@article {2630,
	title = {A new [4]carceplex, and a crystal structure and dynamic combinatorial chemistry of a [5]carceplex},
	journal = {Tetrahedron},
	volume = {65},
	number = {35},
	year = {2009},
	note = {ISI Document Delivery No.: 485CQTimes Cited: 1Cited Reference Count: 16Sun, Jianyu Patrick, Brian O. Sherman, John C.},
	month = {Aug},
	pages = {7296-7302},
	type = {Article},
	abstract = {A new [4]carceplex (2-guest) is reported. It is composed of two cavitands linked by four disulfide bonds. It forms twistomers, which interconvert on a millisecond timescale. The energy barrier for interconversion of twistomers is guest-dependent. Formation of [4]carceplex 2-guest is template dependent. The selectivity in templates is flat relative to most previous related template work. Larger kin [5]carceplex 1.guests were reinvestigated. A crystal structure confirms the twist between the hemispherical cavitands. Use of a redox buffer allowed dynamic combinatorial chemistry to be performed between pairs of templates. (C) 2009 Elsevier Ltd. All rights reserved.},
	keywords = {carceplex, Disulfide, Dynamic combinatorial chemistry, Guest release, HEMICARCEPLEXES, MOLECULES, supramolecular, TEMPLATION},
	isbn = {0040-4020},
	url = {<Go to ISI>://000269098700012},
	author = {Sun, J. Y. and Patrick, B. O. and Sherman, J. C.}
}
@article {1189,
	title = {A six-bowl carceplex that entraps seven guest molecules},
	journal = {Journal of the American Chemical Society},
	volume = {127},
	number = {35},
	year = {2005},
	note = {ISI Document Delivery No.: 961BOTimes Cited: 24Cited Reference Count: 63},
	month = {Sep},
	pages = {12363-12367},
	type = {Article},
	abstract = {A six-bowl carceplex that entraps seven guest molecules, 5(.)(DMSO)(7), was synthesized and characterized. The dynamics of the host shell was studied in solution in the absence and presence of water. A multiple-molecule template was found to drive the formation of 5(.)(DMSO)(x)(.)G((7-x)) (G = DMA, DMF; x = 5-7). Higher selectivity was found for species containing greater numbers of DMSO molecules.},
	keywords = {CAPTURE, COMPLEXATION, CONTAINER COMPOUNDS, COORDINATION CAGES, DIFFUSION NMR, HEMICARCERANDS, ORGANIC-MOLECULES, RESORCINARENE CAPSULE, REVERSIBLE ENCAPSULATION, TEMPLATION},
	isbn = {0002-7863},
	url = {<Go to ISI>://000231637100064},
	author = {Makeiff, D. A. and Sherman, J. C.}
}
@article {452,
	title = {Formation of a tris-capsule and a tris-carceplex from a cyclic six-bowl assembly},
	journal = {Chemical Communications},
	number = {16},
	year = {2002},
	note = {ISI Document Delivery No.: 584WWTimes Cited: 8Cited Reference Count: 25},
	month = {Aug},
	pages = {1672-1673},
	type = {Article},
	abstract = {A macrocycle composed of six cavitands was assembled into a tris-capsule and a tris-carceplex, each of which encapsulates three guest molecules.},
	keywords = {CAVITANDS, CHEMISTRY, COMPLEXATION, COORDINATION, DIMERIC CAPSULE, HYDROGEN-BONDS, MOTION, ORGANIC-MOLECULES, REVERSIBLE MOLECULAR CAPSULES, TEMPLATION},
	isbn = {1359-7345},
	url = {<Go to ISI>://000177492600008},
	author = {Mungaroo, R. and Sherman, J. C.}
}
@article {4771,
	title = {Bis-capsules: Cooperative reversible encapsulation of two molecules in adjacent separate chambers},
	journal = {Angewandte Chemie-International Edition},
	volume = {39},
	number = {1},
	year = {2000},
	note = {ISI Document Delivery No.: 273GWTimes Cited: 31Cited Reference Count: 27},
	pages = {194-+},
	type = {Article},
	keywords = {CALIXARENES, CARCEPLEXES, CAVITANDS, COMPLEXES, GUESTS, host-guest chemistry, HOSTS, HYDROGEN-BONDS, molecular recognition, NONCOVALENT INTERACTIONS, TEMPLATION},
	isbn = {1433-7851},
	url = {<Go to ISI>://000084700400026},
	author = {Chopra, N. and Naumann, C. and Sherman, J. C.}
}
@article {4754,
	title = {Restricted motion of guests confined in carceplexes and capsules},
	journal = {Journal of Organic Chemistry},
	volume = {65},
	number = {2},
	year = {2000},
	note = {ISI Document Delivery No.: 276YFTimes Cited: 25Cited Reference Count: 21},
	month = {Jan},
	pages = {513-516},
	type = {Article},
	abstract = {Guest orientation within carceplexes and capsules was determined qualitatively from NMR data, and the molecular mobility of guests was determined via coalescence of H-1 NMR signals. Both are highly dependent on guest size and shape, as is interconversion of twistomers. Incarceration of 1,4-thioxane results in a large (1.8 kcal/mol) constraint on thioxane{\textquoteright}s conformational mobility (chair-to-chair interconversion). Similar conformational constraints (1.6 kcal/mol) were determined for 1,4-dioxane both when incarcerated in carceplex 1b and when encapsulated reversibly in capsule 3b. Encapsulation-induced conformational constraints of this magnitude are unprecedented, and are particularly striking for the noncovalently linked capsules.},
	keywords = {CRYSTAL-STRUCTURE, TEMPLATION},
	isbn = {0022-3263},
	url = {<Go to ISI>://000084905400036},
	author = {Chapman, R. G. and Sherman, J. C.}
}
@article {4224,
	title = {Reversible molecular capsules composed of two cavitands linked via an assortment of charged-hydrogen bonds and covalent bonds},
	journal = {Journal of the American Chemical Society},
	volume = {120},
	number = {38},
	year = {1998},
	note = {ISI Document Delivery No.: 125EVTimes Cited: 42Cited Reference Count: 29},
	month = {Sep},
	pages = {9818-9826},
	type = {Article},
	abstract = {Six new cavitand bowls are reported (6, 7, 8, 9, 11, and 12), as are three bis-bowl compounds (4, 13, and 14). Eight new complexes (4.guest, 7C.guest, 8C.guest, 9C.guest, 14.guest, 15.guest, 15C.guest, and 16C.guest) that reversibly encapsulate small molecules are reported. Two or more charged-hydrogen bonds (CHBs) or covalent linkages between the bowls are required to form stable complexes. Guest exchange rates vary from milliseconds to days. Thermodynamically, these complexes display an enthalpy-entropy compensation. The relative stability of complex 3.pyrazine versus complex 3.chloroform is 170000 in nitrobenzene-d(5) at 298 It. Apparent stability constants in nitrobenzene-d(5) at 298 K yield 1.1 x 10(9) M-1 for complex 3.pyrazine. The absolute stability constant for complex 4.pyrazine in nitrobenzene-d(5) at 333 K is 3.5 x 10(6) M-1.},
	keywords = {BINDING, carceplex, CHEMISTRY, ENCAPSULATION, HEMICARCERANDS, HOST-GUEST COMPLEXATION, ORGANIC-MOLECULES, RELEASE, TEMPLATION},
	isbn = {0002-7863},
	url = {<Go to ISI>://000076225200012},
	author = {Chapman, R. G. and Sherman, J. C.}
}
