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Cationic iron(III) complex with a hexadentate N-2,N ’(2),O-2-aminopyridylphenolate ligand

TitleCationic iron(III) complex with a hexadentate N-2,N ’(2),O-2-aminopyridylphenolate ligand
Publication TypeJournal Article
Year of Publication1999
AuthorsSetyawati, IA, Rettig, SJ, Orvig, C
JournalCanadian Journal of Chemistry-Revue Canadienne De Chimie
Volume77
Pagination2033-2038
Date PublishedDec
Type of ArticleArticle
ISBN Number0008-4042
KeywordsANALOGS, BINDING-SITE, CATIONIC, CRYSTAL-STRUCTURE, gallium, hexadentate, indium, iron( III), LACTOFERRIN, MODEL, OXO, phenolate, PROTEINS, pyridyl
Abstract

{Iron(III) complexation with potentially hexadentate H(2)bbpen (N,N’-bis(2-hydroxybenzyl)-N,N’-bis(2-methylpyridyl)ethylenediamine) was studied. The resulting monocationic complex, [Fe(bbpen)](+) as its NO3- and PF6- salts, was characterized by infrared spectroscopy, mass spectrometry, elemental analyses, cyclic voltammetry, and X-ray crystallographic analysis. Crystals of [Fe(bbpen)]NO3. CH3OH are monoclinic, space group P2(1)/c

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