of the bound dinitrogen and the formation of ([NPN]Ta)(2)(mu-PhCCH)(mu-H)(2), which is identical to that derived from the reaction with the dinuclear tetrahydride.},
	keywords = {activation of small molecules, alkylidene, alkylidyne, ALKYLIDYNE COMPLEXES, ALKYNE, amidodiphosphine, BONDS, DIAMIDOPHOSPHINE COMPLEXES, DINITROGEN CLEAVAGE, DINUCLEAR, END-ON, FUNCTIONALIZATION, hydride dinitrogen, LIGAND, N-2, NIOBIUM(III), SIDE-ON, tantalum},
	isbn = {0008-4042},
	url = {<Go to ISI>://000231832500020},
	author = {Shaver, M. P. and Johnson, S. A. and Fryzuk,Michael D.}
}
@article {1105,
	title = {Characterization of a rhodium(III)-imine-orthometalated imine complex: Reversible C-H activation of a coordinated imine},
	journal = {Organometallics},
	volume = {24},
	number = {15},
	year = {2005},
	note = {ISI Document Delivery No.: 945IGTimes Cited: 13Cited Reference Count: 40},
	month = {Jul},
	pages = {3753-3757},
	type = {Article},
	abstract = {Solutions of cis-[Rh(PPh3)(2)(solv)(2)]PF6 (solv = acetone or MeOH) react at room temperature under Ar with benzophenone imine to yield cis- [Rh(PPh3)(2)(eta(1)-NH=CPh2)(2)]PF6 (3), but depending on reaction conditions, one of the imine ligands undergoes orthometalation to give [RhH{NH=C(Ph)(o-C6H4)}(HN=CPh2)(PPh3)(2)]PF6 (2) with trans-phosphines; this is the first recorded complex containing an imine in its eta(1)-form and as an eta(2)-moiety formed via orthometalation. Complexes 2 and 3 are characterized by elemental analysis, H-1 and P-31-{H-1} NMR spectroscopy, and, in the case of 2, an X-ray crystal structure.},
	keywords = {BEHAVIOR, BONDS, CATIONIC COMPLEXES, COMPLEXES, HYDROGENATION, METAL-COMPLEXES, OXIDATIVE ADDITION, RHODIUM(III), semicarbazones, TERDENTATE NITROGEN LIGANDS, UNIT},
	isbn = {0276-7333},
	url = {<Go to ISI>://000230495600021},
	author = {Ezhova, M. B. and Patrick, B. O. and James, Brian R.}
}
@article {618,
	title = {Hydrosilylation of a dinuclear tantalum dinitrogen complex: Cleavage of N-2 and functionalization of both nitrogen atoms},
	journal = {Journal of the American Chemical Society},
	volume = {125},
	number = {11},
	year = {2003},
	note = {ISI Document Delivery No.: 655MFTimes Cited: 54Cited Reference Count: 20},
	month = {Mar},
	pages = {3234-3235},
	type = {Article},
	keywords = {BONDS, CHEMISTRY, COORDINATED DINITROGEN, END-ON, FIXATION, LIGAND, REACTIVITY, REDUCTION, SIDE-ON, SILANES},
	isbn = {0002-7863},
	url = {<Go to ISI>://000181555600022},
	author = {Fryzuk,Michael D. and MacKay, B. A. and Patrick, B. O.}
}
@article {395,
	title = {(eta(5)-cyclopentadienyl)(p-fluorophenoxo)(nitrosyl)(trimethylsilyl- methyl)molybdenum(II)},
	journal = {Acta Crystallographica Section C-Crystal Structure Communications},
	volume = {58},
	year = {2002},
	note = {ISI Document Delivery No.: 520RZTimes Cited: 1Cited Reference Count: 11Part 2},
	month = {Feb},
	pages = {m68-m69},
	type = {Article},
