Title | A comparison of bulk metal nitride catalysts for pyridine hydrodenitrogenation |
Publication Type | Journal Article |
Year of Publication | 1998 |
Authors | Milad, IK, Smith, KJ, Wong, PC, Mitchell, KAR |
Journal | Catalysis Letters |
Volume | 52 |
Pagination | 113-119 |
Type of Article | Article |
ISBN Number | 1011-372X |
Keywords | CATALYST, HYDRODENITROGENATION, HYDRODESULFURIZATION, metal nitride, MO2N, PYRIDINE, QUINOLINE, SUPPORTED MOLYBDENUM NITRIDE, SURFACE-AREA |
Abstract | A comparison of various group IV-VIII bulk metal nitride catalysts identified Co4N and Fe3N as having higher pyridine hydrodenitrogenation activity per unit area than Mo2N. Formation of the metal nitrides was confirmed by X-ray diffraction and X-ray photoelectron spectroscopy, and all the nitrides were prepared from metal oxide precursors using the same temperature-programmed reaction technique. In general, the specific activity of the metal nitrides decreased with increased hear of formation of the metal nitride. |
URL | <Go to ISI>://000074430100020 |