Bis(carbonyl)platinum(II) derivatives: Molecular structure of cis-Pt(CO)(2)(SO3F)(2), complete vibrational analysis of cis-Pt(CO)(2)Cl-2, and attempted synthesis of cis-Pt(CO)(2)F-2

{As part of a comprehensive study of square planar palladium(II) and platinum(II) carbonyl derivatives, the molecular structure of cis-Pt(CO)(2)(SO3F)(2), the complete vibrational spectra of cis-Pt(CO)(2)Cl-2 and the attempted synthesis of cis-Pt(CO)(2)F-2 an reported. cis-Pt(CO)(2)(SO3F)(2) is isostructural with cis-Pd(CO) (2)(SO3F)(2) and crystallizes in the monoclinic space group P2(1)/n (no. 14). Crystal data: a = 7.419(1) Angstrom; b = 14.751(2) Angstrom; c 8.634(1) Angstrom; beta = 89.95(1)degrees; V = 934.9(2) Angstrom(3); Z = 4; T = 300 K; R [F-o > 4 sigma(F-o)] = 0.0447 and wR2 = 0.1097. The internal bond parameters of the cis-Pt(CO)(2)(SO3F)(2) are compared to those of cis-Pd(CO)(2)(SO3F)(2), cis-Pt(CO)(2)Cl-2, and [M(CO)(4)](2+)