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FORMATION OF CIS-BIS(CARBONYL)PALLADIUM(II) FLUOROSULFATE, CIS-PD(CO)2(SO3F)2, AND ITS CRYSTAL AND MOLECULAR-STRUCTURE

TitleFORMATION OF CIS-BIS(CARBONYL)PALLADIUM(II) FLUOROSULFATE, CIS-PD(CO)2(SO3F)2, AND ITS CRYSTAL AND MOLECULAR-STRUCTURE
Publication TypeJournal Article
Year of Publication1994
AuthorsWang, CQ, Willner, H, Bodenbinder, M, Batchelor, RJ, Einstein, FWB, Aubke, F
JournalInorganic Chemistry
Volume33
Pagination3521-3525
Date PublishedAug
Type of ArticleArticle
ISBN Number0020-1669
KeywordsCARBONYL, COMPLEXES
Abstract

{An isomeric mixture of bis(carbonyl)palladium(II) fluorosulfate, Pd(CO)2(SO3F)2, is recrystallized from fluorosulfuric acid, HSO3F, and yields after short, intermittent heating of the solution to 60-degrees-C a single crystal of cis-bis-(carbonyl)palladium(II) fluorosulfate, cis-Pd(CO)2(SO3F)2, which crystallizes in a monoclinic unit cell, space group P2(1)/n, with Z = 4

URL<Go to ISI>://A1994PB22200014