@article {4011,
	title = {Coordination chemistry, and catalytic conversions, of H2S},
	journal = {Pure and Applied Chemistry},
	volume = {69},
	number = {10},
	year = {1997},
	note = {ISI Document Delivery No.: YB877Times Cited: 21Cited Reference Count: 6831st International Conference on the Coordination ChemistryAUG 18-23, 1996VANCOUVER, CANADA},
	month = {Oct},
	pages = {2213-2220},
	type = {Proceedings Paper},
	abstract = {Some reactions of H2S with solutions of Pd- and Ru-phosphine complexes are described. The Pd systems involve sulfur abstraction and generation of H-2, catalytic conversions of H2S to H-2, and attempts to catalyse the (H2S {\textendash}> H-2 + {\textquoteright}S{\textquoteright}) reaction. The Ru studies have led to crystallographic characterisation of a reversibly formed H2S complex, as well as more familiar oxidative addition-type chemistry of H2S. This lecture/review naturally emphasises work carried out at this University (UBC).},
	keywords = {ASPECTS, BIS(DIPHENYLPHOSPHINO)METHANE DPM, DINUCLEAR PALLADIUM(I) COMPLEXES, HYDROGEN-SULFIDE, LEWIS-ACIDS, Mechanistic, MOLECULAR-HYDROGEN, PHOSPHINE COMPLEXES, S-H, SULFUR-CONTAINING LIGANDS, TRANSITION-METAL COMPLEXES},
	isbn = {0033-4545},
	url = {<Go to ISI>://A1997YB87700028},
	author = {James, Brian R.}
}
@article {3566,
	title = {{KINETIC AND MECHANISTIC ASPECTS OF SULFUR ABSTRACTION FROM PD(2)X(2)(MU-S)(MU-DPM)(2) USING DPM OR DPMME [X=HALIDE},
	journal = {Inorganic Chemistry},
	volume = {34},
	number = {9},
	year = {1995},
	note = {ISI Document Delivery No.: QV824Times Cited: 23Cited Reference Count: 30},
	month = {Apr},
	pages = {2278-2286},
	type = {Article},
	abstract = {Solution kinetic and mechanistic studies were performed on the abstraction of sulfur from Pd(2)X(2)(mu-S)(mu-dpm)(2) [X = Cl (2a), Br (2b), I(2c)] using bis(diphenylphosphino)methane (dpm) to give, respectively, Pd(2)X(2)(dpm)(2) [X = Cl (1a), Br (1b), I (1c)] and dpm(S). The reaction is first-order in both 2 and dpm with the reactivity trend in CHCl3 being X = Cl > Br > I. The activation parameters for the chloride system are Delta H-double dagger = 41 +/- 3 kJ mol(-1) and Delta S-double dagger = -127 +/- 10 J K-1 mol(-1), and for the bromide, Delta H-double dagger = 38 +/- 1 kJ mol(-1) and Delta S-double dagger = -144 +/- 4 J K-1 mol(-1), showing the entropy term is dominant in governing reactivity. Low-temperature NMR studies did not reveal the presence of observable intermediates. 