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Electronic interaction anisotropy between open-shell lanthanide atoms and helium from cold collision experiment

TitleElectronic interaction anisotropy between open-shell lanthanide atoms and helium from cold collision experiment
Publication TypeJournal Article
Year of Publication2005
AuthorsKrems, RV, Buchachenko, AA
JournalJOURNAL OF CHEMICAL PHYSICS
Volume123
Pagination101101
Date PublishedSEP 8
ISSN0021-9606
Abstract

Based on measurements of the Zeeman relaxation in a cold gas of He-3 {[}C. I. Hancox, S. C. Doret, M. I. Hummon, L. Luo, and J. M. Doyle, Nature (London) 431, 281 (2004)], we show that the electronic interaction anisotropy between rare-earth atoms with nonzero electronic orbital angular momenta and helium is extremely small. The interaction of the rare-earth atoms with He gives rise to several adiabatic potentials with different electronic symmetries. It is demonstrated that the energy splitting between these potentials does not exceed 0.09 cm(-1) at interatomic distances larger than the turning point for collisions at 0.8 K, including the region of the van der Waals interaction minima. (c) 2005 American Institute of Physics.

DOI10.1063/1.2052687