| Title | The influence of chiral auxiliaries is enhanced within zeolites |
| Publication Type | Journal Article |
| Year of Publication | 2000 |
| Authors | Jayaraman, S, Uppili, S, Natarajan, A, Joy, A, Chong, KCW, Netherton, MR, Zenova, A, Scheffer, JR, Ramamurthy, V |
| Journal | Tetrahedron Letters |
| Volume | 41 |
| Pagination | 8231-8235 |
| Date Published | Oct |
| Type of Article | Article |
| ISBN Number | 0040-4039 |
| Keywords | ASYMMETRIC PHOTOCHEMICAL-REACTIONS, ESTERS, INDUCTION, MODEL, SOLID-STATE |
| Abstract | Zeolites significantly enhance the influence of chiral auxiliaries during photochemical reactions. The generality of this phenomenon has been tested with three independent examples. Chiral auxiliaries that lead to 1:1 mixtures of diastereomers in solution give products in up to 80% diastereomeric excess in the presence of faujasite type zeolites. (C) 2000 Elsevier Science Ltd. All rights reserved. |
| URL | <Go to ISI>://000090123600010 |