2b and 1b undergo rapid diphosphine ligand exchange with dpm-d(2); with 2b, prior to any S-abstraction, Pd2Br2(mu-S)(dpm)(dpm-d(2)) (7b) and Pd2Br2(mu-S)(dpm-d(2))(2) (8b) are present, while Pd2Br2(dpm)(dpm-d(2)) (3b) and Pd2Br2(dpm-d(2))(2) (4b) are formed, as well as 1b and dpm(S)-d(2), in the abstraction reaction of 2b with dpm-d(2). The distribution of products is close to statistical on the basis of the stoichiometries of the reactants. Reaction of 2b with 1,1{\textquoteright}-bis(diphenylphosphino)ethane (dpmMe) proceeds in an analogous way generating 1b, Pd2Br2(dpm)(dpmMe) (5b), Pd2Br2(dpmMe)(2) (6b), dpm(S), and dpmMe(S). In contrast, 1b undergoes slow diphosphine ligand exchange with dpmMe to form 5b and 6b; 2b undergoes no ligand exchange with dpmMe prior to the S-abstraction reaction. The findings are rationalized in terms of postulated intermediates and transition states that include formulations with three equivalent diphosphines. No sulfur abstraction occurs on treating 2b with PPh(3), PPh(2)Me, or Ph(2)P(CH2)(3)PPh(2).},
	keywords = {BIS(DIPHENYLPHOSPHINO)METHANE DPM, BIS-PHOSPHORUS LIGANDS, COMPLEXES, CRYSTAL-STRUCTURE, DERIVATIVES, DINUCLEAR PALLADIUM(I), HYDROGEN-SULFIDE, METAL-METAL BONDS, MONONUCLEAR, Pd(I)},
	isbn = {0020-1669},
	url = {<Go to ISI>://A1995QV82400007},
	author = {Wong, T. Y. H. and Barnabas, A. F. and Sallin, D. and James, Brian R.}
}
@article {3247,
	title = {SYNTHESIS AND CHARACTERIZATION OF DINUCLEAR PALLADIUM COMPLEXES WITH BRIDGING SELENIDE OR SELENOXIDE LIGANDS, INCLUDING X-RAY CHARACTERIZATION OF ANTI-PD2CL2(MU-SE)(MU-DPMME)(2) [DPMME=1,1-BIS(DIPHENYLPHOSPHINO)ETHANE]},
	journal = {Inorganic Chemistry},
	volume = {34},
	number = {24},
	year = {1995},
	note = {ISI Document Delivery No.: TF982Times Cited: 12Cited Reference Count: 41},
	month = {Nov},
	pages = {6118-6123},
	type = {Article},
	abstract = {{The complexes Pd2Cl2(P-P)(2), where (P-P) = mu-bis(diphenylphosphino)methane, dpm, or mu-1,1-bis(diphenylphosphino)ethane, dpmMe, react with elemental selenium to give the A-frame adducts Pd2Cl2(mu-Se)(P-P)(2), which can be oxidized by t-BuOOH to the mu-SeO derivatives. Reaction of H2Se with Pd2Cl2(dpm)(2) generates Pd(2)Ch(2-n)-(SeH)(n)(mu-Se)(dpm)(2) species (n = 0-2). anti-Pd2Cl2(mu-Se)(dpmMe)(2) (2d) crystallizes in the monoclinic space group P2(1)/c with a = 11.986(2) Angstrom},
	keywords = {1, 1-bis(diphenylphosphino)ethane, 2-(DIPHENYLPHOSPHINO)PYRIDINE, BIS(DIPHENYLPHOSPHINO)METHANE DPM, CARBON-MONOXIDE, CHEMISTRY, CRYSTAL-STRUCTURES, DIHYDROGEN, DIMERS, HYDROGEN-SULFIDE, METAL-METAL BONDS},
	isbn = {0020-1669},
	url = {<Go to ISI>://A1995TF98200024},
	author = {Besenyei, G. and Parkanyi, L. and Simandi, L. I. and James, Brian R.}
}
@article {6971,
	title = {SYN-ISOMERS AND ANTI-ISOMERS OF PD2CL2(MU-DPMME)2 (DPMME = 1,1-BIS(DIPHENYLPHOSPHINO)ETHANE)},
	journal = {Inorganic Chemistry},
	volume = {30},
	number = {10},
	year = {1991},
	note = {ISI Document Delivery No.: FM296Times Cited: 13Cited Reference Count: 13},
	month = {May},
	pages = {2446-2448},
	type = {Note},
	keywords = {BIS(DIPHENYLPHOSPHINO)METHANE DPM, CONVERSION, DINUCLEAR PALLADIUM(I) COMPLEXES, HYDROGEN-SULFIDE, LIGANDS},
	isbn = {0020-1669},
	url = {<Go to ISI>://A1991FM29600042},
	author = {Besenyei, G. and Lee, C. L. and Xie, Y. and James, Brian R.}
}
