@article {2259,
	title = {Rare-earth amidate complexes. Easily accessed initiators for epsilon-caprolactone ring-opening polymerization},
	journal = {Inorganic Chemistry},
	volume = {47},
	number = {18},
	year = {2008},
	note = {ISI Document Delivery No.: 346UBTimes Cited: 8Cited Reference Count: 76Stanlake, Louisa J. E. Beard, J. David Schafer, Laurel L.},
	month = {Sep},
	pages = {8062-8068},
	type = {Article},
	abstract = {{The direct synthesis of yttrium amidate complexes using the simple reaction of amide proligands and Y(N(SiMe3)(2))(3) results in the high-yielding preparation and isolation of crystalline, monomeric materials. The complex, tris(N-2{\textquoteright},6{\textquoteright}-diisopropylphenyl(naphthyl)amidate)yttrium mono(tetrahydrofuran) (4), was structurally determined to be a 7-coordinate C, symmetric structure, maintaining one bound tetrahydrofuran molecule. Compound 4 (C12H17[NCO]C10H1)(3)Y(C4H8O) crystallized in the monoclinic space group P2(1)/c with a = 13.7820(11) angstrom},
	keywords = {BETA-DIKETIMINATE, BIS(AMIDATE) TITANIUM PRECATALYST, CATALYTIC-ACTIVITY, COMPLEXES, LANTHANIDE, METHYL-METHACRYLATE, MOLECULAR-STRUCTURES, N, ORGANOLANTHANIDE, PHENYL ISOCYANATE, RAY CRYSTAL-STRUCTURES, SIGMA-BOND},
	isbn = {0020-1669},
	url = {<Go to ISI>://000259093700022},
	author = {Stanlake, L. J. E. and Beard, J. D. and Schafer, L. L.}
}
@article {933,
	title = {Dinitrogen coordination chemistry: On the biomimetic borderlands},
	journal = {Chemical Reviews},
	volume = {104},
	number = {2},
	year = {2004},
	note = {ISI Document Delivery No.: 773QMTimes Cited: 189Cited Reference Count: 177},
	month = {Feb},
	pages = {385-401},
	type = {Review},
	keywords = {BRIDGING N-2 UNIT, DIPORPHYRIN, ELECTRONIC-STRUCTURE, END-ON, IRON-MOLYBDENUM COFACTOR, NITROGENASE FEMO-COFACTOR, RAY CRYSTAL-STRUCTURES, REDUCTIVE CLEAVAGE, RUTHENIUM COFACIAL, TRANSITION-METAL-COMPLEXES, VANADIUM DIAMIDOAMINE COMPLEX},
	isbn = {0009-2665},
	url = {<Go to ISI>://000188934400003},
	author = {MacKay, B. A. and Fryzuk,Michael D.}
}
@article {339,
	title = {Crystallographic characterization of the palladium(I) dimers, syn-Pd2Cl2(dppmMe)(2) and Pd2Cl2(dpPM)(2); solution conformational behavior of syn- and anti-Pd2Cl2(dppmMe)(2) and their (mu-Se) adducts [dppmMe = mu-1,1-bis(diphenylphosphino)ethane, and dppm},
	journal = {Inorganica Chimica Acta},
	volume = {327},
	year = {2002},
	note = {ISI Document Delivery No.: 509WATimes Cited: 16Cited Reference Count: 51},
	month = {Jan},
	pages = {179-187},
	type = {Article},
	abstract = {An X-ray diffraction study on syn-Pd2Cl2(dppmMe)(2), syn-1, shows an unusual boat-like conformation of the eight-membered Pd2P4C2 ring. This conformation, containing equatorial Me groups, facilitates access of the Pd-Pd bond to small molecules such as CO, SO2, and elemental sulfur or selenium, and makes the syn isomer more reactive than anti-1. A comparison of bond angles around the Pd and P atoms in the syn- and anti-isomers reveals a more strained geometry of the former, which may also contribute to the stronger propensity of syn-1 to form A-frame adducts. Solution NMR/NOE studies on syn- and anti-1 and their (mu-Se) adducts reveal the structural rigidity of these complexes; the Me groups inhibit the interchange of axial and equatorial positions on the bridging methine C-atom, and solution structures correspond to those in the solid state. The X-ray structure of Pd2Cl2(dppm)(2) is, as expected, like that of the corresponding bromo, complex; both are analogous to that of anti-1 which adopts a chair conformation within both the fused, five-membered rings. (C) 2002 Elsevier Science B.V.. All rights reserved.},
