@article {2610,
	title = {HL2[P(1,2-O(2)C(6)H4)(3)] (L = DMSO or DMF): A Convenient Proton Source with a Weakly Basic Phosphorus(V) Anion},
	journal = {Organometallics},
	volume = {28},
	number = {15},
	year = {2009},
	note = {ISI Document Delivery No.: 476PYTimes Cited: 0Cited Reference Count: 114Siu, Paul W. Gates, Derek P.},
	month = {Aug},
	pages = {4491-4499},
	type = {Review},
	abstract = {Treating phosphorus pentachloride with catechol (3 equiv) followed by the addition of dimethylsulfoxide (DMSO) or dimethylformamide (DMF) affords isolable bronsted acids of tris- (o-phenylenedioxy)phosphate anion, [p(1,2-O2C6H4)(3)](-). Specifically. H(DMSO)(2)[P(1,2-O2C6H4)(3)] and H(DMF)(2)[P(1,2-O2C6H4)(3)] have been isolated as crystalline solids. The downfield shifts of the acidic proton in their H-1 NMR spectra are consistent with its expected high acidity. The molecular structures of H(DMSO)(2)[P(1,2-O2C6H4)(3)] and H(DMF)(2)[P(1,2-O2C6H4)(3)] reveal that the protons in each are O-bound by either DMSO (x2) or DMF (x2). The N-H stretching frequency for the Oct(3)NH[P(1,2-O2C6H4)(3)] ((V) over bar (N-H) =3129 cm(-1)) is identical to that observed for trioctylammonium tetrafluoroborate ((v) over bar (N-H) = 3129 cm(-1)), suggesting that the basicity of these two weakly coordinating anions is similar. A preliminary investigation of the effectiveness of H(DMF)(2)[p(1,2-O2C6H4] in the protonolysis of metal-alkyl bonds was undertaken. Treating (dppe) pdMe(2) [dppe = 1,2-bis(diphenylphosphino)ethane] with H(DMF)(2)[P(1,2-O2C6H4)(3)] affords either [(dppe)pd(NCMe)Me][P(1,2-O2C6H4)(3) (1:1 ratio) or [(dppe)pd(NCMe)(2)(][P(1,2-O2C6H4)(3)](2) (1:2 ratio), both of which are structurally characterized.},
	keywords = {ALTERNATING COPOLYMERIZATION, ANIONS, CARBON-MONOXIDE, COORDINATING ANIONS, CRYSTAL-STRUCTURE, DIMETHYL-SULFOXIDE, MIGRATORY INSERTION, MOLECULAR-STRUCTURE, OLEFIN, PALLADIUM(II) COMPLEXES, POLYMERIZATION, SUPERWEAK},
	isbn = {0276-7333},
	url = {<Go to ISI>://000268455900036},
	author = {Siu, P. W. and Gates, D. P.}
}
@article {1574,
	title = {High resolution laser induced fluorescence spectroscopy of the [18.8] (3)Phi(i)-X (3)Phi(i) (0,0) band of cobalt monofluoride},
	journal = {Journal of Chemical Physics},
	volume = {125},
	number = {6},
	year = {2006},
	note = {ISI Document Delivery No.: 073TITimes Cited: 5Cited Reference Count: 33Steimle, Timothy C. Ma, Tongmei Adam, Allan G. Hamilton, William D. Merer, Anthony J.},
	month = {Aug},
	pages = {9},
	type = {Article},
	abstract = {The fine and hyperfine interaction parameters in the [18.8] (3)Phi (upsilon=0) and X (3)Phi (upsilon=0) states of cobalt monofluoride, CoF, have been determined from an analysis of high-resolution laser induced fluorescence spectra of the [18.8] (3)Phi(3)-X (3)Phi(3) and [18.8] (3)Phi(4)-X (3)Phi(4) band systems. The previously reported pure rotational transitions of the X (3)Phi(4)(upsilon=0) state [T. Okabayashi and M. Tanimoto, J. Mol. Spectrosc. 221, 149 (2003)] were included in the data set. The hyperfine parameters for Co-59 (I=7/2) and F-19 (I=1/2) have been interpreted using atomic data together with a proposed molecular orbital description for the [18.8](3)Phi(i) and X (3)Phi(i) states. A comparison of the hyperfine parameters in the X (3)Phi state of cobalt monohydride, CoH, with those of the X (3)Phi state of CoF reveals that the bonding in the two molecules is significantly different. It is shown that, in a situation where the Omega substates of a multiplet degenerate electronic state are analyzed separately, the Fermi contact parameter b can be determined with fair accuracy from the apparent centrifugal distortion of the hyperfine structure. (c) 2006 American Institute of Physics.},
	keywords = {ALTERNATING COPOLYMERIZATION, CARBON-DIOXIDE, COF, COMPLEXES, ELECTRONIC-SPECTRUM, GROUND-STATE, HYPERFINE-STRUCTURE, PARAMETERS, PROPYLENE-OXIDE, TRANSITION-METAL},
	isbn = {0021-9606},
	url = {<Go to ISI>://000239765100017},
	author = {Steimle, T. C. and Ma, T. M. and Adam, A. G. and Hamilton, W. D. and Merer, A. J.}
}
