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Anthracene as a Launchpad for a Phosphinidene Sulfide and for Generation of a Phosphorus-Sulfur Material Having the Composition P2S, a Vulcanized Red Phosphorus That Is Yellow

TitleAnthracene as a Launchpad for a Phosphinidene Sulfide and for Generation of a Phosphorus-Sulfur Material Having the Composition P2S, a Vulcanized Red Phosphorus That Is Yellow
Publication TypeJournal Article
Year of Publication2019
AuthorsTransue, WJ, Nava, M, Terban, MW, Yang, J, Greenberg, MW, Wu, G, Foreman, ES, Mustoe, CL, Kennepohl, P, Owen, JS, Billinge, SJL, Kulik, HJ, Cummins, CC
JournalJOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume141
Pagination431-440
Date PublishedJAN 9
ISSN0002-7863
Abstract

{Thermolysis of a pair of dibenzo-7-phosphanorbornadiene compounds is shown to lead to differing behaviors: phosphinidene sulfide release and formation of amorphous P2S. These compounds, (BuP)-Bu-t(S)A (1

DOI10.1021/jacs.8b10775