	keywords = {1, 1-bis(diphenylphosphino)ethane, Aa-frame complexes, bis(diphenylphosphino)methane, BIS(DIPHENYLPHOSPHINO)METHANE LIGANDS, BRIDGING, CARBON-MONOXIDE, COMPLEXES, DINUCLEAR PALLADIUM(I), METAL-METAL BONDS, MOLECULAR-STRUCTURE, palladium complexes, PLATINUM(I), RAY CRYSTAL-STRUCTURES, SELENIDE, selenium compounds},
	isbn = {0020-1693},
	url = {<Go to ISI>://000173171700020},
	author = {Besenyei, G. and Parkanyi, L. and Gacs-Baitz, E. and James, Brian R.}
}
@article {392,
	title = {Synthesis, characterization, and solution redox properties of (trimpsi)M(CO)(2)(NO) complexes [M = V, Nb, Ta; trimpsi = (BuSi)-Bu-t(CH2PMe2)(3)]},
	journal = {Inorganic Chemistry},
	volume = {41},
	number = {16},
	year = {2002},
	note = {ISI Document Delivery No.: 582RTTimes Cited: 7Cited Reference Count: 85},
	month = {Aug},
	pages = {4114-4126},
	type = {Article},
	abstract = {{Treatment of [Et4N][M(CO)(6)] (M = Nb, Ta) with I-2 in DME at -78 degreesC produces solutions of the bimetallic anions [M-2(mu-l)(3)(CO)(8)](-). Addition of the tripodal phosphine (BuSi)-Bu-t(CH2PMe2)(3) (trimpsi) followed by refluxing affords (trimpsi)M(CO)(3)I [M = Nb (1), Ta (2)], which are isolable in good yields as air-stable, orange-red microcrystalline solids. Reduction of these complexes with 2 equiv of Na/Hg, followed by treatment with Diazald in THF, results in the formation of (trimpsi)M(CO)(2)(NO) [M = Nb (3), Ta (4)] in high isolated yields. The congeneric vanadium complex, (trimpsi)V(CO)(2)(NO) (5), can be prepared by reacting [Et4N][V(CO)(6)] with [NO][BF4] in CH2Cl2 to form V(CO)(5)(NO). These solutions are treated with 1 equiv of trimpsi to obtain (eta(2)-trimpsi)V(CO)(3)(NO). Refluxing orange THF solutions of this material affords 5 in moderate yields. Reaction of (trimpsi)VCl3(THF) (6) with 4 equiv of sodium naphthalenide in THF in the presence of excess CO provides [Et4N][(trimpsi)V(CO)(3)] (7), (trimpsi)V(CO)(3)H, and [(trimpsi)V(mu-Cl)(3)V(trimpsi)][(eta(2)-trimpsi)V(CO)(4)].3THF ([8][9].3THF). All new complexes have been characterized by conventional spectroscopic methods, and the solid-state molecular structures of 2.(1)/2THF, 3-5, and [8][9].3THF have been established by X-ray diffraction analyses. The solution redox properties of 3-5 have also been investigated by cyclic voltammetry. Cyclic voltammograms of 3 and 4 both exhibit an irreversible oxidation feature in CH2Cl2 (E-p},
	keywords = {CHARACTERIZATION, CHEMISTRY, DERIVATIVES, HIGHLY REDUCED ORGANOMETALLICS, ISOCYANIDE COMPLEXES, NITRIC-OXIDE, PHOSPHINE COMPLEXES, RAY CRYSTAL-STRUCTURES, SPECTROSCOPIC, tantalum, VANADIUM(II)},
	isbn = {0020-1669},
	url = {<Go to ISI>://000177365500013},
	author = {Hayton, T. W. and Daff, P. J. and Legzdins,Peter and Rettig, S. J. and Patrick, B. O.}
}
@article {4809,
	title = {The continuing story of dinitrogen activation},
