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(eta(5)-cyclopentadienyl)oxo(peroxo-O,O’)-(trimethylsilylmethyl)tungsten and the related (eta(5)-pentamethylcyclopentadienyl)-oxo(peroxo-O,O’)(trimethylsilylmeth yl)-tungsten-tetracyanoethylene(2/1) complex

Title(eta(5)-cyclopentadienyl)oxo(peroxo-O,O’)-(trimethylsilylmethyl)tungsten and the related (eta(5)-pentamethylcyclopentadienyl)-oxo(peroxo-O,O’)(trimethylsilylmeth yl)-tungsten-tetracyanoethylene(2/1) complex
Publication TypeJournal Article
Year of Publication1995
AuthorsLegzdins, P, Phillips, EC, Trotter, J, Yee, VC
JournalActa Crystallographica Section C-Crystal Structure Communications
Volume51
Pagination2498-2501
Date PublishedDec
Type of ArticleArticle
ISBN Number0108-2701
KeywordsALKYL, TUNGSTEN
Abstract

{The two organometallic molecules, [WO(C5H5)(C4H11Si)(O-2)] and [WO(C10H15)(C4H11Si)(O-2)] [2:1 complex with C6N4 (TCNE, ethenetetracafbonitrile)], have similar piano-stool structures and separate oxo and peroxo ligands [W-O(oxo) = 1.69(3) and 1.727(7), W-O(peroxo) = 1.91 (mean)

URL<Go to ISI>://A1995TT22500018