@article {3419,
	title = {NITROSYL N-O BOND-CLEAVAGE DURING REACTIONS OF ORGANOMETALLIC NITROSYL COMPLEXES OF THE GROUP-6 ELEMENTS},
	journal = {Comments on Inorganic Chemistry},
	volume = {17},
	number = {4},
	year = {1995},
	note = {ISI Document Delivery No.: RH843Times Cited: 11Cited Reference Count: 44Part A},
	pages = {239-254},
	type = {Article},
	abstract = {The nitrosyl ligands in organotransition-metal nitrosyl complexes usually stay intact during chemical transformations of these complexes. However, our continuing study of the characteristic reactivity of Group 6 organometallic nitrosyl complexes has recently revealed a number of new product complexes which result from N-O bond cleavage of the nitrosyl groups in the reactants. The various reactions and reaction conditions during which these complexes undergo facile nitrosyl N-O bond dissociation are summarized, and mechanistic ideas as to why these bond cleavages occur are also presented.},
	keywords = {(ETA-5-C5ME5)RU(NO), ACTIVATION, COORDINATED NITRIC-OXIDE, COORDINATIVELY UNSATURATED BRIDGING, GAS-PHASE, GROUP 6, LIGANDS, MIGRATORY INSERTION, MOLYBDENUM, NITROSYL, NITROSYL BOND CLEAVAGE, OXIDATIVE ADDITION-REACTIONS, OXO COMPLEXES, TUNGSTEN},
	isbn = {0260-3594},
	url = {<Go to ISI>://A1995RH84300003},
	author = {Legzdins,Peter and Young, M. A.}
}
@article {3420,
	title = {SPONTANEOUS ISOMERIZATION OF SYMMETRICAL M(MU-NO)(2)M LINKAGES TO (ON)M=N=M=O GROUPINGS},
	journal = {Journal of the American Chemical Society},
	volume = {117},
	number = {34},
	year = {1995},
	note = {ISI Document Delivery No.: RR735Times Cited: 13Cited Reference Count: 50},
	month = {Aug},
	pages = {8798-8806},
	type = {Article},
	abstract = {{Treatment of Cp*Mo(NO)R(2) complexes (Cp* = eta(5)-C(5)Me(5); R = CH(2)CMe(3), CH(2)CMe(2)Ph) in C6H6 at 5 degrees C with H-2 results in the formation of [Cp*MoR](2)(mu-NO)(2) products (R = CH(2)CMe(3) (1), CH(2)CMe(2)Ph (2)) which are isolable in 25-30\% yields. Similar treatment of an equimolar mixture of Cp*Mo(NO)(CH(2)SiMe(3))(2) and Cp*W(NO)(CH(2)SiMe(3))(2) with H-2 results in the formation of a heterobimetallic species, [Cp*Mo(CH(2)SiMe(3))](mu-NO)(2)[Cp*W(CH(2)SiMe(3))] (3). Complexes 1, 2, and 3 isomerize in solution at ambient temperatures To form [Cp*Mo-(NO)R](mu-N)[Cp*Mo(O)R] (R = CH(2)CMe(3) (4), CH(2)CMe(2)Ph (5)) and a 60:40 (M(1) = W:M(1) = Mo) mixture of [Cp*M(1)(NO)(CH(2)SiMe(3))](mu-N)[Cp*M(2)(O)(CH(2)SiM(3))] (6), respectively. The solid-state molecular structures of 1 and 6 have been established by single-crystal X-ray crystallographic analyses. Crystals of [Cp*Mo(CH(2)CMe(3))](2)-(mu-NO)(2) (1) are orthorhombic of space group Pbcn: a = 12.570(3) Angstrom},
	keywords = {(ETA-5-C5ME5)RU(NO), BOND, COMPLEXES, GAS-PHASE, LIGANDS, MOLYBDENUM, NITRIC-OXIDE, ORGANOMETALLIC NITROSYL CHEMISTRY, OXIDATIVE ADDITION-REACTIONS, TUNGSTEN},
	isbn = {0002-7863},
	url = {<Go to ISI>://A1995RR73500013},
	author = {Legzdins,Peter and Young, M. A. and Batchelor, R. J. and Einstein, F. W. B.}
}