	abstract = {The title complex, [Mo(C5H5)(C6H4FO)(C4H11Si)(NO)], is formed by reacting CpMo(NO)(CH2SiMe3)(2), where Cp is cyclopentadienyl, with one equivalent of p-FC6H4OH. The complex exhibits the expected piano-stool molecular structure, with a linear nitrosyl ligand [Mo-N-O 168.2 (2)degrees] having Mo-N and N-O distances of 1.764 (2) and 1.207 (3) Angstrom, respectively. The phenoxo Mo-O distance of 1.945 (2) Angstrom is suggestive of some multiple-bond character.},
	keywords = {BONDS, COMPLEXES, FRAGMENT, REACTIVITY},
	isbn = {0108-2701},
	url = {<Go to ISI>://000173796300004},
	author = {Hayton, T. W. and Legzdins,Peter and Rettig, S. J.}
}
@article {4651,
	title = {Dimeric rhodium mu-silylene and mu-eta(2)-silyl complexes: Catalytic silicon-silicon bond formation and x-ray structures of [{Pr(i)(2)PCH2CH2PPr(i)(2)}Rh](2)(mu-SiRR {\textquoteright})(2) (R = R {\textquoteright} = Ph and R = Me, R {\textquoteright} = Ph) and [{Pr(i)(2)PCH2CH2PPr(i)(2)}Rh(H)](2)(},
	journal = {Organometallics},
	volume = {18},
	number = {6},
	year = {1999},
	note = {ISI Document Delivery No.: 178FRTimes Cited: 29Cited Reference Count: 32},
	month = {Mar},
	pages = {958-969},
	type = {Article},
	abstract = {The stoichiometric and catalytic reactions of secondary silanes with the rhodium hydride bridged dimer [(dippe)Rh](2)(mu-H)(2) (1; dippe = 1,2-bis(diisopropylphosphino)ethane) are described. The reaction of 1 with Ph2SiH2 results in the formation of the bis(mu-silylene) complex [(dippe)Rh](2)(mu-SiPh2)(2) (2a); a similar reaction ensues upon addition of MePhSiH2 or Me(p)TolSiH(2) ((P)Tol =p-tolyl) to 1 except that the bis(silylene) complexes exist as a mixture of cis and trans stereoisomers. Dimethylsilane reacts with 1 to generate the dinuclear complex [(dippe)Rh(H)](2)(mu-eta(2)-SiMe2)(2) (4d). The hydride dimer acts as a catalyst precursor for the dimerization of excess Ph2SiH2 to tetraphenyldisilane (Ph2SiHSiHPh2). A catalytic cycle is proposed that consists of dinuclear intermediates.},
	keywords = {BONDS, hydride complexes, HYDROSILYLATION, REACTIVITY, SECONDARY SILANES, SI, TRANSITION-METAL COMPLEXES},
	isbn = {0276-7333},
	url = {<Go to ISI>://000079256000005},
	author = {Rosenberg, L. and Fryzuk,Michael D. and Rettig, S. J.}
}
@article {3296,
	title = {FACILE THERMAL REACTIVITY OF CP-ASTERISK-W(NO)(CH(2)SIME(3)) (CPH=CH2) - UNIQUE ALKANE C-H ACTIVATION UNDER MILD CONDITIONS},
	journal = {Journal of the American Chemical Society},
	volume = {117},
	number = {11},
	year = {1995},
	note = {ISI Document Delivery No.: QN458Times Cited: 18Cited Reference Count: 16},
	month = {Mar},
	pages = {3288-3289},
	type = {Note},
	keywords = {ALKYL, BONDS, COMPLEXES, CRYSTAL, DEHYDROGENATION, LIGAND},
	isbn = {0002-7863},
	url = {<Go to ISI>://A1995QN45800040},
	author = {Debad, J. D. and Legzdins,Peter and Lumb, S. A. and Batchelor, R. J. and Einstein, F. W. B.}
}
@article {3290,
	title = {THE REACTION OF PHSR(R=FC OR PH) WITH RU-3(CO)(12)},
	journal = {Polyhedron},
	volume = {14},
	number = {19},
	year = {1995},
	note = {ISI Document Delivery No.: RU147Times Cited: 6Cited Reference Count: 28},
	month = {Sep},
	pages = {2653-2661},
	type = {Article},
	abstract = {{The reaction of SPh(2) with Ru-3(CO)(12) affords (mu-SR)(mu-eta(1); eta(6)-C6H5)Ru-3(CO)(8) (Ru-Ru)},
	keywords = {BONDS, CLEAVAGE, CLUSTERS, COMPLEXES, NUCLEARITY, PHENYL, SULFIDES, TRICARBONYL},
