@inbook {1136,
	title = {Dynamics and energetics of photoion-pair formation in HF/DF},
	booktitle = {DR2004: Sixth International Conference on Dissociative Recombination: Theory, Experiments and Applications},
	series = {Journal of Physics Conference Series},
	volume = {4},
	year = {2005},
	note = {ISI Document Delivery No.: BCE13Times Cited: 5Cited Reference Count: 23Proceedings Paper6th International Conference on Dissociative RecombinationJUL 12-16, 2004Mosbach, GERMANYDIRAC HOUSE, TEMPLE BACK, BRISTOL BS1 6BE, ENGLAND},
	pages = {267-271},
	publisher = {Iop Publishing Ltd},
	organization = {Iop Publishing Ltd},
	address = {Bristol},
	abstract = {Preliminary results of a high resolution coherent vacuum ultraviolet study of photoion-pair formation in HF/DF are reported. These results include threshold ion-pair production (TIPPS) and total photoion-pair yield spectra, which show sharp resonances due to predissociating Rydberg states. Detailed analysis of the spectra provides precise energies for the ion-pair thresholds, and insight into the mechanism for ion-pair formation.},
	keywords = {DF, DISSOCIATION, F2, HCL, HF, ION, PRODUCTION SPECTROSCOPY, STATES, THRESHOLD},
	isbn = {1742-6588},
	url = {<Go to ISI>://000228817000040},
	author = {Hu, Q. J. and Hepburn, J. W.},
	editor = {Wolf, A. and Lammich, L. and Schmelcher, P.}
}
@article {635,
	title = {Threshold ion-pair production spectroscopy of HCl/DCl: Born-Oppenheimer breakdown in HCl and HCl+ and dynamics of photoion-pair formation},
	journal = {Journal of Chemical Physics},
	volume = {119},
	number = {17},
	year = {2003},
	note = {ISI Document Delivery No.: 733FHTimes Cited: 16Cited Reference Count: 31},
	month = {Nov},
	pages = {8938-8945},
	type = {Article},
	abstract = {Threshold ion-pair production spectroscopy (TIPPS) has been applied to two isotopomers, HCl and DCl. From the high-resolution TIPP spectra the ion-pair thresholds of the two molecules have been precisely measured. Combined with the known ionization energy of H(D) and the electron affinity of Cl, the difference between their bond dissociation energies is calculated, and therefore an experimental determination of the effect of Born-Oppenheimer breakdown on the dissociation limit of the ground state potential curve has been obtained. The difference in D-e for the two isotopomers was found to be: D-e(H-Cl)-D-e(D-Cl)=3.2+/-1.0 cm(-1). The bond energy for HCl was in agreement with our previous determination, D-0(H-Cl)=35748.2+/-0.8 cm(-1). These results are compared to a recent study of Born-Oppenheimer breakdown in HCl by Coxon and Hajigeorgiou, where high resolution spectroscopic data was used to fit Born-Oppenheimer breakdown correction terms for the intramolecular potential function. The present study also measured the high resolution spectra for photoion-pair production for HCl and DCl in the threshold region for ion-pair production (similar to86 nm). Although there is qualitative agreement between the current results and previous experimental and theoretical work, there are some important differences. The possible mechanism for ion-pair formation in HCl and DCl is discussed in light of these high resolution results. (C) 2003 American Institute of Physics.},
	keywords = {BAND SYSTEM, DCL, DEPENDENCE, DF, DISSOCIATION-ENERGY, HF, IONIZATION, MOLECULE, STATES, TIPPS},
	isbn = {0021-9606},
	url = {<Go to ISI>://000185988900021},
	author = {Hu, Q. J. and Melville, T. C. and Hepburn, J. W.}
}
