| Title | Briarane, erythrane, and aquariane diterpenoids from the Caribbean gorgonian Erythropodium caribaeorum |
| Publication Type | Journal Article |
| Year of Publication | 2003 |
| Authors | Taglialatela-Scafati, O, Craig, KS, Reberioux, D, Roberge, M, Andersen, RJ |
| Journal | European Journal of Organic Chemistry |
| Pagination | 3515-3523 |
| Date Published | Sep |
| Type of Article | Article |
| ISBN Number | 1434-193X |
| Keywords | asymmetric, bioorganic chemistry, ELEUTHEROBIN, ERYTHROLIDES, natural products, structure elucidation, SYNTHESIS, terpenoids |
| Abstract | Seven new diterpenoids belonging to the briarane [erythrolides R (5), S (6), T (7), and U (8)], erythrane [erythrolide V (9)], and aquariane [aquariolides B (10) and C (11)] skeletal classes have been isolated from the encrusting gorgonian Erythropodium caribaeorum. The structures of the new compounds were elucidated by spectroscopic analysis and chemical interconversions. A biogenetic proposal that links carbon skeletons found in E. caribaeorum diterpenoids is presented. (C) Wiley-VCH Verlag GmbH Co. |
| URL | <Go to ISI>://000185592300005 |