Research & Teaching Faculty

INNER-SHELL AND VALENCE-SHELL ELECTRONIC EXCITATION OF CYCLOPROPANE AND ETHYLENE-OXIDE BY HIGH-RESOLUTION ELECTRON-ENERGY LOSS SPECTROSCOPY

TitleINNER-SHELL AND VALENCE-SHELL ELECTRONIC EXCITATION OF CYCLOPROPANE AND ETHYLENE-OXIDE BY HIGH-RESOLUTION ELECTRON-ENERGY LOSS SPECTROSCOPY
Publication TypeJournal Article
Year of Publication1991
AuthorsSZE, KH, Brion, CE
JournalJOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA
Volume57
Pagination117-135
Date PublishedOCT
ISSN0368-2048
Abstract

High resolution inner-shell and valence-shell electron energy loss spectra of cyclopropane and ethylene oxide have been measured under dipole-dominated conditions (1.0-3.7 keV impact energy and zero degree scattering angle). The resulting inner-shell spectra include C1s excitation in cyclopropane and C1s and O1s excitation in ethylene oxide. The excitation spectra for each molecule are interpreted as transitions to a common manifold of virtual valence orbitals and also to Rydberg orbitals.

DOI10.1016/0368-2048(91)85019-P