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Macromolecular complexation of poly(methylenephosphine) to gold(I): a facile route to highly metallated polymers

TitleMacromolecular complexation of poly(methylenephosphine) to gold(I): a facile route to highly metallated polymers
Publication TypeJournal Article
Year of Publication2008
AuthorsGillon, BH, Patrick, BO, Gates, DP
JournalChemical Communications
Pagination2161-2163
Date PublishedMay
Type of ArticleArticle
ISBN Number1359-7345
Keywordsaddition polymerization, AMBIENT-TEMPERATURE, ANIONIC-POLYMERIZATION, BONDS, conjugated polymers, COORDINATION POLYMER, COPOLYMERIZATION, LIGANDS, OLIGOMERS, PHOSPHAALKENE
Abstract

Alternating phosphorus-carbon polymers are found to be effective ligands for gold( I) to afford [MesP( AuCl)-CPh2](n), a new class of macromolecule with high gold content.

URL<Go to ISI>://000255425800023