Title | beta,beta’-Dihydroxylation of meso-tetraphenylchlorins and metallochlorins |
Publication Type | Journal Article |
Year of Publication | 1995 |
Authors | Bruckner, C, Dolphin, D |
Journal | Tetrahedron Letters |
Volume | 36 |
Pagination | 9425-9428 |
Date Published | Dec |
Type of Article | Article |
ISBN Number | 0040-4039 |
Keywords | PORPHYRIN |
Abstract | meso-Tetraphenylchlorin and 2,3-vic-dihydroxy-meso-tetraphenylchlorin and their zinc complexes were dihydroxylated by stoichiometric amounts of OsO4. The chlorins gave specifically 2,3-vic-dihydroxy-meso-tetraphenylbacteriochlorins or 2,3, 12,13-bis-(vic-dihydroxy)bacteriochlorins while the Zn(II)-chlorins gave (2,3-vic-dihydroxy-meso-tetraphenylisobacteriochlorinato) Zn(II) or [2,3,7,8-bis-(vic-dihydroxy)-meso-tetraphenylisobacteriochlorinato]Zn(II ). |
URL | <Go to ISI>://A1995TM14800002 |