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COORDINATION CHEMISTRY OF 2-(2’-HYDROXYPHENYL)-2-OXAZOLINES WITH ALUMINUM, GALLIUM, AND INDIUM - 1ST TRIS(LIGAND)METAL(III) COMPLEXES OF THIS NATURALLY-OCCURRING BINDING GROUP

TitleCOORDINATION CHEMISTRY OF 2-(2’-HYDROXYPHENYL)-2-OXAZOLINES WITH ALUMINUM, GALLIUM, AND INDIUM - 1ST TRIS(LIGAND)METAL(III) COMPLEXES OF THIS NATURALLY-OCCURRING BINDING GROUP
Publication TypeJournal Article
Year of Publication1992
AuthorsHoveyda, HR, Karunaratne, V, Rettig, SJ, Orvig, C
JournalInorganic Chemistry
Volume31
Pagination5408-5416
Date PublishedDec
Type of ArticleArticle
ISBN Number0020-1669
KeywordsCHIRAL, CRYSTAL-STRUCTURE, ENTEROBACTIN, INTRAMOLECULAR REARRANGEMENT REACTIONS, ISOMERIZATION, KINETICS, LIGANDS, MICROBIAL IRON TRANSPORT, PROBABLE MECHANISM, SIDEROPHORES, TRIS-CHELATE COMPLEXES
Abstract

{A series of tris(ligand)metal(III) complexes of group 13 metals (Al, Ga, In) with 2-(2’-hydroxyphenyl)-2-oxazoline (Hoz), 2-(5’-bromo-2’-hydroxyphenyl)-2-oxazoline (HBroz), 2-(2’-hydroxy-3’-methylphenyl)-2-oxazoline(Hmoz), 2-(2’-hydroxy-3’-allylphenyl)-2-oxazoline (Haloz) have been prepared. These compounds have been studied by a variety of techniques including variable-temperature NMR (H-1 and Al-27) and single-crystal X-ray diffraction. The M(OZ)3-CH3OH complexes (M = Al, Ga, In) are isomorphous and isostructural. Crystallographic data for C28H28MN3O7: monoclinic

URL<Go to ISI>://A1992KE75400016