@article {2205,
	title = {Template-assembled synthetic G-quartets (TASQs)},
	journal = {Angewandte Chemie-International Edition},
	volume = {47},
	number = {26},
	year = {2008},
	note = {ISI Document Delivery No.: 317SSTimes Cited: 8Cited Reference Count: 38Nikan, Mehran Sherman, John C.},
	pages = {4900-4902},
	type = {Article},
	keywords = {cation, CAVITANDS, CHEMISTRY, DEOXYGUANOSINE, DERIVATIVES, G-quartets, GUANOSINE, HOST-GUEST COMPLEXATION, NUCLEOSIDES, NUCLEOTIDE, ORGANIC-SOLVENTS, QUADRUPLEX STRUCTURE, supramolecular, supramolecular chemistry, SYNTHESIS, TELOMERIC DNA OLIGONUCLEOTIDES, TEMPLATE},
	isbn = {1433-7851},
	url = {<Go to ISI>://000257040800022},
	author = {Nikan, M. and Sherman, J. C.}
}
@inbook {889,
	title = {De novo four-helix bundle proteins},
	booktitle = {Peptide Revolution: Genomics, Proteomics \& Therapeutics},
	year = {2004},
	note = {ISI Document Delivery No.: BEQ46Times Cited: 0Cited Reference Count: 7Huttunen, Heidi K. Sherman, John C.Proceedings Paper18th American Peptide SymposiumJUL 19-23, 2003BOSTON, MA1155 SIXTEENTH ST NW, WASHINGTON, DC 20036 USA},
	pages = {244-245},
	publisher = {Amer Chemical Soc},
	organization = {Amer Chemical Soc},
	address = {Washington},
	keywords = {CAVITANDS, TASP},
	isbn = {0-9715560-1-6},
	url = {<Go to ISI>://000238911100105},
	author = {Huttunen, H. K. and Sherman, J. C.},
	editor = {Chorev, M. and Sawyer, T. K.}
}
@article {736,
	title = {Molecules that can{\textquoteright}t resist templation},
	journal = {Chemical Communications},
	number = {14},
	year = {2003},
	note = {ISI Document Delivery No.: 696EETimes Cited: 26Cited Reference Count: 47},
	pages = {1617-1623},
	type = {Article},
	abstract = {The encapsulation of molecules or ions has captured the interest of a variety of researches, including those using zeolites, fullerenes, micelles, clathrates, and metal coordination complexes. Multiple hemispherical units have been used to create organic cages that can bind guests reversibly or irreversibly. Often such cages will only form in the presence of a guest, which acts as a template. This article summarizes some of the work in this field.},
	keywords = {CAPSULES, CARCEPLEXES, CAVITANDS, CONTAINER COMPOUNDS, CRYSTAL-STRUCTURE, HEMICARCEPLEXES, HOST-GUEST COMPLEXATION, PHASE, REVERSIBLE ENCAPSULATION, SHELL CLOSURE},
	isbn = {1359-7345},
	url = {<Go to ISI>://000183872700002},
	author = {Sherman, J.}
}
@article {452,
	title = {Formation of a tris-capsule and a tris-carceplex from a cyclic six-bowl assembly},
	journal = {Chemical Communications},
	number = {16},
	year = {2002},
	note = {ISI Document Delivery No.: 584WWTimes Cited: 8Cited Reference Count: 25},
	month = {Aug},
	pages = {1672-1673},
	type = {Article},
	abstract = {A macrocycle composed of six cavitands was assembled into a tris-capsule and a tris-carceplex, each of which encapsulates three guest molecules.},
	keywords = {CAVITANDS, CHEMISTRY, COMPLEXATION, COORDINATION, DIMERIC CAPSULE, HYDROGEN-BONDS, MOTION, ORGANIC-MOLECULES, REVERSIBLE MOLECULAR CAPSULES, TEMPLATION},
	isbn = {1359-7345},
	url = {<Go to ISI>://000177492600008},
	author = {Mungaroo, R. and Sherman, J. C.}
}
@article {462,
	title = {Synthesis and characterization of a disulfide-linked C-5-symmetric [5]carceplex},
	journal = {Journal of the American Chemical Society},
	volume = {124},
	number = {1},
	year = {2002},
	note = {ISI Document Delivery No.: 510QCTimes Cited: 23Cited Reference Count: 17},
	month = {Jan},
	pages = {16-17},
	type = {Article},
	keywords = {CARCEPLEXES, CAVITANDS, HOST GUEST COMPLEXATION},
	isbn = {0002-7863},
	url = {<Go to ISI>://000173217900008},
