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11,12-bis(diethylaminomethyl)-9,10-dihydro-9,10-ethenoanthracene: A probe for the heavy atom effect in solid state photoreactions

Title11,12-bis(diethylaminomethyl)-9,10-dihydro-9,10-ethenoanthracene: A probe for the heavy atom effect in solid state photoreactions
Publication TypeJournal Article
Year of Publication1999
AuthorsIhmels, H, Patrick, BO, Scheffer, JR, Trotter, J
JournalTetrahedron
Volume55
Pagination2171-2182
Date PublishedFeb
Type of ArticleArticle
ISBN Number0040-4020
KeywordsCRYSTALLINE, MOLECULES, ORGANIC-PHOTOCHEMISTRY, REACTIVITY, SALTS
Abstract

The photochemistry of title compound 2 and its hydrogen halide salts was investigated in solution and in the solid state. In the solid state the halide ions were shown to cause a heavy atom effect that was not observed in solution. The orientation of the halide ions towards the chromophore was determined on the basis of the corresponding structures in the solid state as determined by X-ray crystallography. (C) 1999 Elsevier Science Ltd. All rights reserved.
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