Research & Teaching Faculty

Default Header Image

The solid-state molecular structure of W(NO)(3)Cl-3 and the nature of its W-NO bonding

TitleThe solid-state molecular structure of W(NO)(3)Cl-3 and the nature of its W-NO bonding
Publication TypeJournal Article
Year of Publication2004
AuthorsHayton, TW, Patrick, BO, Legzdins, P, McNeil, WS
JournalCanadian Journal of Chemistry-Revue Canadienne De Chimie
Volume82
Pagination285-292
Date PublishedFeb
Type of ArticleArticle
ISBN Number0008-4042
Keywordsbonding, CARBONYL, CHEMISTRY, CRYSTAL-STRUCTURE, DERIVATIVES, DICHLORODINITROSYLTUNGSTEN, DICHLOROTRINITROSYLVANADIUM, MOLYBDENUM, MONONUCLEAR, NITROSYL, NITROSYL COMPLEXES, STRUCTURE, TUNGSTEN
Abstract

{The monomeric trinitrosyl complex, W(NO)(3)Cl-3, can be prepared by the treatment of WCl6 in CH2Cl2 with NO gas, and its identity has been unambiguously confirmed by a single-crystal X-ray diffraction analysis. The complex crystallizes in the space group Pmn2(1) as a three-component twin (a = 10.4280(4) Angstrom

URL<Go to ISI>://000220138500024