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A CONVENIENT PROCEDURE FOR THE EFFICIENT PREPARATION OF ALKYL (Z)-3-IODO-2-ALKENOATES

TitleA CONVENIENT PROCEDURE FOR THE EFFICIENT PREPARATION OF ALKYL (Z)-3-IODO-2-ALKENOATES
Publication TypeJournal Article
Year of Publication1994
AuthorsPiers, E, Wong, T, Coish, PD, Rogers, C
JournalCanadian Journal of Chemistry-Revue Canadienne De Chimie
Volume72
Pagination1816-1819
Date PublishedAug
Type of ArticleArticle
ISBN Number0008-4042
KeywordsACID, ALLYLIC ALCOHOLS, DERIVATIVES, PROPIOLIC, STEREOSPECIFIC HYDROHALOGENATION REACTION
Abstract

Reaction of alkyl 2-alkynoates with sodium iodide (1.6-5.5 equiv.) in acetic acid (6.2-13 equiv.) at 115 degrees C provides good to excellent yields of the corresponding alkyl (Z)-3-iodo-2-alkenoates.

URL<Go to ISI>://A1994PE25400009