| Title | Analyte-additive interactions in nonaqueous capillary electrophoresis: a critical review |
| Publication Type | Journal Article |
| Year of Publication | 1998 |
| Authors | Bowser, MT, Kranack, AR, Chen, DDY |
| Journal | Trac-Trends in Analytical Chemistry |
| Volume | 17 |
| Pagination | 424-434 |
| Date Published | Aug |
| Type of Article | Review |
| ISBN Number | 0165-9936 |
| Keywords | ANIONS, CHIRAL SEPARATION, cohesion energy, density, dielectric constant, electron donor-acceptor interaction, FORMAMIDE, ION, MEDIA, nonaqueous capillary electrophoresis, SEPARATION SELECTIVITY, solvent effect, SOLVENTS, SURFACTANTS, WATER, ZONE ELECTROPHORESIS |
| Abstract | This article reviews the recent developments in nonaqueous capillary electrophoresis and discusses the effect of the solvent on analyte-additive interactions. When nonaqueous solvents are used, solvophobic interactions are generally weaker than those in water; therefore, those additives that can change the analyte mobility through electrostatic or donor-acceptor interactions should be further explored. (C) 1998 Elsevier Science B.V. All rights reserved. |
| URL | <Go to ISI>://000075202300022 |
