@article {2168,
	title = {The complexes: RhCl(P-N)(THP), where P-N is P,N-chelated o-diphenylphosphino-N,N-dimethylaniline and THP is tris(hydroxymethyl)phosphine, and RhCl[(O)P-N][THP(O)] containing O-bonded phosphine oxides},
	journal = {Inorganica Chimica Acta},
	volume = {361},
	number = {11},
	year = {2008},
	note = {ISI Document Delivery No.: 323VATimes Cited: 3Cited Reference Count: 42Lorenzini, Fabio Patrick, Brian O. James, Brian R.},
	month = {Jul},
	pages = {3199-3204},
	type = {Article},
	abstract = {{The complex RhCl(P-N)(THP) (1) is synthesized under argon from RhCl(cod)(THP) and P-N, and is structurally characterized; P-N = P, N-chelated o-diphenylphosphino-N,N-dimethylaniline},
	keywords = {BEARING O-N, BIDENTATE PHOSPHINES, CATALYTIC-OXIDATION, HYDROFORMYLATION, LIGANDS, LOW-TEMPERATURE, N-DIMETHYLANILINYL SUBSTITUENTS, OXIDATION, PALLADIUM(II) COMPLEXES, phosphanes, phosphine oxides, phosphines, REACTIVITY, RHODIUM COMPLEXES, RHODIUM(I) COMPLEXES, X-ray structure},
	isbn = {0020-1693},
	url = {<Go to ISI>://000257475300029},
	author = {Lorenzini, F. and Patrick, B. O. and James, Brian R.}
}
@article {1143,
	title = {Platinum(II) and palladium(II) complexes of bisphosphine ligands bearing o-N,N-dimethylanilinyl substituents: A hint of catalytic olefin hydration},
	journal = {Inorganic Chemistry},
	volume = {44},
	number = {9},
	year = {2005},
	note = {ISI Document Delivery No.: 922CLTimes Cited: 9Cited Reference Count: 55},
	month = {May},
	pages = {3290-3298},
	type = {Article},
	abstract = {Platinum(II) and palladium(II) complexes of the potentially hexadentate P,N-donor ligand family Ar2P-X-PAr2 (X = (CH2)(2) [dmape], cyclic-C5H8 [dmapcp]; Ar = o-NN-dimethylanilinyl) are described. In CH2Cl2, the dmape complexes exist as equilibrium mixtures of MCl2(P,P{\textquoteright}-dmape) and [MCl(P, P, N-dmape)]Cl isomers (M = Pd, Pt), governed by Delta H degrees = -19 +/- 4 U mol(-1) and Delta S degrees = -100 +/- 30 J mol(-1) K-1 for M = Pt, and Delta H degrees = -11 +/- 7 U mol-1 and Delta S degrees = -60 +/- 20 J mol-1 K-1 for M = Pd. The water-soluble dmapcp complexes exist solely in the [MCl(P,P{\textquoteright},N-dmapcp)]Cl form, but the free and coordinated anilinyl rings in these complexes are in slow diastereoselective exchange, X-ray crystal structures for MCl2(P,P{\textquoteright}-dmape) (M = Pd, Pt), and the [PdCl(P,P{\textquoteright},N-dmape)](+) and [PtCl-P,P{\textquoteright},N-dmapcp)](+) cations, are presented. Some of the complexes show marginal activity in water for the catalyzed hydration of maleic to malic acid, giving about 6-7\% conversion in 24 h at 100 degrees C and substrate: catalyst loadings of 100:1. Attempts to synthesize a PdCl(P,P{\textquoteright},N-dmapm)(+) species led instead to isolation of [Pd(mu-Cl)(P,P-dmapm)](2)-[PF6](2) (dmapm = Ar2PCH2Ar2).},
