@article {7039, title = {SYNTHESIS AND CHARACTERIZATION OF DIHALOGENORUTHENIUM(IV)-TETRAPHENYLPORPHYRIN, DIPHENYLRUTHENIUM(IV)-TETRAPHENYLPORPHYRIN, AND PHENYLRUTHENIUM(III)-TETRAPHENYLPORPHYRIN COMPLEXES, INCLUDING THE CRYSTAL-STRUCTURE OF RU(TPP)BR2}, journal = {Inorganic Chemistry}, volume = {30}, number = {25}, year = {1991}, note = {ISI Document Delivery No.: GT938Times Cited: 40Cited Reference Count: 94}, month = {Dec}, pages = {4766-4771}, type = {Article}, abstract = {{The paramagnetic (S = 1) Ru(TPP)X2 complexes (X = halide) are made by treatment of [Ru(TPP)]2 with HBr, HCl, or I2 (TPP = the dianion of 5,10,15,20-tetraphenylporphyrin). The dibromo species (2) crystallizes in the tetragonal system, space group C4h5-I4/m, with a = 13.686 (9) angstrom}, keywords = {CARBONYL-COMPLEXES, DIOXYGEN INSERTION, IRON(II) PORPHYRINS, MOLECULAR-STRUCTURES, NUCLEAR MAGNETIC-RESONANCE, OXO COMPLEXES, PORPHYRIN COMPLEXES, redox properties, RUTHENIUM PORPHYRIN, Schiff-base}, isbn = {0020-1669}, url = {://A1991GT93800017}, author = {Ke, M. and Sishta, C. and James, Brian R. and Dolphin, D. and Sparapany, J. W. and Ibers, J. A.} }