Research & Teaching Faculty

  1. Research & Teaching Faculty
  2. Department Publications
  3. Formation of hexacarbonylmanganese(I) salts, [Mn(CO)(6)]X-+(-), in anhydrous HFII

Formation of hexacarbonylmanganese(I) salts, [Mn(CO)(6)]X-+(-), in anhydrous HFII

TitleFormation of hexacarbonylmanganese(I) salts, [Mn(CO)(6)]X-+(-), in anhydrous HFII
Publication TypeJournal Article
Year of Publication2007
AuthorsGeier, J, Willner, H, Lehmann, CW, Aubke, F
JournalInorganic Chemistry
Volume46
Pagination7210-7214
Date PublishedAug
ISBN Number0020-1669
Abstract

{A convenient one-step synthesis for [Mn(CO)(6)](+) salts has been developed. The method involves the one-electron oxidation of Mn-2(CO)lo by protons in solutions of Lewis acids (BF3, (CF3)(3)BCO) and anhydrous HF. The molecular structure of [Mn(CO)(6))[BF4]center dot SO2 was determined by single-crystal X-ray diffraction. Crystal data: orthorhombic, space group Cmc2(1); a = 8.7001(2) angstrom
URL<Go to ISI>://000248757200055