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Dinuclear organometallic dinitrogen complexes of niobium

TitleDinuclear organometallic dinitrogen complexes of niobium
Publication TypeJournal Article
Year of Publication2003
AuthorsFryzuk, MD, Kozak, CM, Patrick, BO
JournalInorganica Chimica Acta
Volume345
Pagination53-62
Date PublishedMar
Type of ArticleArticle
ISBN Number0020-1693
KeywordsACTIVATION, amidophosphine ligands, AZOBENZENE, CLEAVAGE, CRYSTAL-STRUCTURE, CRYSTALLOGRAPHY, DINITROGEN COMPLEXES, END-ON, FIXATION, fluxionality, macrocycle, macrocycles, N-2, NIOBIUM, NITRIDE, SIDE-ON
Abstract

{The niobium(III) chloride precursors (R)[P2N2]NbCl stabilized by the bis-(amidophosphine) macrocycle (where (R)[P2N2] RP(CH2SiMe2NSiMe2CH2)(2)PR

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