@article {678,
	title = {Template effect where 1-3 molecules drive formation of a trimer carceplex},
	journal = {Chemistry-a European Journal},
	volume = {9},
	number = {14},
	year = {2003},
	note = {ISI Document Delivery No.: 706XATimes Cited: 6Cited Reference Count: 46},
	month = {Jul},
	pages = {3253-3262},
	type = {Article},
	abstract = {The template effect in the formation of a trimer carceplex using 1-3 molecules as templates is explored. Thirteen different templates were studied and template ratios were measured for templates of like and unlike molecularity. Five transition-state models were studied for their binding abilities to see if these mirror the template ratios. The chemical shifts of the guests and the thermodynamic and kinetic values for templation suggest that binding is key, often tight, and that the guest determining step is formation of the last covalent bond. The molecular dynamics of guests as well as the conformational dynamics of both hosts and guests further addresses nature of the recognition between host and guest. Finally, we were surprised to discover that water can bind reversibly to the trimer carceplexes, which will have ramifications to any inner phase reactions conducted inside the cage.},
	keywords = {AMPLIFICATION, BARRIER, BINDING, CAPTURE, carceplex, CHEMISTRY, DIELS-ALDER REACTION, DYNAMICS, ELUCIDATION, ENCAPSULATION, HOST-GUEST COMPLEXATION, host-guest systems, molecular recognition, RESORCINARENE CAPSULE, REVERSIBLE, supramolecular, TEMPLATE SYNTHESIS},
	isbn = {0947-6539},
	url = {<Go to ISI>://000184479300009},
	author = {Makeiff, D. A. and Sherman, J. C.}
}
@article {4874,
	title = {Template effects in the formation of a tetramethylene-bridged hemicarceplex},
	journal = {Journal of the American Chemical Society},
	volume = {122},
	number = {7},
	year = {2000},
	note = {ISI Document Delivery No.: 289TZTimes Cited: 20Cited Reference Count: 57},
	month = {Feb},
	pages = {1337-1342},
	type = {Article},
	abstract = {We report a study of the template effect in the formation of tetramethylene-bridged hemicarceplex 7.guest. Two tetrol cavitands were bridged with 1,4-dibromobutane in the presence of suitable template (guest) molecules in N-formylpiperidine as solvent. Selectivity was observed when competing templates were present during the reaction: the relative templating abilities (template ratios) of 30 different guest molecules range by 3600-fold, and manifest a significant preference for para-disubstituted benzenes. Twenty-one of the 30 hemicarceplexes used in this templation study are new. The trend in guest selectivity is markedly different from previous studies in which smaller cavities (e.g., carceplex 2.guest) are formed. In such studies, capsule 3.guest was a good transition state model, whereas this is not the case in the present work.},
	keywords = {2 BOWLS, BINDING-PROPERTIES, CARCEPLEXES, CONTAINER, CRYSTAL-STRUCTURE, ENCAPSULATION, METAL-ION, O-BENZYNE, REVERSIBLE MOLECULAR CAPSULES, zeolites},
	isbn = {0002-7863},
	url = {<Go to ISI>://000085639200011},
	author = {Makeiff, D. A. and Pope, D. J. and Sherman, J. C.}
}
@article {4223,
	title = {Crystal structure and thermodynamics of reversible molecular capsules},
	journal = {Journal of the American Chemical Society},
	volume = {120},
	number = {25},
	year = {1998},
	note = {ISI Document Delivery No.: ZY238Times Cited: 60Cited Reference Count: 40},
	month = {Jul},
	pages = {6252-6260},
	type = {Article},
	abstract = {The reversible encapsulation of small molecules by two rigid hemispherical molecules is described. The "bowls" are linked by four charged hydrogen bonds. The complex is highly guest-selective. A crystal structure of one complex and a thermodynamic analysis of several complexes provide an unusually vivid description of the structure and dynamics of these complexes. The relevance of these complexes as transition state models for the formation of carceplexes is also presented.},
	keywords = {BARRIER, carceplex, ENCAPSULATION, HOST GUEST COMPLEXATION, ORGANIC-MOLECULES},
	isbn = {0002-7863},
	url = {<Go to ISI>://000074600100009},
	author = {Chapman, R. G. and Olovsson, G. and Trotter, J. and Sherman, J. C.}
}
@article {4223,
	title = {Crystal structure and thermodynamics of reversible molecular capsules},
	journal = {Journal of the American Chemical Society},
	volume = {120},
	number = {25},
	year = {1998},
	note = {ISI Document Delivery No.: ZY238Times Cited: 60Cited Reference Count: 40},
