| Title | FIXATION OF AMMONIACAL COPPER PRESERVATIVES - REACTION OF VANILLIN, A LIGNIN MODEL-COMPOUND WITH AMMONIACAL COPPER-SULFATE SOLUTION |
| Publication Type | Journal Article |
| Year of Publication | 1995 |
| Authors | Xie, CS, Ruddick, JNR, Rettig, SJ, Herring, FG |
| Journal | Holzforschung |
| Volume | 49 |
| Pagination | 483-490 |
| Type of Article | Article |
| ISBN Number | 0018-3830 |
| Keywords | AMMONIACAL COPPER PRESERVATIVES, COMPLEXES, DIAMINE, ESR, FIXATION, ION, LIGNIN MODEL COMPOUND, RESONANCE, VANILLIN, WOOD PRESERVATION, X-ray crystal structure |
| Abstract | {A model for the fixation of ammoniacal copper preservatives in wood was examined through reaction of vanillin, a lignin model compound, with ammoniacal copper sulphate solution. The compound produced on evaporation of the aqueous ammoniacal solution has been characterized spectroscopically as di(amine)bis(vanillinato)copper(II); [Cu(vanillin)(2)(NH3)(2)]. Single crystal X-ray crystallographic studies showed that the crystals of [Cu(vanillin)(2)(NH3)(2)] are monoclinic with space group P2(1) with a = 5.4172(9) |
| URL | <Go to ISI>://A1995TJ86800001 |
