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Field and in-lab determination of Ca<sup>2+</sup> in seawater

TitleField and in-lab determination of Ca2+ in seawater
Publication TypeJournal Article
Year of Publication2014
AuthorsStoodley, R, Rodríguez Núñez, J, Bartz, T
JournalJournal of Chemical Education
Volume91
Issue11
Start Page1954
Date Published04/2014
Abstract

Portions of classic undergraduate quantitative analysis experiments in complexiometric titration and potentiometry are combined with a field-sampling experience to create a two period (2 × 3 h) comparison-based experiment for second-year students. A multifunctional chemical analysis device is used with calcium ion-selective electrode for field measurement of calcium concentration in seawater. The results are compared with later simultaneous potentiometric and colorimetric titration with ethylenediaminetetraacetic acid (EDTA). Students compare precision, difficulty, and sources of error of the different methods and present a written argument supporting their choice of best method including advantages and limitations. The experiment provides an introduction to chemistry in-the-field, sample collection and handling, complex matrices, imperfect methods, fallibility of instrumentation, real-world performance, and decision-making.

URLhttp://pubs.acs.org/doi/abs/10.1021/ed4005722
DOI10.1021/ed4005722