	month = {Jul},
	pages = {6252-6260},
	type = {Article},
	abstract = {The reversible encapsulation of small molecules by two rigid hemispherical molecules is described. The "bowls" are linked by four charged hydrogen bonds. The complex is highly guest-selective. A crystal structure of one complex and a thermodynamic analysis of several complexes provide an unusually vivid description of the structure and dynamics of these complexes. The relevance of these complexes as transition state models for the formation of carceplexes is also presented.},
	keywords = {BARRIER, carceplex, ENCAPSULATION, HOST GUEST COMPLEXATION, ORGANIC-MOLECULES},
	isbn = {0002-7863},
	url = {<Go to ISI>://000074600100009},
	author = {Chapman, R. G. and Olovsson, G. and Trotter, J. and Sherman, J. C.}
}
@article {4224,
	title = {Reversible molecular capsules composed of two cavitands linked via an assortment of charged-hydrogen bonds and covalent bonds},
	journal = {Journal of the American Chemical Society},
	volume = {120},
	number = {38},
	year = {1998},
	note = {ISI Document Delivery No.: 125EVTimes Cited: 42Cited Reference Count: 29},
	month = {Sep},
	pages = {9818-9826},
	type = {Article},
	abstract = {Six new cavitand bowls are reported (6, 7, 8, 9, 11, and 12), as are three bis-bowl compounds (4, 13, and 14). Eight new complexes (4.guest, 7C.guest, 8C.guest, 9C.guest, 14.guest, 15.guest, 15C.guest, and 16C.guest) that reversibly encapsulate small molecules are reported. Two or more charged-hydrogen bonds (CHBs) or covalent linkages between the bowls are required to form stable complexes. Guest exchange rates vary from milliseconds to days. Thermodynamically, these complexes display an enthalpy-entropy compensation. The relative stability of complex 3.pyrazine versus complex 3.chloroform is 170000 in nitrobenzene-d(5) at 298 It. Apparent stability constants in nitrobenzene-d(5) at 298 K yield 1.1 x 10(9) M-1 for complex 3.pyrazine. The absolute stability constant for complex 4.pyrazine in nitrobenzene-d(5) at 333 K is 3.5 x 10(6) M-1.},
	keywords = {BINDING, carceplex, CHEMISTRY, ENCAPSULATION, HEMICARCERANDS, HOST-GUEST COMPLEXATION, ORGANIC-MOLECULES, RELEASE, TEMPLATION},
	isbn = {0002-7863},
	url = {<Go to ISI>://000076225200012},
	author = {Chapman, R. G. and Sherman, J. C.}
}
@article {4351,
	title = {Water-soluble cavitands: Synthesis of methylene-bridged resorcin[4]arenes containing hydroxyls and phosphates at their feet and bromomethyls and thiomethyls at their rims},
	journal = {Journal of Organic Chemistry},
	volume = {63},
	number = {20},
	year = {1998},
	note = {ISI Document Delivery No.: 127ZGTimes Cited: 11Cited Reference Count: 31},
	month = {Oct},
	pages = {6824-6829},
	type = {Article},
	abstract = {The synthesis of rim-functionalized methylene-bridged resorcin[4]arenes ("cavitands") containing hydrophilic propanol or water-solublilizing propylphosphate feet is described. The cavitands possess the synthetically useful benzylthiol (cavitands 6 and 16) or benzylbromide (cavitands 9 and 11) functionalities at their rims, which are suitable for further derivatization near the hydrophobic cavity of the cavitand. These water-soluble cavitands represent new building blocks that are ideal for use in aqueous supramolecular chemistry. As an example of their synthetic utility in supramolecular studies, we have reacted phosphate-footed cavitands 11 and 16 with cysteine-containing peptide 17 and chloroacetylated peptide 19, respectively, to afford the corresponding de novo proteins 18 and 20.},
	keywords = {ADSORPTION, BUILDING-BLOCKS, CARCERANDS, ENCAPSULATION, HOST-GUEST COMPLEXATION, MOLECULAR, PHASE, RECOGNITION, RESORCINARENES, SELF-ASSEMBLED MONOLAYERS},
	isbn = {0022-3263},
	url = {<Go to ISI>://000076380300019},
	author = {Mezo, A. R. and Sherman, J. C.}
}
@article {3935,
	title = {A bis(carceplex) from a cyclic tetramer of cavitands},
	journal = {Angewandte Chemie-International Edition in English},
	volume = {36},
	number = {16},
	year = {1997},
	note = {ISI Document Delivery No.: XX181Times Cited: 36Cited Reference Count: 35},
	month = {Sep},
	pages = {1727-1729},
	type = {Article},
	keywords = {CALIX<4>ARENE, CARCEPLEXES, CAVITANDS, CHANNELS, CHEMISTRY, COMPLEXES, ENCAPSULATION, HOST, host-guest chemistry, INCLUSION, MOLECULES, self-assembly, supramolecular chemistry, THERMODYNAMICS},
	isbn = {0570-0833},
	url = {<Go to ISI>://A1997XX18100014},
	author = {Chopra, N. and Sherman, J. C.}
}
