@article {452, title = {Formation of a tris-capsule and a tris-carceplex from a cyclic six-bowl assembly}, journal = {Chemical Communications}, number = {16}, year = {2002}, note = {ISI Document Delivery No.: 584WWTimes Cited: 8Cited Reference Count: 25}, month = {Aug}, pages = {1672-1673}, type = {Article}, abstract = {A macrocycle composed of six cavitands was assembled into a tris-capsule and a tris-carceplex, each of which encapsulates three guest molecules.}, keywords = {CAVITANDS, CHEMISTRY, COMPLEXATION, COORDINATION, DIMERIC CAPSULE, HYDROGEN-BONDS, MOTION, ORGANIC-MOLECULES, REVERSIBLE MOLECULAR CAPSULES, TEMPLATION}, isbn = {1359-7345}, url = {://000177492600008}, author = {Mungaroo, R. and Sherman, J. C.} } @article {4874, title = {Template effects in the formation of a tetramethylene-bridged hemicarceplex}, journal = {Journal of the American Chemical Society}, volume = {122}, number = {7}, year = {2000}, note = {ISI Document Delivery No.: 289TZTimes Cited: 20Cited Reference Count: 57}, month = {Feb}, pages = {1337-1342}, type = {Article}, abstract = {We report a study of the template effect in the formation of tetramethylene-bridged hemicarceplex 7.guest. Two tetrol cavitands were bridged with 1,4-dibromobutane in the presence of suitable template (guest) molecules in N-formylpiperidine as solvent. Selectivity was observed when competing templates were present during the reaction: the relative templating abilities (template ratios) of 30 different guest molecules range by 3600-fold, and manifest a significant preference for para-disubstituted benzenes. Twenty-one of the 30 hemicarceplexes used in this templation study are new. The trend in guest selectivity is markedly different from previous studies in which smaller cavities (e.g., carceplex 2.guest) are formed. In such studies, capsule 3.guest was a good transition state model, whereas this is not the case in the present work.}, keywords = {2 BOWLS, BINDING-PROPERTIES, CARCEPLEXES, CONTAINER, CRYSTAL-STRUCTURE, ENCAPSULATION, METAL-ION, O-BENZYNE, REVERSIBLE MOLECULAR CAPSULES, zeolites}, isbn = {0002-7863}, url = {://000085639200011}, author = {Makeiff, D. A. and Pope, D. J. and Sherman, J. C.} } @article {4577, title = {Carceplexes and hemicarceplexes}, journal = {Chemical Reviews}, volume = {99}, number = {4}, year = {1999}, note = {ISI Document Delivery No.: 189WZTimes Cited: 258Cited Reference Count: 229}, month = {Apr}, pages = {931-967}, type = {Review}, keywords = {CONSTRICTIVE BINDING, CRYSTAL-STRUCTURE, DIELS-ALDER REACTION, ENDOHEDRAL METALLOFULLERENES, ENERGY-TRANSFER, HOST-GUEST COMPLEXATION, HYDROGEN-BONDING PREFERENCES, REVERSIBLE MOLECULAR CAPSULES, SELF-ASSEMBLED MONOLAYERS, supramolecular chemistry, TRIPLET}, isbn = {0009-2665}, url = {://000079930300001}, author = {Jasat, A. and Sherman, J. C.} }