Composition and distribution of polycyclic aromatic hydrocarbon contamination in surficial marine sediments from Kitimat Harbor, Canada

Surficial marine sediments from 20 sites within the Kitimat fjord system were analyzed for polycyclic aromatic hydrocarbons (PAHs), Levels of the sum of the 16 USEPA priority pollutant PAHs varied from below detection limits (ca, 1 mu g . g(-1)) to over 10 000 mu g . g(-1). Sediment PAH levels were highest in the immediate vicinity of a large aluminum smelter at the head of Kitimat Arm, and declined rapidly with increasing distance from the smelter. However, even at some of the more distant sites which are geographically isolated from the smelter PAH levels were elevated. The PAH distribution in the fjord system is consistent with a combination of aeolian and fluvial transport of PAHs emitted by the aluminum smelter at the head of Kitimat Arm. The mixture of PAHs present was qualitatively similar in all samples analyzed, including those from the distant sites. All aspects of the PAH composition are consistent with combustion generated PAHs. A correlation between PAH levels and sediment organic carbon was observed; however, this was only significant for highly contaminated sites in the harbor. This probably reflects the high organic content of particulate emissions from the smelter, rather than equilibrium partitioning of PAHs to sediment organic carbon within the harbor itself.