	author = {Naumann, C. and Place, S. and Sherman, J. C.}
}
@article {460,
	title = {Synthesis and characterization of upper and lower rim functionalized [6]cavitands},
	journal = {Chemistry-a European Journal},
	volume = {8},
	number = {16},
	year = {2002},
	note = {ISI Document Delivery No.: 587QETimes Cited: 2Cited Reference Count: 17},
	month = {Aug},
	pages = {3717-3723},
	type = {Article},
	abstract = {A [6]cavitand has been selectively derivatized on both the lower and upper rims. On the lower rim, two out of six potential sites were oxidized to produce a 1,4 substituted [6]cavitand bisketone, which was converted to a corresponding diol as well as a bisacetate [6]cavitand. The crystal structures of the bisketone and the diol were solved. On the upper rim, all six ArCH3 groups were selectively brominated to ArCH2Br groups to produce the hexabromomethyl [6]cavitand, which was converted to the corresponding hexabenzylthiol and hexabenzylthioacetate [6]cavitands. The conformational properties of all compounds are discussed.},
	keywords = {CAVITANDS, CHEMISTRY, interconversion, NMR spectroscopy, supramolecular chemistry},
	isbn = {0947-6539},
	url = {<Go to ISI>://000177652800016},
	author = {Naumann, C. and Patrick, B. O. and Sherman, J.}
}
@article {461,
	title = {Synthesis and conformational dynamics of ortho-xylyl-bridged-[4]cavitands},
	journal = {Tetrahedron},
	volume = {58},
	number = {4},
	year = {2002},
	note = {ISI Document Delivery No.: 515QLTimes Cited: 10Cited Reference Count: 24},
	month = {Jan},
	pages = {787-798},
	type = {Article},
	abstract = {ortho-Xylyl-[4]cavitands 2 to 6 were synthesized from bromoresorcin[4] arenes 1. Cavitands 2 to 6 show C-4nu symmetry in their H-1 NMR spectra at higher temperatures. Dynamic H-1 NMR studies of 2 to 6 indicate the C-4nu symmetry is due to fast interconversion of rectangular C-2nu isomers. This is supported by the crystal structure of 2a, which shows a C-2nu rectangular structure. The activation energy barriers for 2a and 2b were measured by quantitative 1D NOESY (EXSY) experiments. The results were analyzed by the initial rate approximation and matrix calculations. The activation energy barrier was found to depend strongly on the size of the upper rim group (Br, H, OH, CN). In addition, replacing the phenolic proton of tetrol derivatives 4a and 4b with metal ions raises the energy barrier further, likely via bridging metal cations. The two tetrabromo compounds (2a and 2b) reveal a sensitivity of the activation barrier to the feet of the cavitands. Cavitand 6 may act as a hub for radially expanded cavitands. The advantages of the 1D NOESY experiments over the more commonly used two-dimensional experiments are discussed. (C) 2002 Elsevier Science Ltd. All rights reserved.},
	keywords = {1D NOESY (EXSY), CARCEPLEXES, CAVITANDS, CHEMICAL-EXCHANGE, DEEP-CAVITY CAVITANDS, dynamic H-1 NMR, EXCHANGE, HEMICARCEPLEXES, KINETICS, MAGNETIC-RESONANCE SPECTROSCOPY, NMR},
	isbn = {0040-4020},
	url = {<Go to ISI>://000173506800019},
	author = {Naumann, C. and Patrick, B. O. and Sherman, J. C.}
}
@article {5154,
	title = {Expanding cavitand chemistry: The preparation and characterization of [n]cavitands with n >= 4},
	journal = {Chemistry-a European Journal},
	volume = {7},
	number = {8},
	year = {2001},
	note = {ISI Document Delivery No.: 426VFTimes Cited: 21Cited Reference Count: 26},
	month = {Apr},
	pages = {1637-1645},
	type = {Article},
	abstract = {{The preparation of cavitands composed of 4, 5, 6, and 7 aromatic subunits ([n]cavitands},
