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A formal, enantiospecific synthesis of pseudoguaianolides

TitleA formal, enantiospecific synthesis of pseudoguaianolides
Publication TypeJournal Article
Year of Publication1996
AuthorsMoney, T, Wong, MKC
JournalTetrahedron
Volume52
Pagination6307-6324
Date PublishedApr
Type of ArticleArticle
ISBN Number0040-4020
Keywords(+)-CONFERTIN, (+/-)-CONFERTIN, ANTI-TUMOR LACTONES, CAMPHOR DERIVATIVES, DL-HELENALIN, inhibitors, ROUTE, SESQUITERPENE LACTONES, STEROID-SYNTHESIS, SYSTEM
Abstract

The preparation of ketal-enone (3) and hydroxy-ketones (1a), (16), and (4a), from (-)-camphor (6) represents a formal enantiospecific synthesis of (+)-carpesiolin, (+)-confertin, (-)-damsin, (-)-helenalin, (+)-bigelovin, (+)-mexicanin I, and (+)-linifolin A. Copyright (C) 1996 Elsevier Science Ltd

URL<Go to ISI>://A1996UH37800004