	keywords = {2-PYRIDYLPHOSPHINE LIGANDS, COORDINATION CHEMISTRY, CRYSTAL-STRUCTURE, DERIVATIVES, DONOR GROUPS, HYDROGENATION, RHODIUM COMPLEXES, RUTHENIUM(II), TERTIARY PHOSPHINES, WATER-SOLUBLE PHOSPHINES},
	isbn = {0020-1669},
	url = {<Go to ISI>://000228813400045},
	author = {Jones, N. D. and Meessen, P. and Losehand, U. and Patrick, B. O. and James, Brian R.}
}
@article {408,
	title = {Bisphosphine ligands containing two o-N,N-dimethylanilinyl substituents at each phosphorus atom},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {80},
	number = {11},
	year = {2002},
	note = {ISI Document Delivery No.: 623LDTimes Cited: 11Cited Reference Count: 35},
	month = {Nov},
	pages = {1600-1606},
	type = {Article},
	abstract = {The synthesis and complete characterization of the family of tetra(amine)bisphosphine ligands (o-NMe2C6H4)(2)P-(X)-P(o-NMe2C6H4)(2), where X = CH2 (dmapm), (CH2)(2) (dmape), and CH(CH2)(3)CH (dmapcp), are described. Crystal structure data are compared with known, analogous bisphosphines containing o-pyridyl or phenyl substituents in place of the o-dimethylanilinyl groups. Several short, intramolecular C-H...N distances in the anilinyl derivatives may represent the presence of weak hydrogen bonds.},
	keywords = {ACID, amine, AMPHIPHILIC DIPHOSPHINES, CATALYTIC-HYDROGENATION, CHEMISTRY, DERIVATIVES, HYDROFORMYLATION, hydrogen-bonding to N atoms, phosphine, polydentate, RESOLUTION, RHODIUM COMPLEXES, RUTHENIUM(II), WATER-SOLUBLE PHOSPHINES},
	isbn = {0008-4042},
	url = {<Go to ISI>://000179703800030},
	author = {Jones, N. D. and Meessen, P. and Smith, M. B. and Losehand, U. and Rettig, S. J. and Patrick, B. O. and James, Brian R.}
}
@article {7389,
	title = {MONONUCLEAR AND DINUCLEAR PALLADIUM COMPLEXES CONTAINING 2-PYRIDYLPHOSPHINE LIGANDS, INCLUDING X-RAY CHARACTERIZATION OF PD2I2(MU-PPH2PY)2 AND A DIMETHYLACETYLENEDICARBOXYLATE A-FRAME COMPLEX PD2CL2(MU-PPY3)2(MU-MEO2C.C=C.CO2ME) PY = 2-PYRIDYL},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {70},
	number = {3},
	year = {1992},
	note = {ISI Document Delivery No.: JD670Times Cited: 41Cited Reference Count: 48},
	month = {Mar},
	pages = {751-762},
	type = {Article},
	abstract = {{Dibromo- and diiodo[(2-pyridyl)phosphine]palladium(II) complexes are prepared by metathesis of cis-PdCl2(PPh3-npyn)2 species (n = 1-3) using the appropriate sodium halide; py = 2-pyridyl. NMR spectroscopy, particularly C-13{H-1}, is used to distinguish cis and trans isomers. The dinuclear complexes Pd2X2(mu-PPh3-npyn)2},
	keywords = {(DINUCLEAR), 2-(DIPHENYLPHOSPHINO)PYRIDINE, BINUCLEAR COMPLEXES, bis(diphenylphosphino)methane, BRIDGING, CHEMISTRY, CRYSTAL, DIMETHYLACETYLENEDICARBOXYLATE ADDUCTS, hydration, LIGAND, MOLECULAR-STRUCTURE, palladium complexes, pyridylphosphines, RHODIUM COMPLEXES, RUTHENIUM(II)},
	isbn = {0008-4042},
	url = {<Go to ISI>://A1992JD67000009},
	author = {Xie, Y. and Lee, C. L. and Yang, Y. P. and Rettig, S. J. and James, Brian R.}
}
