@article {1580,
	title = {Ion pair dissociation: Spectroscopy and dynamics},
	journal = {Annual Review of Physical Chemistry},
	volume = {57},
	year = {2006},
	note = {ISI Document Delivery No.: 044JOTimes Cited: 26Cited Reference Count: 82Suits, Arthur G. Hepburn, John W.},
	pages = {431-465},
	type = {Review},
	abstract = {Ion pair dissociation processes may be studied Using coherent vacuum Ultraviolet laser sources in a manner entirely analogous to photoelectron spectroscopy, albeit with the anion playing the role of a heavy electron. If the excitation energy is above the dissociation energy and the kinetic energy of the fragment is measured Using ion imaging. this approach is termed ion pair imaging spectroscopy (IPIS) and is related to conventional photoelectron spectroscopy. If the excitation energy is just below the dissociation energy and pulsed-field dissociation is employed, this approach is analogous to mass analyzed threshold ionization (MATI) spectroscopy and is termed threshold ion pair production spectroscopy (TIPPS). These approaches provide a novel means of investigating ion thermochemistry and spectroscopy and superexcited state decay dynamics at high resolution.},
	keywords = {cation, ENERGY, HIGH-RESOLUTION, ion imaging, IONIZATION, METHYL, MOLECULAR-OXYGEN, NEGATIVE-IONS, PHOTODISSOCIATION DYNAMICS, PHOTOELECTRON-SPECTROSCOPY, PHOTOIONIZATION, superexcited states, TIPPS, VACUUM-ULTRAVIOLET, velocity map imaging, VUV, ZEKE},
	isbn = {0066-426X},
	url = {<Go to ISI>://000237668700015},
	author = {Suits, A. G. and Hepburn, J. W.}
}
@article {1645,
	title = {Rhodium(III) peroxo complexes containing carbene and phosphine ligands},
	journal = {Organometallics},
	volume = {25},
	number = {20},
	year = {2006},
	note = {ISI Document Delivery No.: 084QMTimes Cited: 12Cited Reference Count: 50Yu, Xiao-Yan Patrick, Brian O. James, Brian R.},
	month = {Sep},
	pages = {4870-4877},
	type = {Article},
	abstract = {The Rh(I) carbene precursors [RhCl(COE)(NHC)](2), where the N-heterocyclic carbene is 1,3-bis(2,6-diisopropylphenyl) imidazol-2-ylidene (IPr) or 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes), were used to synthesize the RhCl(NHC)(P-N) complexes 4 (NHC = IPr) and 5 (NHC = IMes), where P-N is P, N-chelated o-(diphenylphosphino)-N, N-dimethylaniline, and the corresponding cis-RhCl(NHC)(PPh3)(2) complexes 6 and 7. The synthesis of 4 surprisingly requires the reaction to be carried out under a hydrogen atmosphere and occurs via the intermediate dihydride RhCl(H)(2)(IPr)(P-N) (3). Complexes 4-7 in benzene readily undergo irreversible oxidative addition of O-2 to form the corresponding Rh(III) peroxide complexes 9-12. For comparative purposes, RhCl(PPh3)(P-N) (8) was synthesized from RhCl(PPh3)(3), and this also added O-2 to form a peroxo complex (13). All of the complexes were generally characterized by elemental analysis and H-1, P-31{H-1}, and C-13{H-1} NMR and IR spectroscopies and, in the cases of 9, 10, and 13, by X-ray crystallography.},
	keywords = {14-ELECTRON RH(III), C-H ACTIVATION, CATALYTIC CYCLIZATION, DIOXYGEN ACTIVATION, hydride, HYDROFORMYLATION, HYDROGENATION, MOLECULAR-OXYGEN, REACTIVITY, TRANSITION-METAL-COMPLEXES},
	isbn = {0276-7333},
	url = {<Go to ISI>://000240549500028},
	author = {Yu, X. Y. and Patrick, B. O. and James, Brian R.}
}
