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  3. ANTIMONY(III) FLUORIDE FLUOROSULFATES - SYNTHESES AND MOLECULAR-STRUCTURES OF ANTIMONY(III) DIFLUORIDE FLUOROSULFATE [SBF2(SO3F)](X), ANTIMONY(III) FLUORIDE BIS(FLUOROSULFATE) [SBF(SO3F)(2)](X), AND ANTIMONY(III) TRIS(FLUOROSULFATE) [SB(SO3F)(3)](X)

ANTIMONY(III) FLUORIDE FLUOROSULFATES - SYNTHESES AND MOLECULAR-STRUCTURES OF ANTIMONY(III) DIFLUORIDE FLUOROSULFATE [SBF2(SO3F)](X), ANTIMONY(III) FLUORIDE BIS(FLUOROSULFATE) [SBF(SO3F)(2)](X), AND ANTIMONY(III) TRIS(FLUOROSULFATE) [SB(SO3F)(3)](X)

TitleANTIMONY(III) FLUORIDE FLUOROSULFATES - SYNTHESES AND MOLECULAR-STRUCTURES OF ANTIMONY(III) DIFLUORIDE FLUOROSULFATE [SBF2(SO3F)](X), ANTIMONY(III) FLUORIDE BIS(FLUOROSULFATE) [SBF(SO3F)(2)](X), AND ANTIMONY(III) TRIS(FLUOROSULFATE) [SB(SO3F)(3)](X)
Publication TypeJournal Article
Year of Publication1995
AuthorsZhang, DL, Rettig, SJ, Trotter, J, Aubke, F
JournalInorganic Chemistry
Volume34
Pagination3153-3164
Date PublishedJun
Type of ArticleArticle
ISBN Number0020-1669
KeywordsCRYSTAL-STRUCTURE, DERIVATIVES, MOSSBAUER, SPECTRA
Abstract

{Following unsuccessful attempts to confirm the existence of previously reported antimony(I) fluorosulfate, Sb(SO3F), the reaction of antimony and fluorosulfuric acid is reinvestigated and synthetic routes are developed that allow the preparation of polymeric [SbF2(SO3F)](x), [SbF(SO3F)(2)](x), and [Sb(SO3F)(3)](x). Recrystallization from fluorosulfuric acid is found to produce single crystals of all three materials, which are suitable for molecular structure determinations by single-crystal X-ray diffraction. Crystals of [SbF2(SO3F)](x) are orthorhombic
URL<Go to ISI>://A1995RC42400005