Title | Briarane, erythrane, and aquariane diterpenoids from the Caribbean gorgonian Erythropodium caribaeorum |
Publication Type | Journal Article |
Year of Publication | 2003 |
Authors | Taglialatela-Scafati, O, Craig, KS, Reberioux, D, Roberge, M, Andersen, RJ |
Journal | European Journal of Organic Chemistry |
Pagination | 3515-3523 |
Date Published | Sep |
Type of Article | Article |
ISBN Number | 1434-193X |
Keywords | asymmetric, bioorganic chemistry, ELEUTHEROBIN, ERYTHROLIDES, natural products, structure elucidation, SYNTHESIS, terpenoids |
Abstract | Seven new diterpenoids belonging to the briarane [erythrolides R (5), S (6), T (7), and U (8)], erythrane [erythrolide V (9)], and aquariane [aquariolides B (10) and C (11)] skeletal classes have been isolated from the encrusting gorgonian Erythropodium caribaeorum. The structures of the new compounds were elucidated by spectroscopic analysis and chemical interconversions. A biogenetic proposal that links carbon skeletons found in E. caribaeorum diterpenoids is presented. (C) Wiley-VCH Verlag GmbH Co. |
URL | <Go to ISI>://000185592300005 |