	journal = {Coordination Chemistry Reviews},
	volume = {200},
	year = {2000},
	note = {ISI Document Delivery No.: 345HCTimes Cited: 235Cited Reference Count: 121},
	month = {May},
	pages = {379-409},
	type = {Review},
	abstract = {This review attempts to survey the recent literature concerning the coordination chemistry and the reactivity patterns of metal-dinitrogen complexes. In order that this work may stand alone, a certain amount of background information is included; however, the emphasis is on synthesis and reactivity patterns of recently discovered dinitrogen complexes. In addition, some effort is made to discuss new trends in dinitrogen chemistry as well as to point out underdeveloped topics in this area. (C) 2000 Elsevier Science S.A. All rights reserved.},
	keywords = {(1-PYRIDINIO)IMIDO, 3-COORDINATE MOLYBDENUM(III) COMPLEXES, BRIDGING N-2 UNIT, COMPLEXES, COORDINATED DINITROGEN, DINITROGEN, metal complexes, MOLECULAR, N BOND-CLEAVAGE, NITROGEN, nitrogen fixation, nitrogenase, RAY CRYSTAL-STRUCTURES, SIDE-ON, TO-END ROTATION, TRIAMIDOAMINE COMPLEXES},
	isbn = {0010-8545},
	url = {<Go to ISI>://000088809700013},
	author = {Fryzuk,Michael D. and Johnson, S. A.}
}
@article {2773,
	title = {PREPARATION AND CHARACTERIZATION OF THE OSMIUM CLUSTER COMPLEXES H2OS3(CO)8L(ETFCPCME) (L=CO OR PET2FC) AND H2OS3(CO)8[(ETA-C5H3PET2)FE(ETA-C5H4)]},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {71},
	number = {3},
	year = {1993},
	note = {ISI Document Delivery No.: KU982Times Cited: 4Cited Reference Count: 35},
	month = {Mar},
	pages = {399-409},
	type = {Article},
	abstract = {{Thermolysis of Os3(CO)11](PEt2Fc) (Fc = (eta-C5H4)Fe(eta-C5H5)) in octane for 8 h affords H2Os3(CO)9(EtFcPCMe), 10, and H2Os3(CO)8[(eta-C5H3PEt2)Fe(eta-C5H4)], 9e, in 15 and 65\% yield, respectively. Heating Os3(CO),2 and PEt2Fc in 1:2 molar ratio in xylene for 10 h gives two isomers of H2Os3(CO)8(PEt2Fc)(EtFcPCMe), 11, in about 40\% yield. Two crystalline modifications of the complex 9e have been obtained from the same solvent: 9eA, triclinic},
	keywords = {BENZYNE, BOND, CHEMISTRY, COMPOUND, COORDINATION, LIGANDS, MODE, RAY CRYSTAL-STRUCTURES, REACTIVITY, TRIOSMIUM CLUSTERS},
	isbn = {0008-4042},
	url = {<Go to ISI>://A1993KU98200020},
	author = {Cullen, W. R. and Rettig, S. J. and Zheng, T. C.}
}
@article {7269,
	title = {HYDRIDO MERCAPTO AND BIS(MERCAPTO) DERIVATIVES OF RUTHENIUM(II) PHOSPHINE COMPLEXES},
	journal = {Inorganic Chemistry},
	volume = {31},
	number = {22},
	year = {1992},
	note = {ISI Document Delivery No.: JV836Times Cited: 27Cited Reference Count: 42},
	month = {Oct},
	pages = {4601-4605},
	type = {Article},
	abstract = {{The complex cct-Ru(SH)2(CO)2(PPh3)2 (1), synthesized by treating THF solutions of RU(CO)2(PPh3)3 or cct-Ru(H)2(CO)2(PPh3)2 With H2S, crystallizes in the space group P1BAR (No. 2), with a = 10.3030 (6) angstrom},
	keywords = {bis(diphenylphosphino)methane, CHEMISTRY, ELECTROCHEMICAL PARAMETRIZATION, H2S, HYDROGEN-SULFIDE, LIGANDS, MOLECULAR-STRUCTURE, RAY CRYSTAL-STRUCTURES, SULFUR},
	isbn = {0020-1669},
	url = {<Go to ISI>://A1992JV83600030},
	author = {Jessop, P. G. and Lee, C. L. and Rastar, G. and James, Brian R. and Lock, C. J. L. and Faggiani, R.}
}