	keywords = {CAVITANDS, chemical exchange, CHEMICAL-EXCHANGE, CHEMISTRY, HOST GUEST COMPLEXATION, host-guest chemistry, KINETICS, NMR, supramolecular},
	isbn = {0947-6539},
	url = {<Go to ISI>://000168368500009},
	author = {Naumann, C. and Roman, E. and Peinador, C. and Ren, T. and Patrick, B. O. and Kaifer, A. E. and Sherman, J. C.}
}
@article {4771,
	title = {Bis-capsules: Cooperative reversible encapsulation of two molecules in adjacent separate chambers},
	journal = {Angewandte Chemie-International Edition},
	volume = {39},
	number = {1},
	year = {2000},
	note = {ISI Document Delivery No.: 273GWTimes Cited: 31Cited Reference Count: 27},
	pages = {194-+},
	type = {Article},
	keywords = {CALIXARENES, CARCEPLEXES, CAVITANDS, COMPLEXES, GUESTS, host-guest chemistry, HOSTS, HYDROGEN-BONDS, molecular recognition, NONCOVALENT INTERACTIONS, TEMPLATION},
	isbn = {1433-7851},
	url = {<Go to ISI>://000084700400026},
	author = {Chopra, N. and Naumann, C. and Sherman, J. C.}
}
@article {4510,
	title = {A giant carceplex permanently entraps three organic molecules},
	journal = {Angewandte Chemie-International Edition},
	volume = {38},
	number = {13-14},
	year = {1999},
	note = {ISI Document Delivery No.: 217RCTimes Cited: 52Cited Reference Count: 26},
	pages = {1955-1957},
	type = {Article},
	keywords = {CAPSULES, CARCEPLEXES, CAVITANDS, CRYSTAL-STRUCTURE, HOST GUEST COMPLEXATION, host-guest chemistry, inclusion compounds, SHELL CLOSURE, TEMPLATE SYNTHESIS},
	isbn = {1433-7851},
	url = {<Go to ISI>://000081511900022},
	author = {Chopra, N. and Sherman, J. C.}
}
@article {3935,
	title = {A bis(carceplex) from a cyclic tetramer of cavitands},
	journal = {Angewandte Chemie-International Edition in English},
	volume = {36},
	number = {16},
	year = {1997},
	note = {ISI Document Delivery No.: XX181Times Cited: 36Cited Reference Count: 35},
	month = {Sep},
	pages = {1727-1729},
	type = {Article},
	keywords = {CALIX<4>ARENE, CARCEPLEXES, CAVITANDS, CHANNELS, CHEMISTRY, COMPLEXES, ENCAPSULATION, HOST, host-guest chemistry, INCLUSION, MOLECULES, self-assembly, supramolecular chemistry, THERMODYNAMICS},
	isbn = {0570-0833},
	url = {<Go to ISI>://A1997XX18100014},
	author = {Chopra, N. and Sherman, J. C.}
}
@article {3322,
	title = {AN ASYMMETRIC CARCEPLEX AND NEW CRYSTAL-STRUCTURE YIELD INFORMATION REGARDING A 1-MILLION-FOLD TEMPLATE EFFECT},
	journal = {Journal of Organic Chemistry},
	volume = {60},
	number = {5},
	year = {1995},
	note = {ISI Document Delivery No.: QL605Times Cited: 48Cited Reference Count: 50},
	month = {Mar},
	pages = {1207-1213},
	type = {Article},
	abstract = {We report the incorporation of methyl {\textquoteright}{\textquoteright}feet{\textquoteright}{\textquoteright} as pendant groups in cavitands and carceplexes and their use in the creation of an asymmetric carceplex and the facilitation of the determination of the crystal structure of a carceplex. From the asymmetric carceplex, we have determined a 19 kcal/mol energy barrier to rotation of the guest pyrazine about the host{\textquoteright}s pseudo-C-2 axes, which demonstrates a high degree of complementarity between the shell of the carceplex and the guest pyrazine. The crystal structure reveals the extensive conjugation of the aryl ethers into the aromatic rings of the host when pyrazine is the guest. This result helps explain why pyrazine is, to date, the best template for the reaction to form the carceplex and thus provides insight to the powerful template effect that is the hallmark of this carceplex reaction. Thus, the investigation of this template effect provides a sensitive probe into noncovalent interactions in general and may be useful in the understanding of recognition in both natural systems such as enzyme/substrate complexes and in non-natural systems such as designed self-assembling structures.},
