@article {1416,
	title = {Energetics and dynamics of threshold photoion-pair formation in HF/DF},
	journal = {Journal of Chemical Physics},
	volume = {124},
	number = {7},
	year = {2006},
	note = {ISI Document Delivery No.: 014IPTimes Cited: 4Cited Reference Count: 36},
	month = {Feb},
	pages = {10},
	type = {Article},
	abstract = {Threshold ion-pair production spectroscopy (TIPPS) has been applied to two isotopomers, HF and DF. From the high resolution (similar to 0.3 cm(-1)) TIPP spectra, the ion-pair thresholds of HF/DF have been precisely measured. Combined with the ionization energy of H(D), the electron affinity of F, and the zero point energies of HF/DF, the difference between their classical bond dissociation energies was obtained as D-e(H-F)-D-e(D-F)=12.4 +/- 0.5 cm(-1). Our result provides an experimental estimate of the Born-Oppenheimer breakdown in the ground electronic state. The present work also measured the total ion-pair yield spectra of HF and DF in the threshold region, and the ion-pair formation mechanisms of these two molecules were discussed in light of the high resolution results.},
	keywords = {Born-Oppenheimer breakdown, DIATOMIC HYDRIDES, DISSOCIATION-ENERGIES, ELECTRONIC-SPECTRUM, HF, ION, ISOTOPIC DEPENDENCE, PHOTOELECTRON-SPECTROSCOPY, PRODUCTION SPECTROSCOPY, X1-SIGMA+ STATES},
	isbn = {0021-9606},
	url = {<Go to ISI>://000235473500019},
	author = {Hu, Q. J. and Hepburn, J. W.}
}
@inbook {1136,
	title = {Dynamics and energetics of photoion-pair formation in HF/DF},
	booktitle = {DR2004: Sixth International Conference on Dissociative Recombination: Theory, Experiments and Applications},
	series = {Journal of Physics Conference Series},
	volume = {4},
	year = {2005},
	note = {ISI Document Delivery No.: BCE13Times Cited: 5Cited Reference Count: 23Proceedings Paper6th International Conference on Dissociative RecombinationJUL 12-16, 2004Mosbach, GERMANYDIRAC HOUSE, TEMPLE BACK, BRISTOL BS1 6BE, ENGLAND},
	pages = {267-271},
	publisher = {Iop Publishing Ltd},
	organization = {Iop Publishing Ltd},
	address = {Bristol},
	abstract = {Preliminary results of a high resolution coherent vacuum ultraviolet study of photoion-pair formation in HF/DF are reported. These results include threshold ion-pair production (TIPPS) and total photoion-pair yield spectra, which show sharp resonances due to predissociating Rydberg states. Detailed analysis of the spectra provides precise energies for the ion-pair thresholds, and insight into the mechanism for ion-pair formation.},
	keywords = {DF, DISSOCIATION, F2, HCL, HF, ION, PRODUCTION SPECTROSCOPY, STATES, THRESHOLD},
	isbn = {1742-6588},
	url = {<Go to ISI>://000228817000040},
	author = {Hu, Q. J. and Hepburn, J. W.},
	editor = {Wolf, A. and Lammich, L. and Schmelcher, P.}
}
