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  3. A cis-dioxomolybdenum(VI) complex, [MoN2C3H3C(Me)(2)O(2)(O)(2)]

A cis-dioxomolybdenum(VI) complex, [MoN2C3H3C(Me)(2)O(2)(O)(2)]

TitleA cis-dioxomolybdenum(VI) complex, [MoN2C3H3C(Me)(2)O(2)(O)(2)]
Publication TypeJournal Article
Year of Publication1998
AuthorsEhlert, MK, Rettig, SJ, Storr, A, Trotter, J
JournalActa Crystallographica Section C-Crystal Structure Communications
Volume54
Pagination473-475
Date PublishedApr
Type of ArticleArticle
ISBN Number0108-2701
KeywordsATOM TRANSFER-REACTIONS
Abstract

In the cis-dioxomolybdenum(VI) complex bis[1-methyl-1-(1–pyrazolyl) ethanolato-N-2,O]dioxomolybden [Mo(O)(2)(C6H9N2O)(2)] or C12H18MoN4O4, the Mo atom has distorted octahedral coordination to two (cis) oxo ligands, and two N and two O atoms of the two substituted pyrazole ligands. Mo-O-oxo bond distances [mean 1.698(6)Angstrom] correspond to double bonds, Mo-O-oxy [mean 1.951(2)Angstrom] to single bonds, and Mo-N bonds [mean 2,326(3)Angstrom] are lengthened as a result of the effect of the oxo ligands, which are trans to the N atoms.
URL<Go to ISI>://000073458300013