	keywords = {4 PORTALS, CAPTURE, CAVITANDS, CONSTRICTIVE BINDING, DERIVATIVES, HEMICARCERAND, HOST-GUEST COMPLEXATION, RELEASE},
	isbn = {0022-3263},
	url = {<Go to ISI>://A1995QL60500025},
	author = {Fraser, J. R. and Borecka, B. and Trotter, J. and Sherman, J. C.}
}
@article {3322,
	title = {AN ASYMMETRIC CARCEPLEX AND NEW CRYSTAL-STRUCTURE YIELD INFORMATION REGARDING A 1-MILLION-FOLD TEMPLATE EFFECT},
	journal = {Journal of Organic Chemistry},
	volume = {60},
	number = {5},
	year = {1995},
	note = {ISI Document Delivery No.: QL605Times Cited: 48Cited Reference Count: 50},
	month = {Mar},
	pages = {1207-1213},
	type = {Article},
	abstract = {We report the incorporation of methyl {\textquoteright}{\textquoteright}feet{\textquoteright}{\textquoteright} as pendant groups in cavitands and carceplexes and their use in the creation of an asymmetric carceplex and the facilitation of the determination of the crystal structure of a carceplex. From the asymmetric carceplex, we have determined a 19 kcal/mol energy barrier to rotation of the guest pyrazine about the host{\textquoteright}s pseudo-C-2 axes, which demonstrates a high degree of complementarity between the shell of the carceplex and the guest pyrazine. The crystal structure reveals the extensive conjugation of the aryl ethers into the aromatic rings of the host when pyrazine is the guest. This result helps explain why pyrazine is, to date, the best template for the reaction to form the carceplex and thus provides insight to the powerful template effect that is the hallmark of this carceplex reaction. Thus, the investigation of this template effect provides a sensitive probe into noncovalent interactions in general and may be useful in the understanding of recognition in both natural systems such as enzyme/substrate complexes and in non-natural systems such as designed self-assembling structures.},
	keywords = {4 PORTALS, CAPTURE, CAVITANDS, CONSTRICTIVE BINDING, DERIVATIVES, HEMICARCERAND, HOST-GUEST COMPLEXATION, RELEASE},
	isbn = {0022-3263},
	url = {<Go to ISI>://A1995QL60500025},
	author = {Fraser, J. R. and Borecka, B. and Trotter, J. and Sherman, J. C.}
}
@article {3520,
	title = {CARCEPLEXES AND HEMICARCEPLEXES - MOLECULAR ENCAPSULATION - FROM HOURS TO FOREVER},
	journal = {Tetrahedron},
	volume = {51},
	number = {12},
	year = {1995},
	note = {ISI Document Delivery No.: QN982Times Cited: 70Cited Reference Count: 124},
	month = {Mar},
	pages = {3395-3422},
	type = {Review},
	keywords = {4, CARBON NANOTUBES, CARCERANDS, CAVITANDS, CHEMISTRY, CONSTRICTIVE BINDING, CONTAINER COMPOUNDS, HEMICARCERANDS, HOST-GUEST COMPLEXATION, PORTALS, SHELL CLOSURE, supramolecular},
	isbn = {0040-4020},
	url = {<Go to ISI>://A1995QN98200001},
	author = {Sherman, J. C.}
}
@article {3343,
	title = {PROTOTYPE FOR A NEW FAMILY OF DE-NOVO PROTEINS},
	journal = {Tetrahedron Letters},
	volume = {36},
	number = {42},
	year = {1995},
	note = {ISI Document Delivery No.: RZ295Times Cited: 24Cited Reference Count: 30},
	month = {Oct},
	pages = {7587-7590},
	type = {Article},
	abstract = {We report the design, synthesis, and preliminary structural analysis of a four-helix bundle affixed to a rigid organic macrocycle.},
	keywords = {ASSEMBLED SYNTHETIC PROTEINS, CAVITANDS, CHANNEL, DESIGN, HOST GUEST COMPLEXATION, MOLECULAR, PEPTIDE, TASP, TOPOLOGY, VESSELS},
	isbn = {0040-4039},
	url = {<Go to ISI>://A1995RZ29500004},
	author = {Gibb, B. C. and Mezo, A. R. and Sherman, J. C.}
}
