@article {878,
	title = {New details concerning the reactions of nitric oxide with vanadium tetrachloride},
	journal = {Inorganic Chemistry},
	volume = {43},
	number = {22},
	year = {2004},
	note = {ISI Document Delivery No.: 866SHTimes Cited: 2Cited Reference Count: 35},
	month = {Nov},
	pages = {7227-7233},
	type = {Article},
	abstract = {The slow addition of NO to a CCl4 solution Of VCl4 reproducibly forms the known polymer [V(NO)(3)Cl-2](n) as a dark brown powder. Treatment of a CH2Cl2 suspension of [V(NO)(3)Cl-2], with excess THF generates mer-(THF)(3)V(NO)Cl-2 (1) which can be isolated as an orange crystalline material in 55\% yield. The reaction of 1 with excess MeCN or 1 equiv of trimpsi (trimpsi = (BuSi)-Bu-t(CH2PMe2)(3)) provides yellow-orange (MeCN)(3)V(NO)Cl-2.MeCN (2.MeCN) and yellow (trimpsi)V(NO)Cl-2 (3), respectively. A black, crystalline complex formulated as [NO][VCl5] (4) is formed by the slow addition of NO to neat VCl4 or by the reaction of excess CINO with neat VCl4. Complex 4 is extremely air- and moisture-sensitive, and IR spectroscopy suggests that in solutions and in the gas phase it dissociates back into VCl4 and CINO. Reaction of 4 with excess [NEt3(CH2Ph)]Cl generates [NEt3(CH2Ph)](2)[VCl6].2CH(2)Cl(2) (5.2CH(2)Cl(2)), which can be isolated as deep-red crystals in 51\% yield. All new complexes have been characterized by conventional spectroscopic methods, and the solid-state molecular structures of 1, 2.MeCN, and 5.2CH(2)Cl(2) have been established by single-crystal X-ray diffraction analyses.},
	keywords = {(BUSI)-BU-T(CH2PME2)(3), (TRIMPSI)M(CO)(2)(NO) COMPLEXES M, CHLORIDE, COORDINATION-COMPOUNDS, CRYSTAL-STRUCTURE, DICHLOROTRINITROSYLVANADIUM, IR-SPECTRUM, NITROSYLS, REACTIVITY, TRIMPSI},
	isbn = {0020-1669},
	url = {<Go to ISI>://000224792900049},
	author = {Hayton, T. W. and Patrick, B. O. and Legzdins,Peter}
}
@article {880,
	title = {The solid-state molecular structure of W(NO)(3)Cl-3 and the nature of its W-NO bonding},
	journal = {Canadian Journal of Chemistry-Revue Canadienne De Chimie},
	volume = {82},
	number = {2},
	year = {2004},
	note = {ISI Document Delivery No.: 802BHTimes Cited: 1Cited Reference Count: 46},
	month = {Feb},
	pages = {285-292},
	type = {Article},
	abstract = {{The monomeric trinitrosyl complex, W(NO)(3)Cl-3, can be prepared by the treatment of WCl6 in CH2Cl2 with NO gas, and its identity has been unambiguously confirmed by a single-crystal X-ray diffraction analysis. The complex crystallizes in the space group Pmn2(1) as a three-component twin (a = 10.4280(4) Angstrom},
	keywords = {bonding, CARBONYL, CHEMISTRY, CRYSTAL-STRUCTURE, DERIVATIVES, DICHLORODINITROSYLTUNGSTEN, DICHLOROTRINITROSYLVANADIUM, MOLYBDENUM, MONONUCLEAR, NITROSYL, NITROSYL COMPLEXES, STRUCTURE, TUNGSTEN},
	isbn = {0008-4042},
	url = {<Go to ISI>://000220138500024},
	author = {Hayton, T. W. and Patrick, B. O. and Legzdins,Peter and McNeil, W. S.}
}
