@article {2630,
	title = {A new [4]carceplex, and a crystal structure and dynamic combinatorial chemistry of a [5]carceplex},
	journal = {Tetrahedron},
	volume = {65},
	number = {35},
	year = {2009},
	note = {ISI Document Delivery No.: 485CQTimes Cited: 1Cited Reference Count: 16Sun, Jianyu Patrick, Brian O. Sherman, John C.},
	month = {Aug},
	pages = {7296-7302},
	type = {Article},
	abstract = {A new [4]carceplex (2-guest) is reported. It is composed of two cavitands linked by four disulfide bonds. It forms twistomers, which interconvert on a millisecond timescale. The energy barrier for interconversion of twistomers is guest-dependent. Formation of [4]carceplex 2-guest is template dependent. The selectivity in templates is flat relative to most previous related template work. Larger kin [5]carceplex 1.guests were reinvestigated. A crystal structure confirms the twist between the hemispherical cavitands. Use of a redox buffer allowed dynamic combinatorial chemistry to be performed between pairs of templates. (C) 2009 Elsevier Ltd. All rights reserved.},
	keywords = {carceplex, Disulfide, Dynamic combinatorial chemistry, Guest release, HEMICARCEPLEXES, MOLECULES, supramolecular, TEMPLATION},
	isbn = {0040-4020},
	url = {<Go to ISI>://000269098700012},
	author = {Sun, J. Y. and Patrick, B. O. and Sherman, J. C.}
}
@article {678,
	title = {Template effect where 1-3 molecules drive formation of a trimer carceplex},
	journal = {Chemistry-a European Journal},
	volume = {9},
	number = {14},
	year = {2003},
	note = {ISI Document Delivery No.: 706XATimes Cited: 6Cited Reference Count: 46},
	month = {Jul},
	pages = {3253-3262},
	type = {Article},
	abstract = {The template effect in the formation of a trimer carceplex using 1-3 molecules as templates is explored. Thirteen different templates were studied and template ratios were measured for templates of like and unlike molecularity. Five transition-state models were studied for their binding abilities to see if these mirror the template ratios. The chemical shifts of the guests and the thermodynamic and kinetic values for templation suggest that binding is key, often tight, and that the guest determining step is formation of the last covalent bond. The molecular dynamics of guests as well as the conformational dynamics of both hosts and guests further addresses nature of the recognition between host and guest. Finally, we were surprised to discover that water can bind reversibly to the trimer carceplexes, which will have ramifications to any inner phase reactions conducted inside the cage.},
	keywords = {AMPLIFICATION, BARRIER, BINDING, CAPTURE, carceplex, CHEMISTRY, DIELS-ALDER REACTION, DYNAMICS, ELUCIDATION, ENCAPSULATION, HOST-GUEST COMPLEXATION, host-guest systems, molecular recognition, RESORCINARENE CAPSULE, REVERSIBLE, supramolecular, TEMPLATE SYNTHESIS},
	isbn = {0947-6539},
	url = {<Go to ISI>://000184479300009},
	author = {Makeiff, D. A. and Sherman, J. C.}
}
@article {4223,
	title = {Crystal structure and thermodynamics of reversible molecular capsules},
	journal = {Journal of the American Chemical Society},
	volume = {120},
	number = {25},
	year = {1998},
	note = {ISI Document Delivery No.: ZY238Times Cited: 60Cited Reference Count: 40},
	month = {Jul},
	pages = {6252-6260},
	type = {Article},
	abstract = {The reversible encapsulation of small molecules by two rigid hemispherical molecules is described. The "bowls" are linked by four charged hydrogen bonds. The complex is highly guest-selective. A crystal structure of one complex and a thermodynamic analysis of several complexes provide an unusually vivid description of the structure and dynamics of these complexes. The relevance of these complexes as transition state models for the formation of carceplexes is also presented.},
	keywords = {BARRIER, carceplex, ENCAPSULATION, HOST GUEST COMPLEXATION, ORGANIC-MOLECULES},
	isbn = {0002-7863},
	url = {<Go to ISI>://000074600100009},
	author = {Chapman, R. G. and Olovsson, G. and Trotter, J. and Sherman, J. C.}
}
@article {4223,
	title = {Crystal structure and thermodynamics of reversible molecular capsules},
	journal = {Journal of the American Chemical Society},
	volume = {120},
	number = {25},
	year = {1998},
	note = {ISI Document Delivery No.: ZY238Times Cited: 60Cited Reference Count: 40},
	month = {Jul},
	pages = {6252-6260},
	type = {Article},
	abstract = {The reversible encapsulation of small molecules by two rigid hemispherical molecules is described. The "bowls" are linked by four charged hydrogen bonds. The complex is highly guest-selective. A crystal structure of one complex and a thermodynamic analysis of several complexes provide an unusually vivid description of the structure and dynamics of these complexes. The relevance of these complexes as transition state models for the formation of carceplexes is also presented.},
	keywords = {BARRIER, carceplex, ENCAPSULATION, HOST GUEST COMPLEXATION, ORGANIC-MOLECULES},
	isbn = {0002-7863},
	url = {<Go to ISI>://000074600100009},
	author = {Chapman, R. G. and Olovsson, G. and Trotter, J. and Sherman, J. C.}
}
@article {4224,
	title = {Reversible molecular capsules composed of two cavitands linked via an assortment of charged-hydrogen bonds and covalent bonds},
	journal = {Journal of the American Chemical Society},
	volume = {120},
	number = {38},
	year = {1998},
	note = {ISI Document Delivery No.: 125EVTimes Cited: 42Cited Reference Count: 29},
	month = {Sep},
	pages = {9818-9826},
	type = {Article},
	abstract = {Six new cavitand bowls are reported (6, 7, 8, 9, 11, and 12), as are three bis-bowl compounds (4, 13, and 14). Eight new complexes (4.guest, 7C.guest, 8C.guest, 9C.guest, 14.guest, 15.guest, 15C.guest, and 16C.guest) that reversibly encapsulate small molecules are reported. Two or more charged-hydrogen bonds (CHBs) or covalent linkages between the bowls are required to form stable complexes. Guest exchange rates vary from milliseconds to days. Thermodynamically, these complexes display an enthalpy-entropy compensation. The relative stability of complex 3.pyrazine versus complex 3.chloroform is 170000 in nitrobenzene-d(5) at 298 It. Apparent stability constants in nitrobenzene-d(5) at 298 K yield 1.1 x 10(9) M-1 for complex 3.pyrazine. The absolute stability constant for complex 4.pyrazine in nitrobenzene-d(5) at 333 K is 3.5 x 10(6) M-1.},
	keywords = {BINDING, carceplex, CHEMISTRY, ENCAPSULATION, HEMICARCERANDS, HOST-GUEST COMPLEXATION, ORGANIC-MOLECULES, RELEASE, TEMPLATION},
	isbn = {0002-7863},
	url = {<Go to ISI>://000076225200012},
	author = {Chapman, R. G. and Sherman, J. C.}
}