	isbn = {0277-5387},
	url = {<Go to ISI>://A1995RU14700008},
	author = {Cullen, W. R. and Rettig, S. J. and Zheng, T. C.}
}
@article {7250,
	title = {THE PASSIVATION OF GALLIUM-ARSENIDE SURFACES WITH ATOMIC SULFUR},
	journal = {Journal of Applied Physics},
	volume = {72},
	number = {2},
	year = {1992},
	note = {ISI Document Delivery No.: JD971Times Cited: 19Cited Reference Count: 23},
	month = {Jul},
	pages = {762-765},
	type = {Article},
	abstract = {A new technique for bonding sulfur atoms to gallium arsenide surfaces is described. In this technique the surface is exposed to gas-phase atomic sulfur at 60-70-degrees-C. The resulting surfaces were characterized by angle-dependent x-ray photoelectron spectroscopy. The data show that, in contrast to passivation of GaAs by H2S at low temperatures, this technique yields a surface on which the sulfur is almost exclusively bonded only to gallium atoms.},
	keywords = {BONDS, CHEMICAL PASSIVATION, ELECTRONIC-PROPERTIES, GAAS-SURFACES},
	isbn = {0021-8979},
	url = {<Go to ISI>://A1992JD97100063},
	author = {Gu, G. Y. and Ogryzlo, E. A. and Wong, P. C. and Zhou, M. Y. and Mitchell, K. A. R.}
}
@article {7017,
	title = {BINUCLEAR PALLADIUM COMPLEXES WITH BRIDGING HYDRIDES - UNUSUAL COORDINATION BEHAVIOR OF LIBET4},
	journal = {Journal of the American Chemical Society},
	volume = {113},
	number = {11},
	year = {1991},
	note = {ISI Document Delivery No.: FN005Times Cited: 29Cited Reference Count: 22},
	month = {May},
	pages = {4332-4334},
	type = {Note},
	keywords = {BONDS, CENTERS, NICKEL, platinum, RHODIUM HYDRIDES},
	isbn = {0002-7863},
	url = {<Go to ISI>://A1991FN00500047},
	author = {Fryzuk,Michael D. and Lloyd, B. R. and Clentsmith, G. K. B. and Rettig, S. J.}
}
@article {7020,
	title = {REACTIONS OF SILANES WITH THE BINUCLEAR HYDRIDE [(PR(I)2PCH2CH2PPR(I)2)RH]2(MU-H)2 - CATALYTIC DEUTERIUM-EXCHANGE ON DIPHENYLSILANE AND X-RAY STRUCTURE OF [(PR(I)2PCH2CH2PPR(I)2)RH]2(MU-H)(MU-ETA-2-HSIPH2)},
	journal = {Organometallics},
	volume = {10},
	number = {8},
	year = {1991},
	note = {ISI Document Delivery No.: GA275Times Cited: 45Cited Reference Count: 25},
	month = {Aug},
	pages = {2537-2539},
	type = {Note},
	abstract = {Stoichiometric reactions of diphenylsilane (H2SiPh2) with [(dippe)Rh]2(mu-H)2 (1; dippe = 1,2-bis(diisopropylphosphino)ethane) have produced the new compounds [(dippe)Rh]2(mu-H)(mu-eta-2-HSiPh2) (2) and [(dippe)-Rh]2(mu-SiPh2)2 (3). An X-ray structure determination of 2 indicates the presence of a three-center, two-electron Rh-Si-H interaction. Deuterium exchange and silicon-silicon coupling to give 1,1,2,2-tetraphenyldisilane are both observed for diphenylsilane in the presence of catalytic amounts of 1; the isolated silyl-dihydride complex 2 and the bis(silylene) derivative 3 are likely to be active in these catalytic cycles.},
	keywords = {BONDS, CRYSTAL, HYDROSILATION, MOLECULAR-STRUCTURE, MU-SILYLENE COMPLEXES, POLYMERIZATION, PRIMARY ORGANOSILANES, SI, SILICON},
	isbn = {0276-7333},
	url = {<Go to ISI>://A1991GA27500005},
	author = {Fryzuk,Michael D. and Rosenberg, L. and Rettig, S. J.}
}
