Title | AN ENANTIOSPECIFIC ROUTE TO C,D RING SYNTHONS FOR STEROID-SYNTHESIS |
Publication Type | Journal Article |
Year of Publication | 1992 |
Authors | Clase, JA, Money, T |
Journal | Canadian Journal of Chemistry-Revue Canadienne De Chimie |
Volume | 70 |
Pagination | 1537-1544 |
Date Published | May |
Type of Article | Article |
ISBN Number | 0008-4042 |
Keywords | APPROACH, asymmetric, CONSTRUCTION, Diels-Alder, ENANTIOSELECTIVE SYNTHESIS, GAMMA-BUTYROLACTONE DERIVATIVES, INHOFFEN-LYTHGOE DIOL, SIDE-CHAIN CONSTRUCTION, STEREOCONTROLLED, STEREOSELECTIVE SYNTHESIS, TANDEM ALKYLATION, TRIPLY CONVERGENT SYNTHESIS, VITAMIN-D METABOLITES |
Abstract | A simple enantiospecific route to a hydrindenone intermediate for steroid synthesis has been accomplished. The introduction of a wide variety of side-chain units is made possible hy stereoselective alkylation of a bicyclic ester 13 derived from (+)-camphor 4. |
URL | <Go to ISI>://A1992JL87000031 |