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An aurophilicity-determined 3-D bimetallic coordination polymer: using [Au(CN)(2)](-) to increase structural dimensionality through gold center dot center dot center dot gold bonds in (tmeda)Cu[Au(CN)(2)](2)

TitleAn aurophilicity-determined 3-D bimetallic coordination polymer: using [Au(CN)(2)](-) to increase structural dimensionality through gold center dot center dot center dot gold bonds in (tmeda)Cu[Au(CN)(2)](2)
Publication TypeJournal Article
Year of Publication2001
AuthorsLeznoff, DB, Xue, BY, Patrick, BO, Sanchez, V, Thompson, RC
JournalChemical Communications
Pagination259-260
Type of ArticleArticle
ISBN Number1359-7345
KeywordsBUILDING-BLOCKS, CHEMISTRY, COMPONENT, CRYSTAL-STRUCTURE, LIGANDS, MAGNETIC-PROPERTIES, NETWORK
Abstract

A coordination polymer with the [Au(CN)(2)](-) building block has been prepared and it exhibits weak Au(I)-mediated ferromagnetic interactions; the structure illustrates that aurophilicity is a powerful tool to increase dimensionality, generating a three-dimensional system from a 1-D polymer.

URL<Go to ISI>://000166635200017