@article {639,
	title = {N-bromosuccinimide promoted ring expansion reactions: Diastereoselective formation of functionalized azaspirocyclic cyclopentanones},
	journal = {Synlett},
	number = {14},
	year = {2003},
	note = {ISI Document Delivery No.: 741GTTimes Cited: 10Cited Reference Count: 30},
	month = {Nov},
	pages = {2131-2134},
	type = {Article},
	abstract = {N-Bromosuccinimide (NBS) induces ring enlargements of 2-(1-hydroxycyclobutyl)-p-toluenesulfonylenamides such as 1. These high yielding reactions typically occur with good diastereoselectivity. This ring expansion protocol under neutral conditions forms compounds that are potentially versatile intermediates for the construction of spirocycle-containing alkaloids.},
	keywords = {bromine, CONSTRUCTION, entry, HALICHLORINE, ION, KETONES, PINNAIC ACID, piperidines, REDUCTION, ring expansion, spiro compounds, SPIROCYCLIC CORE, STEREOSELECTIVE},
	isbn = {0936-5214},
	url = {<Go to ISI>://000186450900005},
	author = {Hurley, P. B. and Dake, G. R.}
}
@article {358,
	title = {Formation of ruthenium(II)-bis(phosphine) monoxide complexes from the bis(phosphine) precursors: BINAP-monoxide (BINAPO) as a six-electron (P,O,eta(2)-naphthyl) donor},
	journal = {Organometallics},
	volume = {21},
	number = {22},
	year = {2002},
	note = {ISI Document Delivery No.: 607EFTimes Cited: 31Cited Reference Count: 105},
	month = {Oct},
	pages = {4672-4679},
	type = {Review},
	abstract = {{Aerobic oxidation of one P atom in cis-RuCl2(P-P)(L-2) complexes (P-P = (R)-BINAP (2,2{\textquoteright}-bis(diphenylphosphino)-1,1{\textquoteright}-binaphthyl) or dppb (1,4-bis(diphenylphosphino)butane)},
	keywords = {ASYMMETRIC HYDROGENATION, CATALYTIC ENANTIOSELECTIVE, CHIRAL RUTHENIUM(II) CATALYSTS, COORDINATION CHEMISTRY, DIELS-ALDER REACTIONS, HYDROGENATION, MEO-BIPHEP, P-C BOND, PHOSPHINE OXIDE LIGANDS, STEREOSELECTIVE, X-RAY},
	isbn = {0276-7333},
	url = {<Go to ISI>://000178778100015},
	author = {Cyr, P. W. and Rettig, S. J. and Patrick, B. O. and James, Brian R.}
}
@article {4003,
	title = {Stereoselective hydrogenation of lignin degradation model compounds},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {75},
	number = {9},
	year = {1997},
	note = {ISI Document Delivery No.: YE063Times Cited: 20Cited Reference Count: 29},
	month = {Sep},
	pages = {1234-1239},
	type = {Article},
	abstract = {Di-mu-chloro-bis(eta(4)-1,5-hexadiene)dirhodium(I) in a two-phase hexane-aqueous medium catalyzes the diastereoselective H-2-hydrogenation of lignin degradation model compounds 4-propylphenol, 2-methoxy-3-propylphenol, and 2,6-dimethoxy-3-propylphenol. The all-cis diastereomer is obtained selectively when the phenolic hydroxy group is protected as a methyl ether or when a model compound possessing two methoxy substituents adjacent to the phenolic hydroxy group is used. The relative stereochemistries of the hydrogenated products are established by X-ray crystal structure analysis and (or) H-1 NMR.},
	keywords = {catalytic hydrogenation, CATALYTIC-HYDROGENATION, COMPOUNDS, diastereomer, lignin degradation model, STEREOSELECTIVE, X-ray crystal structure},
	isbn = {0008-4042},
	url = {<Go to ISI>://A1997YE06300011},
	author = {Hu, Thomas Q. and James, Brian R. and Rettig, S. J. and Lee, C. L.}
}
@article {4003,
	title = {Stereoselective hydrogenation of lignin degradation model compounds},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {75},
	number = {9},
	year = {1997},
	note = {ISI Document Delivery No.: YE063Times Cited: 20Cited Reference Count: 29},
	month = {Sep},
	pages = {1234-1239},
	type = {Article},
	abstract = {Di-mu-chloro-bis(eta(4)-1,5-hexadiene)dirhodium(I) in a two-phase hexane-aqueous medium catalyzes the diastereoselective H-2-hydrogenation of lignin degradation model compounds 4-propylphenol, 2-methoxy-3-propylphenol, and 2,6-dimethoxy-3-propylphenol. The all-cis diastereomer is obtained selectively when the phenolic hydroxy group is protected as a methyl ether or when a model compound possessing two methoxy substituents adjacent to the phenolic hydroxy group is used. The relative stereochemistries of the hydrogenated products are established by X-ray crystal structure analysis and (or) H-1 NMR.},
	keywords = {catalytic hydrogenation, CATALYTIC-HYDROGENATION, COMPOUNDS, diastereomer, lignin degradation model, STEREOSELECTIVE, X-ray crystal structure},
	isbn = {0008-4042},
	url = {<Go to ISI>://A1997YE06300011},
	author = {Hu, Thomas Q. and James, Brian R. and Rettig, S. J. and Lee, C. L.}
}
@article {7018,
	title = {SYNTHESIS AND REACTIVITY OF RUTHENIUM AMIDE PHOSPHINE COMPLEXES - FACILE CONVERSION OF A RUTHENIUM AMIDE TO A RUTHENIUM AMINE VIA DIHYDROGEN ACTIVATION AND ORTHO METALATION - X-RAY STRUCTURE OF RUCL(C6H4PPH2)[NH(SIME2CH2PPH2)2]},
	journal = {Organometallics},
	volume = {10},
	number = {2},
	year = {1991},
	note = {ISI Document Delivery No.: EY681Times Cited: 68Cited Reference Count: 38},
	month = {Feb},
	pages = {467-473},
	type = {Article},
	abstract = {{The reaction of LiN(SiMe2CH2PPh2)2 with RuCl2(PPh3)3 leads to the formation of the ruthenium amide complex RuCl(PPh3)[N(SiMe2CH2PPh2)2]. This complex reacts with H2 to form two isomeric amine-hydride derivatives of the formula RuCl(PPh3)H[NH(SiMe2CH2PPh2)2]. Reaction of RuCl(PPh3)[N-(SiMe2CH2PPh2)2] with MeLi, Me3SiCH2Li, or H2C = CHCH2MgCl does not lead to the expected hydrocarbyl derivative; rather, ortho metalation occurs to generate Ru(C6H4PPh2)[N(SiMe2CH2PPh2)2]. Attempts to displace the PPh3 ligand of RuCl(PPh3)[N(SiMe2CH2PPh2)2] with PEt3 lead to the formation of RuCl(C6H4PPh2)[NH(SiMe2PPh2)2], having an amine ligand and the ortho-metalated phenyl group. The complex RuCl(C6H4PPh2)[NH(SiMe2CH2PPh2)2] crystallizes in space group P2(1)/n with a = 9.8385 (5) angstrom},
	keywords = {5-COORDINATE D6 COMPLEXES, CARBONYL-COMPLEXES, CRYSTAL, formation, HYDROGEN, IRIDIUM, MOLECULAR-STRUCTURE, STEREOSELECTIVE},
	isbn = {0276-7333},
	url = {<Go to ISI>://A1991EY68100025},
	author = {Fryzuk,Michael D. and Montgomery, C. D. and Rettig, S. J.}
}
