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Crystal structure and magnetic properties of polybis(formamide)bis(mu-formato)cobalt(II): An extended two-dimensional square lattice material which exhibits spontaneous magnetization below 9 K

TitleCrystal structure and magnetic properties of polybis(formamide)bis(mu-formato)cobalt(II): An extended two-dimensional square lattice material which exhibits spontaneous magnetization below 9 K
Publication TypeJournal Article
Year of Publication1999
AuthorsRettig, SJ, Thompson, RC, Trotter, J, Xia, SH
JournalInorganic Chemistry
Volume38
Pagination1360-+
Date PublishedMar
Type of ArticleArticle
ISBN Number0020-1669
KeywordsSYSTEM
Abstract

In the title compound extended sheets of cobalt(II) ions, linked in a square array by bridging formates, couple antiferromagnetically. Spin canting generates residual spin on the sheets, and interaction between the sheets leads to long-range ferromagnetic ordering and spontaneous magnetization below 9 K.

URL<Go to ISI>://000079370000047