Title | Cationic indium catalysts for ring opening polymerization: tuning reactivity with hemilabile ligands |
Publication Type | Journal Article |
Year of Publication | 2020 |
Authors | Goonesinghe, C, Roshandel, H, Diaz, C, Jung, H-J, Nyamayaro, K, Ezhova, M, Mehrkhodavandi, P |
Journal | CHEMICAL SCIENCE |
Volume | 11 |
Pagination | 6485-6491 |
Date Published | JUL 7 |
ISSN | 2041-6520 |
Abstract | This is a comprehensive study of the effects of rationally designed hemilabile ligands on the stability, reactivity, and change in catalytic behavior of indium complexes. We report cationic alkyl indium complexes supported by a family of hemi-salen type ligands bearing hemilabile thiophenyl (2a), furfuryl (2b) and pyridyl (2c) pendant donor arms. Shelf-life and stability of these complexes followed the trend2a<2b<2c, showing direct correlation to the affinity of the pendant donor group to the indium center. Reactivity towards polymerization of epichlorohydrin and cyclohexene oxide followed the trend2a>2b>2cwith control of polymerization following an inverse relationship to reactivity. Surprisingly,2cpolymerizedracemiclactide without an external initiator, likely through an alkyl-initiated coordination-insertion mechanism. |
DOI | 10.1039/d0sc01291b |
